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Expanding the 3d-4f heterometallic chemistry of the (py)2CO and pyCOpyCOpy ligands: structural, magnetic and Mössbauer spectroscopic studies of two FeII–GdIII co mplexes

A.N. Georgopoulou、Rosa Adam、Catherine P. Raptopoulou 等 7 位作者2011-01-01Dalton Transactions

Complex [Fe(II)Gd(III){pyCO(OEt)pyCOH(OEt)py}(3)](ClO(4))(2) (1) crystallizes in the Cc space group and contains one hexacoordinate ferrous ion and one enneacoordinate Gd(III) ion. Complex [Fe(2)(II)Gd(III){pyCO(OEt)py}(4)(NO(3))(H(2)O)][Gd(NO(3))(5)](0.5)(ClO(4)) (2) crystallizes in the C2/c space group and contains…

Metal complexes synthesis and propertiesMagnetism in coordination complexesLanthanide and Transition Metal Complexes

Experimental Study of Sound Propagation Through Bubbly Water: Comparison With Optical Measurements

Vincent Duro、Dominique R. Rajaona、Dominique Décultot 等 4 位作者2011-01-01IEEE Journal of Oceanic Engineering

The study of the acoustical properties of bubbly flows remains a challenge for scientists. Classical theoretical results provide the expression of a complex effective wave number characterizing sound propagation through such a medium. Theoretical attenuation and phase-speed changes of sound can be obtained from this e…

Fluid Dynamics and MixingUltrasound and Cavitation PhenomenaFlow Measurement and Analysis

Numerical elimination methods of ITO cell contribution to dielectric spectra of ferroelectric liquid crystals

P. Perkowski2011-01-01Opto-Electronics Review

Abstract Indium tin oxide (ITO) electrodes are widely used for liquid crystal applications as well as for measuring cells. Unfortunately, ITO layer possesses its own non zero resistivity R which produces (with the capacity C) the cut-off frequency f0 of RC circuit. Dielectric spectroscopy cannot be performed for high…

Liquid Crystal Research AdvancementsSemiconductor Lasers and Optical DevicesMechanical and Optical Resonators

Non-isothermal crystallization kinetics and phase transformation of Bi2O3-SiO2 glass-ceramics

Hongwei Guo、Xiufeng Wang、Dameng Gao2011-01-01Science of Sintering

The Bi2O3-SiO2 (BS) glass-ceramics were prepared by melt-quench technique, and the crystallization kinetics and phase transformation behavior were investigated in accordance with Kissinger and Johson-Mehl-Avrami equation, DSC, XRD and SEM. The results show that in the heat treatment process (or termed as re-crystalliz…

Advanced ceramic materials synthesisGlass properties and applicationsRecycling and utilization of industrial and municipal waste in materials production

Synthesis and characterisation of ZnO/PVA composite nanofibres by electrospinning

Ramdane Bouzerara、S. Achour、Nouar Tabet 等 4 位作者2011-01-01International Journal of Nanoparticles

In this work, polyvinyl alcohol (PVA) and zinc acetate, with small quantity of cobalt acetate as dopant were used to prepare composite nanofibres by electrospinning technique. The obtained nanofibres were calcined at 520°C in air. After calcination of the above precursor fibres, ZnO or ZnO/PVA and Co doped ZnO/PVA com…

Supercapacitor Materials and FabricationConducting polymers and applicationsElectrospun Nanofibers in Biomedical Applications

EFFECTS OF STERILIZATION AND TEMPERATURE ON THE DECREASE KINETIC OF PHOSPHORUS BIOAVAILABILITY IN TWO DIFFERENT SOIL TYPES

Ali Akbar Safari Sinegani、Serveh Sedri2011-01-01Journal of soil science and plant nutrition

The aim of this work was to study the effects temperature and microbial activity on the decrease kinetic of availabile P in two different soil types.Surface soils were sampled from Guilan and Hamadan provinces in north and northwest of Iran with temperate and semiarid climates.The availability of P in soil samples was…

Soil Carbon and Nitrogen DynamicsPlant Micronutrient Interactions and EffectsClay minerals and soil interactions

Urea-functionalized mesoporous polymeric catalyst: a cooperative effect between support and secondary amine on water-medium Knoevenagel reactions

Ruixing Zhu、Jian Shen、Yongyi Wei 等 4 位作者2011-01-01New Journal of Chemistry

Urea-functionalized mesoporous polymers (urea-MPs) were synthesized through the surfactant-directed urea-phenol-formaldehyde oligomers self-assembly approach. The as-prepared urea-MPs material exhibited superior catalytic activity than parent urea in water-medium Knoevenagel condensation reactions and could be used re…

Mesoporous Materials and CatalysisCovalent Organic Framework ApplicationsSynthesis and properties of polymers

A molecular dynamics study of the mechanical properties of graphene nanoribbon-embedded gold composites

Shih-Kai Chien、Yue-Tzu Yang、Cha’o-Kuang Chen2011-01-01Nanoscale

Molecular dynamics simulations were performed to investigate the mechanical properties of a single-crystal gold nanosheet and graphene nanoribbon-embedded gold (GNR/Au) composites for various embedded locations, temperatures, and lengths. The computational results show that the Young's modulus, tensile strength, and f…

Graphene research and applicationsMicrostructure and mechanical propertiesAluminum Alloys Composites Properties

Influence of polymer conformations on the aggregation behaviour of alternating dialkylsilylene-[4,4′-divinyl(cyanostilbene)] copolymers

Chih‐Hsien Chen、Chih‐Hsien Chen、Shern‐Long Lee 等 7 位作者2011-01-01Polymer Chemistry

The influence of the substituents at silicon on the aggregation enhanced emission (AEE) of alternating dialkylsilylene-[4,4′-divinyl(cyanostilbene)] copolymers 3 and 4 is examined. The presence of the bulky isopropyl group in 3b significantly enhances the quantum yield upon aggregation. On the other hand, the emission…

Organic Electronics and PhotovoltaicsOrganic Light-Emitting Diodes ResearchLuminescence and Fluorescent Materials

Hybrid A–B–A type nanowires through cation exchange

Akshaya K. Samal、Thalappil Pradeep2011-01-01Nanoscale

Hybrid A–B–A type nanowires (NWs) with Ag5Te3–HgTe–Ag5Te3 composition have been created by the reaction of Hg2+ with Ag2Te NWs. The NW morphology of Ag2Te is preserved upon reaction with minor changes and the two separate phases formed are spatially separated within the same NW. The reaction of Hg2+ with Ag2Te NWs was…

Quantum Dots Synthesis And PropertiesAdvanced Thermoelectric Materials and DevicesChalcogenide Semiconductor Thin Films

Wavelength dependence of polyyne preparation by liquid-phase laser ablation using pellet targets

Ryutaro Matsutani、Kohei Inoue、Noriyuki Wada 等 4 位作者2011-01-01Chemical Communications

The amount of polyynes produced by Nd:YAG laser (355, 532, and 1064 nm) ablation of fullerene and graphite pellet targets was the largest for 1064 nm ablation, contrary to the powder target in the previous report. This result is believed to come from the difference in the main polyyne-production area in liquids in the…

Diamond and Carbon-based Materials ResearchAtomic and Molecular PhysicsLaser-induced spectroscopy and plasma

Identification of corrosion products on a medieval copper-silver coin

Chrissy M. Martins、J.I. Martins2011-01-01Protection of Metals and Physical Chemistry of Surfaces

This work relates a study on a medieval coin found during archaeological works carried out at the site of Senhora do Castelo in Urros (Torre de Moncorvo, Portugal). The artefact has been identified as a coin of D. Afonso IX of Leon (1155–1188). The substratum showed composition typical of bullion, Cu-Ag (30–33%) with…

Corrosion Behavior and InhibitionCultural Heritage Materials AnalysisConservation Techniques and Studies

Grain Boundary Deformation at High Temperature Tensile Tests in ODS Ferritic Steel

Yoshito Sugino、Shigeharu Ukai、Bin Leng 等 7 位作者2011-01-01ISIJ International

The tensile test of the recrystallized ODS ferritic steels was performed in the loading direction for the longitudinal and 45° inclined with respect to the grains alignment. The testing temperature was 800°C and the strain rate was 10–4 s–1. A clear serration structure was observed at near the grain boundaries at the…

Microstructure and mechanical propertiesFusion materials and technologiesNuclear Materials and Properties

Clay nanoplatelet induced morphological evolutions during polymeric foaming

G. Harikrishnan、T. Umasankar Patro、A. Raman Unni 等 4 位作者2011-01-01Soft Matter

Remarkable evolutionary changes in cell morphology during reactive polymer nanocomposite foaming are observed by controlled foaming of suspensions of montmorillonite clay in the oligomeric polyurethane component. Delaminated nanoplatelets, when present as a networked cluster in suspensions, are shown to have very high…

Enhanced Oil Recovery TechniquesPickering emulsions and particle stabilizationPolymer Foaming and Composites

The application of a photochromic probe to monitor the self-assembly of thermosensitive block copolymers

Francesca Ercole、Simon Harrisson、Thomas P. Davis 等 4 位作者2011-01-01Soft Matter

Analysis of the thermal decolouration kinetics of a spirooxazine dye (SOX) incorporated into various thermally responsive, amphiphilc block copolymers, poly(N-isopropyl acrylamide)-block-poly(N-acryloyl morpholine), was used to probe their self-assembly behaviour in water. The Arrhenius plots of the thermal decolourat…

Advanced Polymer Synthesis and CharacterizationSurfactants and Colloidal SystemsPhotochromic and Fluorescence Chemistry

ZnO Nanoestructured Layers Processing with Morphology Control by Pulsed Electrodeposition

María Dolores Reyes Tolosa、Javier Orozco-Messana、L. C. Damonte 等 4 位作者2011-01-01Journal of The Electrochemical Society

The fabrication of nanostructured ZnO thin films is a critic process for a lot of applications of this semiconductor material. The final properties of this film depend fundamentally of the morphology of the sintered layer. In this paper a process is presented for the fabrication of ZnO nanostructured layers with morph…

ZnO doping and propertiesGas Sensing Nanomaterials and SensorsElectrodeposition and Electroless Coatings

Role of Oxidative Stress in Transformation Induced by Metal Mixture

Martín Silva-Aguilar、Emilio Rojas、Mahara Valverde2011-01-01Oxidative Medicine and Cellular Longevity

Metals are ubiquitous pollutants present as mixtures. In particular, mixture of arsenic-cadmium-lead is among the leading toxic agents detected in the environment. These metals have carcinogenic and cell-transforming potential. In this study, we used a two step cell transformation model, to determine the role of oxida…

Nanoparticles: synthesis and applicationsEnvironmental Toxicology and EcotoxicologyHeavy Metal Exposure and Toxicity

Comparison of Radioimmuno and Carbon Nanotube Field-Effect Transistor Assays for Measuring Insulin-Like Growth Factor-1 in a Preclinical Model of Human Breast Cancer

Laundette P. Jones、Steingrimur Stefansson、Man S. Kim 等 4 位作者2011-01-01Journal of Nanobiotechnology

BACKGROUND: To realize the promise of personalized medicine, diagnostic instruments used for detecting and measuring biomarkers must become smaller, faster and less expensive. Although most techniques used currently to detect biomarkers are sensitive and specific, many suffer from several disadvantages including their…

Carbon Nanotubes in CompositesAdvanced biosensing and bioanalysis techniquesAdvanced Biosensing Techniques and Applications

Synthesis of ZrP2O7 by hydrothermal reaction and post-calcination

Ahmed Jalal Samed、Dongjie Zhang、Satoshi Hinokuma 等 4 位作者2011-01-01Journal of the Ceramic Society of Japan

A new method of synthesis of single phase ZrP2O7 was studied using hydrothermal reaction of amorphous ZrO(OH)2 with H3PO4 and subsequent air calcination. The reaction steps to ZrP2O7 were analyzed by means of XRD, TG/DTA and FT-IR. The hydrothermal reaction at 200°C for 18 h yielded well-crystallized tetraphosphate, Z…

Microwave Dielectric Ceramics SynthesisNuclear materials and radiation effectsThermal Expansion and Ionic Conductivity

Early Inspection of Wet Steam Generator Tubes Based on Metal Magnetic Memory Method

Tingjun Yan、Jiedong Zhang、Guodong Feng 等 4 位作者2011-01-01Procedia Engineering

Fatigue tests on wet steam generator 20G tubes were carried out and the metal magnetic memory (MMM) signals were detected. Though the analysis of MMM signals from different fatigue cycles, the variation characteristic of the MMM signals was obtained and a novel quantitative evaluation method of the early failure by MM…

Metallurgy and Material FormingMagnetic Properties and ApplicationsNon-Destructive Testing Techniques