Materials Literature
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Introduction Properties of Titanium Dioxide and its Nanoparticles Preparation of Nanostructured Titanium Dioxide and Titanates Applications of Nanostructured Titanium Dioxide Supported and Immobilized Titanium Dioxide Nanomaterials.
In this communication, we present results of theoretical studies of various systems where Van der Waals interaction plays a considerable role. In the first-principle calculations performed in the density functional theory framework we implement novel functionals accounting for Van der Waals forces and employ to the te…
The aromatic nature of porphyrins is commonly attributed to the presence of an [18]annulene substructure. However, this viewpoint has been disputed. Drawing on a range of examples of carbaporphyrinoid systems from the author's own studies, the [18]annulene model is shown to be a self-consistent and insightful approach…
Combining physics, engineering, chemistry and biology, we can now design, synthesize and fabricate biological nanomaterials at the molecular scale using self-assembling peptide systems. These peptides have been used for fabrication of nanomaterials, including nanofibers, nanotubes and vesicles, nanometer-thick surface…
The optical response of nanoplasmonic colloids in disperse phase is strictly related to their shape. However, upon self-assembly, new optical features, for example, bonding or antibonding modes, emerge as a result of the mutual orientations of nanoparticles. The geometry of the final assemblies often determines which…
The corrosion of Monel-400 after varied exposure periods in naturally aerated Arabian Gulf seawater (AGS) has been carried out using gravimetric, cyclic potentiodynamic polarization, chronoamperometry, open-circuit potential, and impedance spectroscopy measurements along with SEM/EDX investigations. Gravimetric data w…
The effect of addition of argan Kernels extract (AKE) and cosmetic argan oil (CAO) on the corrosion of steel in 1M HCl acid has been studied by weight loss measurements, potentiodynamic polarisation and Electrochemical Impedance Spectroscopy (EIS) measurements. The inhibition efficiency was found to increase with inhi…
Azobenzene functionalised banana–calamitic dimers and a novel type of banana–calamitic–banana trimers have been synthesised. Their thermotropic behaviour and the structure of the mesophases have been characterised by differential scanning calorimetry, polarising optical microscopy and X-ray diffractions measurements.…
Polylactide (PLA) electrospun fibers have been reported as a scaffold for bone tissue engineering application, however, the great hydrophobicity limits its broad application. In this study, the hybrid amphiphilic poly(ethylene glycol) (PEG)/hydrophobic PLA fibrous scaffolds exhibited improved morphology with regular a…
The use of in situ tools to monitor the transformation of a polymorphic material has the potential to provide unique information about the mechanism and rate of transformation of the polymorphs. In this paper, the solution mediated transformation between α and β form p-aminobenzoic acid (PABA) was investigated in deta…
Polarising optical microscopy (POM) shows evidence for a reversible uniaxial nematic (NU) to biaxial nematic (NB) phase transition in a quiescent melt of bent-core mesogens (BCM). A second superimposed Schlieren texture, attributed to a second director field, grows into the NU phase on lowering the temperature and dis…
Ionized point defects that act as electron donors or acceptors can strongly affect thermoelectric transport properties of bismuth telluride compounds. These crystal imperfections including antisite defects and vacancies can be generated or annihilated during material processing. Here, we reported the effect of ball mi…
Effectiveness of nanomedicines in cancer therapy is limited in part by inadequate delivery and transport in tumor interstitium. This article reviews the experimental approaches to improve nanomedicine delivery and transport in solid tumors. These approaches include tumor vasculature normalization, interstitial fluid p…
This paper presents a laboratory experimental study on the effect of high strain rate loading on compressive behaviour of plain and fibre-reinforced high-strength concrete with similar strength of 80–90 MPa. Steel fibres, polyethylene fibres and a combination of these were used in the fibre-reinforced high-strength co…
Single-walled carbon nanotubes (SWNTs) have been identified as an efficient drug carrier. Here a controlled drug-delivery system based on SWNTs coated with doxorubicin (DOX) through hydrazone bonds was developed, because the hydrazone bond is more sensitive to tumor microenvironments than other covalent linkers. The S…
5,10,15,20-tetrakis(pentafluorophenyl)porphyrin reacts with a range of nucleophiles (amines, alcohols, thiols, nitrogen heterocycles, and others) resulting in the nucleophilic aromatic substitution of the para-F atoms of the pentafluorophenyl groups. This reaction, which was fortuitously discovered by Kadish and colla…
In this paper, a new method of one-pot biosynthesizing of gold nanoparticles (GNPs), using chloroplasts as reductants and stabilizers is reported. The as-prepared GNPs were characterized by ultraviolet visible spectroscopy, transmission electron microscopy, X-ray powder diffraction, and Fourier transform infrared spec…
In our present study, we attempted to grow the single crystals of (2 E )-1-(4-chlorophenyl)-3-[4-(methylsulfanyl)phenyl]prop-2-en-1-one by making use of the slow evaporation solution growth technique at room temperature. But the single crystal X-ray diffraction technique revealed that the grown crystal was a co-crysta…
The oxidation of three-dimensionally ordered macroporous (3DOM) CeO2 (ceria) by H2O and CO2 at 1100 K is presented in comparison to the oxidation of nonordered mesoporous and sintered, low porosity ceria. 3DOM ceria, which features interconnected and ordered pores, increases the maximum H2 and CO production rates over…