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Kinetics of cation ordering in synthetic MgAl 2 O 4 spinel

Giovanni B. Andreozzi、Francesco Princivalle2002-07-01American Mineralogist

The time and temperature evolution of intracrystalline Mg-Al exchange in synthetic MgAl 2 O 4 spinel was studied by single-crystal X-ray diffraction of quenched samples, with the aim of contributing to rock cooling-rate estimation. Flux-grown, homogeneous crystals (0.1 mm in size) were annealed at 1000°C and then were…

Advanced Condensed Matter PhysicsNuclear materials and radiation effectsX-ray Diffraction in Crystallography

Melt‐state polymer chain dimensions as a function of temperature

Ramanan Krishnamoorti、William W. Graessley、A. Zirkel 等 7 位作者2002-07-01Journal of Polymer Science Part B Polymer Physics

Abstract The unperturbed chain dimensions (〈 R 2 〉 o / M ) of cis / trans ‐1,4‐polyisoprene, a near‐atactic poly(methyl methacrylate), and atactic polyolefins were measured as a function of temperature in the melt state via small‐angle neutron scattering (SANS). The polyolefinic materials were derived from polydienes…

Polymer crystallization and propertiesPolymer Nanocomposites and PropertiesRheology and Fluid Dynamics Studies

A novel robot hand with embedded shape memory alloy actuators

Kai Yang、Chaochen Gu2002-07-01Proceedings of the Institution of Mechanical Engineers Part C Journal of Mechanical Engineering Science

This paper describes the development of an active robot hand, which allows smooth and lifelike motions for anthropomorphic grasping and fine manipulations. An active robot finger 10mm in outer diameter with a shape memory alloy (SMA) wire actuator embedded in the finger with a constant distance from the geometric cent…

Robot Manipulation and LearningShape Memory Alloy TransformationsSoft Robotics and Applications

Inhibition of corrosion of mild steel by sodium n,n-diethyl dithiocarbamate in hydrochloric acid solution

Hongbo Fan、C. Fu、H.-L. Wang 等 5 位作者2002-07-01British Corrosion Journal

The effect of sodium n,n-diethyl dithiocarbamate (SDEDTC) on the corrosion of mild steel in 0·5 mol L-1 HCl solution was studied using weight loss and potentiodynamic polarisation methods. Experimental data revealed that SDEDTC acted as an inhibitor in the acid environment and, furthermore, that the compound was a mix…

Corrosion Behavior and InhibitionConcrete Corrosion and DurabilityOrganometallic Compounds Synthesis and Characterization

In situ resistivity measurements during the atomic layer deposition of ZnO and W thin films

Mikael Schuisky、Jeffrey W. Elam、Steven M. George2002-07-01Applied Physics Letters

In situ monitoring of the electrical resistivity of ZnO and W thin films during atomic layer deposition (ALD) was performed using a four-point probe. Large oscillations were observed during the ZnO ALD resistivity measurements. The resistivity dramatically increased during each diethyl zinc exposure and decreased duri…

ZnO doping and propertiesGas Sensing Nanomaterials and SensorsSemiconductor materials and devices

Effect of spatial spin modulation on the relaxation and NMR frequencies of 57Fe nuclei in a ferroelectric antiferromagnet BiFeO3

A. V. Zalesskiǐ、А. А. Фролов、А. К. Звездин 等 8 位作者2002-07-01Journal of Experimental and Theoretical Physics

The 57 Fe NMR spectra of the 57 Fe-enriched (95.43%) ceramics of a ferroelectric antiferromagnet BiFeO 3 with a spatially modulated magnetic structure have been studied. It is established that a cycloidal spin modulation in BiFeO 3 causes a spatial modulation of the spin-spin relaxation rate along the magnetic cycloid…

Multiferroics and related materialsMagnetic Properties and ApplicationsMagneto-Optical Properties and Applications

Effect of Microstructure on the Stress Corrosion Cracking of X-80 Pipeline Steel in Diluted Sodium Bicarbonate Solutions

J.G. González-Rodrı́guez、M. Casales、V.M. Salinas-Bravo 等 5 位作者2002-07-01CORROSION

An investigation was carried out on the effect of heat treatments on the stress corrosion cracking (SCC) resistance of X-80 pipeline steel in 0.01 M and 0.05 M sodium bicarbonate (NaHCO3) solutions using the slow strain rate testing (SSRT) technique. The heat treatments were either water-quenched, water-quenched and t…

Hydrogen embrittlement and corrosion behaviors in metalsEngineering Diagnostics and ReliabilityMaterial Properties and Failure Mechanisms

Corrosion inhibition of carbon steel in hydrochloric acid by organic compounds containing heteroatoms

Moina Athar、Hapipah Binti Mohd Ali、M.A. Quraishi2002-07-01British Corrosion Journal

Three organic inhibitors containing heteroatoms, namely: undecenoic acid hydrazide (UAH); 2-mercaptobenzothiazole (MBT); and 2-hydrazinobenzothiazole (HBT) have been synthesised in the lab and their inhibiting action on the corrosion of carbon steel in 1N HCl was investigated by means of two different techniques, name…

Corrosion Behavior and InhibitionHydrogen embrittlement and corrosion behaviors in metalsConcrete Corrosion and Durability

Solvothermal Synthesis and Crystal Structure of the New Layered Thioantimonate(III) [Ni(C4H13N3)2]9Sb22S42 · 0.5H2O: Interconnection of the SbS3, SbS4, and SbS5 Primary Building Units Yielding the Very Large Sb30S30 HeteroringDedicated to Professor Welf Bronger on the Occasion of his 70th Birthday

R. Stähler、Wolfgang Bensch2002-07-01Zeitschrift für anorganische und allgemeine Chemie

The novel thioantimonate(III) [Ni(dien)2]9Sb22S42 · 0.5H2O was synthesised under solvothermal conditions by reacting elemental Ni, Sb and S in an aqueous solution of diethylenetriamine (dien) (80%). The compound crystallises in the triclinic space group P1¯, a = 8.997(2) Å, b = 15.293(3) Å, c = 34.434(7) Å, α = 85.51(…

Crystal Structures and PropertiesSolid-state spectroscopy and crystallographyOrganometallic Compounds Synthesis and Characterization

IEEE Task Force Report: brittle fracture in nonceramic insulators

J.T. Burnham、T. Baker、A. Bernstorf 等 16 位作者2002-07-01IEEE Transactions on Power Delivery

A description of the composite insulator brittle fracture phenomenon suitable to allow correct diagnosis of a failure is provided. This paper reports on the number of brittle fractures that have occurred around the world and contains specific empirical data surrounding composite insulator brittle fractures in the US.…

High voltage insulation and dielectric phenomenaPower Transformer Diagnostics and InsulationElectrical Fault Detection and Protection

Specific heat and magnetocaloric effect measurements using commercial heat-flow sensors

T. Plackowski、Yuxing Wang、Alain Junod2002-07-01Review of Scientific Instruments

We present a technique for measuring the specific heat (C) and the isothermal magnetocaloric effect (MT) in the temperature range from 30 to 300 K. The method consists of precise measurements of the heat flux between the sample and its surroundings. This design, which uses commercially available Peltier elements as he…

Physics of Superconductivity and MagnetismMagnetic and transport properties of perovskites and related materialsAdvanced Condensed Matter Physics

Anaerobic Corrosion of Carbon Steel and Cast Iron in Artificial Groundwaters: Part 1—Electrochemical Aspects

N.R. Smart、Daniel John Blackwood、L. Werme2002-07-01CORROSION

In Sweden, high-level radioactive waste will be disposed of in a canister with a copper outer container and a cast iron or carbon steel insert. If the iron insert comes into contact with anoxic geological water, anaerobic corrosion will occur. This paper presents a study of the electrochemical aspects of anaerobic cor…

Corrosion Behavior and InhibitionHydrogen embrittlement and corrosion behaviors in metalsConcrete Corrosion and Durability

Structural Analysis of the Y299C Mutant of Escherichia coli UDP-galactose 4-Epimerase

James B. Thoden、J.M. Henderson、Judith L. Fridovich‐Keil 等 4 位作者2002-07-01Journal of Biological Chemistry

UDP-galactose 4-epimerase catalyzes the interconversion of UDP-Gal and UDP-Glc during normal galactose metabolism. The mammalian form of the enzyme, unlike its Escherichia coli counterpart, can also interconvert UDP-GalNAc and UDP-GlcNAc. One key feature of the epimerase reaction mechanism is the rotation of a 4-ketop…

Protein Structure and DynamicsGlycosylation and Glycoproteins ResearchEnzyme Structure and Function

Impact Testing and Analysis of Composites for Aircraft Engine Fan Cases

Gary D. Roberts、Duane M. Revilock、Wieslaw K. Binienda 等 6 位作者2002-07-01Journal of Aerospace Engineering

The fan case in a jet engine is a heavy structure because of its size and because of the requirement that it contain a blade released during engine operation. Composite materials offer the potential for reducing the weight of the case. Efficient design, test, and analysis methods are needed to efficiently evaluate the…

Energetic Materials and CombustionHigh-Velocity Impact and Material BehaviorStructural Response to Dynamic Loads

Fluorinated mesogen-jacketed liquid-crystalline polymers as surface-modifying agents: Design, synthesis and characterization

Padma Gopalan、Luisa Andruzzi、Xuefa Li 等 4 位作者2002-07-01Macromolecular Chemistry and Physics

Monomers with semifluorinated tails on monomeric vinyl hydroquinone cores were synthesized and their polymerization behavior was examined. The resulting semifluorinated mesogen-jacketed liquid-crystalline polymers (MJLCPs) proved to form fairly hydrophobic surfaces with water contact angles of 110–118°. These polymers…

Liquid Crystal Research AdvancementsSurface Modification and SuperhydrophobicitySynthesis and properties of polymers

Optically and Thermally Stimulated Luminescence of KMgF3:Ce3+ and NaMgF3:Ce3+

N.J.M. Le Masson、A. J. J. Box、C.W.E. van Eijk 等 5 位作者2002-07-01Radiation Protection Dosimetry

The potentialities of optically stimulated luminescence (OSL) for personal dosimetry of ionising radiation have stimulated the search for new synthetic materials with good dosimetric properties. The sensitivity of two new OSL materials KMgF3 and NaMgF3 doped with Ce3+ ions has been evaluated and found to be of the sam…

Luminescence Properties of Advanced MaterialsRadiation Detection and Scintillator TechnologiesInorganic Fluorides and Related Compounds

Tunnelling in Afterglow: its Coexistence and Interweaving with Thermally Stimulated Luminescence

R. Visocekas2002-07-01Radiation Protection Dosimetry

After irradiation of a phosphorescent material, the intensity of the afterglow is usually strongly dependent on the temperature: as lower temperatures are reached, it drops below the noise. But sometimes this intensity stops dropping and becomes stationary. It is seen then to decrease slowly with the time t with (1/t)…

Luminescence Properties of Advanced MaterialsRadiation Detection and Scintillator TechnologiesPhotoreceptor and optogenetics research

Elastomer Blends

D. Mangaraj2002-07-01Rubber Chemistry and Technology

Abstract Blending of elastomers is often used to enhance he performance characteristics of rubber products. This article reviews the thermodynamic principles underlying polymer-polymer miscibility, with special reference to elastomer blends. It discusses the distribution of fillers, additives and curatives in differen…

Polymer Nanocomposites and Properties

On the possabilities to enhance the fatigue properties of ultrafine-grained metals

Heinz Werner Höppel、Р. З. Валиев2002-07-01International Journal of Materials Research (formerly Zeitschrift fuer Metallkunde)

Abstract Cyclic deformation behaviour of ultrafine-grained (UFG) materials processed by severe plastic deformation is reviewed in the light of possabilities to enhance the fatigue properties of UFG...

Microstructure and mechanical propertiesAluminum Alloys Composites PropertiesAdvanced Surface Polishing Techniques

Structural Studies on the Synchronization of Catalytic Centers in Glutamate Synthase

Robert H. H. van den Heuvel、Davide Ferrari、R Bossi 等 8 位作者2002-07-01Journal of Biological Chemistry

The complex iron-sulfur flavoprotein glutamate synthase (GltS) plays a prominent role in ammonia assimilation in bacteria, yeasts, and plants. GltS catalyzes the formation of two molecules of l-glutamate from 2-oxoglutarate and l-glutamine via intramolecular channeling of ammonia. GltS has the impressive ability of sy…

Protein Structure and DynamicsEnzyme Structure and FunctionGABA and Rice Research