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Glass Forming Region and Ti<sup>4+</sup> Co-Ordination Number in R<sub>2</sub>O-TiO<sub>2</sub> (R=Rb, K, Na) and BaO-TiO<sub>2</sub> Binary Glasses

Katsuhiko Yoshimaru、Yasuaki UEDA、Kenji Morinaga 等 4 位作者1984-01-01Journal of the Ceramic Association Japan

Rb2O-, K2O-, Na2O-及びBaO-TiO2の2成分系のガラスをスプラット・クェンチング法により作製し, ガラス生成領域を決定するとともに, ガラス中のTi4+の酸素配位数を赤外線分光法 (IR) 及び光音響分光法 (PAS) により推定した. 電子線回折で確認したガラス生成領域は推定冷却度が高くなると広く, また添加酸化物の塩基度が大きいほどガラスを生成しやすい傾向を示した.これらガラスのPASスペクトルはIRスペクトルよりもTi4+の酸素配位数の変化を反映する傾向を示した. 2成分チタネートガラス中ではTi4+(4) とTi4+(6) が共存し, その存在割合を支配する因子はガラスの塩基度と考えられた. PASスペ…

Glass properties and applicationsRecycling and utilization of industrial and municipal waste in materials productionPigment Synthesis and Properties

Electrodeposition of Molybdenum in KF-B<SUB>2</SUB>O<SUB>3</SUB>&ndash;K<SUB>2</SUB>MoO<SUB>4</SUB> Fused Salts

Koichiro Koyama、Yasuhiko Hashimoto、Shinichirô Ômori 等 4 位作者1984-01-01Transactions of the Japan Institute of Metals

Visually smooth and adherent deposits of molybdenum have been obtained electrolytically on a copper, a nickel and a molybdenum substrate in a KF-B2O3–K2MoO4 fused salt at temperatures of 1023–1173 K and current densities of 110–990 A/m2 with a molybdenum or a graphite anode.

Gas Sensing Nanomaterials and SensorsTransition Metal Oxide NanomaterialsCatalysis and Oxidation Reactions

L'uchucchacuaïte, AgMnPb3Sb5S12, une nouvelle espèce minérale de la série de l'andorite

Yves Moëlo、Elisabeth Oudin、Paul Picot 等 4 位作者1984-01-01Bulletin de Minéralogie

L'uchucchacuaïte est associée à : galène, alabandite, bénavidésite, sphalérite, pyrite, pyrrhotite et mispickel dans la minéralisation télescopée de Uchuc-Chacua (Pérou). L'analyse à la microsonde électronique donne Pb 34,8 ; Sb 34,4 ; Ag 5,9 ; Mn 2,8 ; Fe 0,2 ; S 21,1 ; Se 0,3 ; total 99,5 %. Formule : Ag0,98(Mn0,91F…

Geological and Geochemical AnalysisCrystal Structures and PropertiesMineralogy and Gemology Studies

On the Representative Domain

Qi-Keng Lu1984-01-01Birkhäuser Boston eBooks

Professor Stefan Bergman [1] introduced the idea of Repräsentantenbereich of a bounded domain in ℂn. However the strict definition of a representative domain is not very clear as noted in [2]. It seems that he called the image f( ) of the mapping f: 1 $$ {\text{z}} \to \frac{{\partial \log \frac{{{\text{k}}({\text{z}}…

Metamaterials and Metasurfaces ApplicationsAlgebraic and Geometric Analysis

PSEUDO WEAK PHASE OBJECT APPROXIMATION IN HIGH RESOLUTION ELECTRON MICROSCOPY

Fanghua Li、TANG DONG、中国科学院物理研究所1984-01-01Acta Physica Sinica

A pseudo weak phase object approximation to the principle of image formation in high resolution electron microscopy is presented. It is pointed out that there is the possibility of preferential revealing lighter or heavier atoms in the crystal structure in high resolution electron micrographs by choicing different cry…

Advanced Electron Microscopy Techniques and ApplicationsElectron and X-Ray Spectroscopy TechniquesAdvanced Materials Characterization Techniques

Excited state redox properties of phthalocyanines: influence of the axial ligand on the rates of relaxation and electron-transfer quenching of the lowest 3 ππ* excited state

G. Ferraudi、D. Rajendra Prasad1984-01-01Journal of the Chemical Society Dalton Transactions

Laser flash excitations at 640 nm have been used to generate the transient spectra of the lowest-lying 3ππ* state of phthalocyaninatoruthenium(II) complexes. The properties of this excited state such as the positions of the maxima, λmax.= 500 ± 30 nm, and lifetimes, t½= 70–4 500 ns, exhibit a large dependence on the e…

Porphyrin and Phthalocyanine ChemistryPhotochemistry and Electron Transfer StudiesMetal-Catalyzed Oxygenation Mechanisms

Optimization of optical parameters and electric field distribution in multilayers

F. Demichelis、E. Mezzetti-Minetti、Luigi Tallone 等 4 位作者1984-01-01Applied Optics

Multilayer coatings for high-power laser mirrors and lenses have been optimized by a particular constrained gradient method to reach together with a reduction of damage threshold (i.e., suppression of the peak electric field), good values of optical parameters (reflectance or transmittance). The problem has been solve…

Laser Material Processing TechniquesAdvanced optical system designOptical Coatings and Gratings

Electrochemical Studies of the Corrosion of Ni and Fe in Molten Carbonate

Atsushi Nishikata、Shirō Haruyama1984-01-01Journal of the Japan Institute of Metals and Materials

Electrochemical studies of corrosion of Ni, Fe and their alloys have been made in molten carbonate at 973 K by using potentiodynamic polarization and polarization resistance methods. It was concluded that metallic corrosion in molten carbonate was well explained by the mixed potential theory. Partial cathodic reaction…

Corrosion Behavior and InhibitionHydrogen embrittlement and corrosion behaviors in metalsMetallurgical Processes and Thermodynamics

Ecological studies on the littoral attaching micro-algae - I. The cell division rates of ten species of attaching diatoms in natural seawater.

Nobuhiko Tanaka1984-01-01NIPPON SUISAN GAKKAISHI

The cell division rates of ten species of attaching diatoms isolated from Ago Bay were measured on the bottom of the culture vessel with running nutrient-poor natural seawater under the illumination of 4000 lx with a dark/light cycle of 10/14 hours at ca. 19°C. The exchange rate of running seawater through the culture…

Diatoms and Algae ResearchWater Quality Monitoring and Analysis

Structure of the Laves Phase Observed in Polystyrene Latexes

Masayuki Hasaka、Hiromichi Nakashima、K. Oki1984-01-01Transactions of the Japan Institute of Metals

This paper describes the light-microscopic observations of polystyrene latexes with spherical particles of two different diameters, d and 1.4–1.9d. Polystyrene latexes are available for simulating real structures in intermetallic compounds. An amorphous state appeared for a few hours after stirring or vibrating the la…

Polymer Nanocomposites and PropertiesMetallurgical and Alloy ProcessesElectrophoretic Deposition in Materials Science

Anticapsin, an active-site directed irreversible inhibitor of glucosamine-6-phosphate synthetase from Escherichia coli.

Henryk Chmara、H Zähner、Edward Borowski1984-01-01The Journal of Antibiotics

Glucosamine-6-phosphate synthetase from Escherichia coli K-12 is progressively inactivated L-beta-(2,3-epoxycyclohexyl-4-on)alanine (anticapsin). With increasing concentrations of anticapsin the reaction exhibits rate saturation: the minimum inactivation half-time is 1.15 minutes, with a Kin alpha ct of 2.5 microM. Gl…

Enzyme Catalysis and ImmobilizationChemical Synthesis and AnalysisEnzyme Structure and Function

Blue Phase one : first optical measurements of the order parameter

R. Barbet-Massin、P. Pierański1984-01-01Journal de Physique Lettres

We have recently developed a method of nucleation of large perfect monocrystallites of Blue Phases on glass surfaces. We have obtained spectra of Bragg-reflected light on such crystallites of BPI and show that they can be very easily interpreted in terms of the dynamical theory of light diffraction. From a comparison…

Liquid Crystal Research AdvancementsPhotonic Crystals and ApplicationsNonlinear Optical Materials Studies

The order parameter dependence of the flexoelectric coefficients in nematic liquid crystals

M. A. Osipov1984-01-01Journal de Physique Lettres

Within the general framework of Landau-de Gennes theory for nematic liquid crystals it is shown that the difference of flexoelectric coefficients e* = e1 - e3 ∼ S2 , where S is the nematic order parameter. This result agrees with the molecular theory but is in contradiction with recent measurements of the constant e*…

Liquid Crystal Research AdvancementsForce Microscopy Techniques and ApplicationsAdvanced Materials and Mechanics

Degradation of synthetic oligomers by microorganisms. Part V. Bacterial degradation of 1,4-type polybutadiene.

Akio Tsuchii、Tomoo Suzuki、Seiichi Fukuoka1984-01-01Agricultural and Biological Chemistry

A Moraxella strain capable of utilizing 1, 4-type polybutadiene as a sole source of carbon was isolated from soil. About 40% of polybutadiene having a number average molecular weight (Mn) of 2, 350 was degraded and assimilated by the strain in 5 days. A polybutadiene sample with an Mn of 16, 100, however, was hardly d…

Nanocomposite Films for Food Packagingbiodegradable polymer synthesis and propertiesMicroplastics and Plastic Pollution

The influence of relative humidity in the polymerization of methyl trimethoxy silane

A. Elena Charola、G. E. Wheeler、Guenter Freund1984-01-01Studies in Conservation

(1984). The influence of relative humidity in the polymerization of methyl trimethoxy silane. Studies in Conservation: Vol. 29, Preprints of the Contributions to the Paris Congress, 2-8 September 1984. Adhesives and Consolidants, pp. 177-181.

Synthesis and properties of polymersSilicone and Siloxane ChemistryPhotopolymerization techniques and applications

Neutron diffraction study on U0.5Np0.5O2 at low temperatures

A. Tabuteau、M. Pagés、A. Boéuf 等 7 位作者1984-01-01Journal de Physique Lettres

The results of a neutron diffraction study on U0.5Np0.5 O2 solid solution at low temperature are reported. Below T = 12 K the solid solution is magnetically ordered with a magnetic structure different from that of the UO2 low temperature phase. The temperature dependence of the observed magnetic line width could sugge…

Radioactive element chemistry and processingNuclear Materials and PropertiesNuclear Physics and Applications

The Influence of Alloying Elements on the Electrochemical Behavior of Titanium: A Study of Two Commercial Alloys (TU2, TA6V) in Hydrochloric Acid

J.P. Frayret、A. Caprani、H. Luc 等 4 位作者1984-01-01CORROSION

Stationary behavior is investigated by plotting the stationary polarization curves (I,V) and by examination of the dissolution morphology with scanning microscopy. It is shown that in 4 M deaerated HCl, the TU2 alloy dissolves more rapidly than the unalloyed titanium T40, whereas the TA6V alloy dissolves less rapidly.…

Corrosion Behavior and InhibitionHydrogen embrittlement and corrosion behaviors in metalsNuclear Materials and Properties

A systematic account of the littoral diatoms of the southwest coast of India

C P Gopinathan1984-01-01Eprints@CMFRI Open Access Institutional Repository (Central Marine Fisheries Research Institute)

In this account, a systematic enumeration of 109 littoral and epiphytic diatoms of the south west coast of India is presented. This work forms a supplement to the available information regarding the diatom flora of the Indian Seas.

Diatoms and Algae Research

Novel tin(II) sites in X-ray crystal structures of the tin(II) halide sulphates K3Sn2(SO4)3X (X = Br or Cl)

J. D. Donaldson、Susan M. Grimes1984-01-01Journal of the Chemical Society Dalton Transactions

The crystal structures of K3Sn2(SO4)3X (X = Br or Cl) have been determined by the heavy-atom method and refined by the full-matrix least-squares method to R= 0.0564 for the bromide and 0.0839 for the chloride. The crystals of both compounds are of the hexagonal space group P63(C66, no. 173) with a= 10.256(2), c= 7.582…

Crystal Structures and PropertiesOrganometallic Compounds Synthesis and CharacterizationX-ray Diffraction in Crystallography

Effect of Jamming on Seam Pucker in Plain Woven Fabrics

Peter Schwartz1984-01-01Textile Research Journal

Geometrical relationships between fabric and sewing thread are developed for lock- stitch seams in plain woven fabrics. The tendency to pucker is associated with structural jamming within the fabric. Jamming increases with stitch count and decreases with thread size as reported in earlier studies.

Optical measurement and interference techniquesTextile materials and evaluationsIndustrial Vision Systems and Defect Detection