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Localized relaxation in a glass and the minimum in its orientational polarization contribution

G. P. Johari、G. Power、J. K. Vij2002-07-22The Journal of Chemical Physics

The dielectric permittivity and loss spectra of the glassy state of 5-methyl-2-hexanol obtained by quenching it from the liquid state has been studied. In one experiment, the spectra were studied at different temperatures as the quenched sample was heated at 0.1 K/min from 105.3 to 160.5 K. In the second experiment, t…

Liquid Crystal Research AdvancementsMaterial Dynamics and PropertiesThermodynamic properties of mixtures

Bias effect on the growth of carbon nanotips using microwave plasma chemical vapor deposition

C. L. Tsai、C. F. Chen、Lihai Wu2002-07-22Applied Physics Letters

Carbon nanotips with a high-aspect ratio were directly grown on Pt films. Carbon nanotips grew up to 5.4 μm length and 64 nm diameter under a −120 V bias. Compared to the hollow structure of carbon nanotubes, transmission electron microscopy images indicate its solid body, which is made of graphite. Carbon nanotips po…

Carbon Nanotubes in CompositesGraphene research and applicationsDiamond and Carbon-based Materials Research

Abnormal anti-Stokes Raman scattering of carbon nanotubes

Shulin Zhang、Xinhua Hu、Hongdong Li 等 14 位作者2002-07-22Physical review. B, Condensed matter

Abnormal anti-Stokes Raman scattering (AASR) was unambiguously observed in carbon nanotubes (CNT's). In contrast to traditional Raman scattering theory, the absolute value of the Raman frequency of the anti-Stokes peak is not the same as that of the corresponding Stokes peak. It was demonstrated that AASR scattering o…

Carbon Nanotubes in CompositesGraphene research and applicationsNanopore and Nanochannel Transport Studies

Studies on blends of high‐density polyethylene and polypropylene produced by oscillating shear stress field

Gong Zhang、Qiang Fu、Kaizhi Shen 等 5 位作者2002-07-22Journal of Applied Polymer Science

Abstract Tensile strength and morphology of blends of high‐density polyethylene (HDPE) and polypropylene (PP) obtained by oscillating packing injection molding were investigated via Universal Testing Machine, DSC, and SAXS. Tensile strength is greatly enhanced from 24.5 MPa to more than 90 MPa for pure HDPE and for bl…

Polymer crystallization and propertiesRheology and Fluid Dynamics StudiesPolymer Foaming and Composites

Free radical grafting of itaconic acid and glycidyl methacrylate onto PP initiated by organic peroxides

С. С. Песецкий、B. Jurkowski、О. А. Макаренко2002-07-22Journal of Applied Polymer Science

Abstract Comparative analysis was conducted to learn the grafting of itaconic acid (IA) and glycidyl methacrylate (GMA) onto polypropylene (PP) in the course of reactive extrusion. Seven organic peroxides, which satisfactorily dissolve in PP, but do not dissolve in the monomer, were used to initiate free‐radical react…

Polymer crystallization and propertiesAdvanced Polymer Synthesis and Characterizationbiodegradable polymer synthesis and properties

Synthesis and characterization of starch‐poly(methyl methacrylate) graft copolymers

Meltem Çelık、Mehmet Saçak2002-07-22Journal of Applied Polymer Science

Abstract The graft copolymerization was carried out by methyl methacrylate with starch in which azobisisobutyronitrile was used as an initiator. The grafting reactions were carried out within a 65–95°C temperature range, and the effect of the monomer, initiator concentrations, and the amount of starch on the graft yie…

Advanced Polymer Synthesis and Characterizationbiodegradable polymer synthesis and propertiesElectrospun Nanofibers in Biomedical Applications

Enhanced strain hardening in elongational viscosity for HDPE/crosslinked HDPE blend. I. Characteristics of crosslinked HDPE

Masayuki Yamaguchi、Kenichi Suzuki、Shingo Maeda2002-07-22Journal of Applied Polymer Science

Abstract Blending a crosslinked high‐density polyethylene (xHDPE) enhances melt strength and strain hardening behavior in elongational viscosity of high‐density polyethylene (HDPE) to a great degree. Gel fraction of xHDPE has a stronger effect on the strain hardening than sol fraction, although sol fraction also enhan…

Polymer crystallization and propertiesPolymer Nanocomposites and PropertiesRheology and Fluid Dynamics Studies

Rapid eutectic growth under containerless condition

Xiujun Han、Nan Wang、B. Wei2002-07-22Applied Physics Letters

Rapid eutectic growth in a highly undercooled liquid was accomplished by containerlessly processing Co–Mo eutectic alloy in a drop tube. The containerless state during free fall produces substantial undercoolings up to 391 K (0.24TE) in falling droplets before crystallization. The eutectic growth mechanism is found to…

Aluminum Alloy Microstructure PropertiesSolidification and crystal growth phenomenaBlock Copolymer Self-Assembly

Electronic structure of carbon nanotubes studied by photoelectron spectromicroscopy

Satoru Suzuki、Y. Watanabe、T. Ogino 等 11 位作者2002-07-22Physical review. B, Condensed matter

The electronic structure of multiwalled carbon nanotubes aligned perpendicularly on a Si substrate was studied by means of photoelectron spectromicroscopy. The valence band and the C $1s$ spectra, measured systematically from spatially selected regions along the tube axes, were the fingerprint for lateral variations i…

Carbon Nanotubes in CompositesGraphene research and applicationsChemical and Physical Properties of Materials

Synthesis and properties of waterborne self‐crosslinkable sulfo‐urethane silanol dispersions

Kevin Lewandowski、Larry R. Krepski、Daniel E. Mickus 等 13 位作者2002-07-22Journal of Polymer Science Part A Polymer Chemistry

Abstract A novel type of crosslinkable waterborne polyurethane ionomer was prepared by the acetone process. Two new types of sulfonated diols compatible with this process were synthesized from dimethyl 5‐sodium sulfo isophthalate using a one‐ or two‐stage method. Isocyanate‐terminated polyurethane oligomers were prepa…

Polymer composites and self-healingSynthetic Organic Chemistry MethodsMarine Biology and Environmental Chemistry

Impact‐specific essential work of fracture of maleic anhydride‐compatibilized polypropylene/elastomer blends and their composites

S. C. Tjong、Shiai Xu、Yiu‐Wing Mai2002-07-22Journal of Polymer Science Part B Polymer Physics

Abstract Charpy drop‐weight‐impact and essential work of fracture (EWF) characteristics of maleic anhydride (MA)‐compatibilized styrene–ethylene butylene–styrene (SEBS)/polypropylene (PP) blends and their composites reinforced with short glass fibers (SGFs) were investigated. MA was grafted to either SEBS copolymer (S…

Polymer crystallization and propertiesPolymer Nanocomposites and PropertiesNatural Fiber Reinforced Composites

Synchrotron x-ray scattering studies of water intercalation in a layered synthetic silicate

G. J. da Silva、Jon Otto Fossum、Elaine DiMasi 等 5 位作者2002-07-22Physical review. E, Statistical physics, plasmas, fluids, and related interdisciplinary topics

Synchrotron x-ray diffraction studies were performed on a synthetic layered silicate Fluorohectorite clay. Diffraction patterns along the stacking direction were obtained in surface reflection and bulk transmission geometries on bulk pressed samples under controlled temperature and relative humidity. One-dimensional s…

Concrete and Cement Materials ResearchGlass properties and applicationsClay minerals and soil interactions

Study of domain stability on (Pb0.76Ca0.24)TiO3 thin films using piezoresponse microscopy

Haiyan Guo、Jianbin Xu、I. H. Wilson 等 7 位作者2002-07-22Applied Physics Letters

We introduce a method to investigate the domain stability issue based on piezoresponse microscopy. The switching and back-switching processes of sol–gel derived (Pb0.76Ca0.24)TiO3 thin films were investigated by comparing the local piezoelectric hysteresis loops in continuous mode and pulse mode. It was found that the…

Ferroelectric and Piezoelectric MaterialsAcoustic Wave Resonator TechnologiesAnodic Oxide Films and Nanostructures

Theoretical and experimental study of the intermediate Sm CFI 2* and the Sm CFI 1* phases in antiferroelectric liquid crystals

Mojca Čepič、Ewa Górecka、Damian Pociecha 等 5 位作者2002-07-22The Journal of Chemical Physics

Within the new phenomenological model of antiferroelectric liquid crystals, structures of the two phases, the Sm CFI2* and the Sm CFI1* that appear in the temperature range between the Sm C* and the Sm CA* phase, are found. The structure of the Sm CFI2* and the Sm CFI1* phases is consistent with extensive optical, ele…

Liquid Crystal Research AdvancementsPlant Reproductive BiologyMolecular spectroscopy and chirality

Local environment surrounding magnetic impurity atoms in a structural phase transition of Co-doped TiO2 nanocrystal ferromagnetic semiconductors

Y. L. Soo、Γ. Κιοσέογλου、S. Kim 等 8 位作者2002-07-22Applied Physics Letters

The local environment surrounding magnetic impurity atoms and the host crystal structure of codoped TiO2 (TiO2:Co) nanocrystal ferromagnetic semiconductors have been investigated using the x-ray absorption fine structure and powder diffraction techniques. It has been found that the magnetic Co impurity atoms substitut…

ZnO doping and propertiesQuantum Dots Synthesis And PropertiesCopper-based nanomaterials and applications

Effects of surface waves on the behavior of perfect lenses

Michael W. Feise、Peter J. Bevelacqua、John B. Schneider2002-07-22Physical review. B, Condensed matter

Backwards-wave (BW) materials, which have simultaneously negative permittivity and permeability, support electromagnetic waves with phase propagation in the direction opposite to power flow. At an interface between BW materials and free space, the normal component of the wave vector changes sign. In the case of an eva…

Metamaterials and Metasurfaces ApplicationsElectromagnetic Scattering and AnalysisAdvanced Antenna and Metasurface Technologies

Ultrasonic improvement of the compatibility and rheological behavior of high‐density polyethylene/polystyrene blends

Guangshun Chen、Shaoyun Guo、Huilin Li2002-07-22Journal of Applied Polymer Science

Abstract The effects of ultrasonic oscillations on the rheological behavior, mechanical properties, and morphology of high‐density polyethylene (HDPE)/polystyrene (PS) blends were studied. The experimental results show that the die pressure and apparent viscosity of HDPE/PS blends are remarkably reduced in the presenc…

Polymer crystallization and propertiesRheology and Fluid Dynamics StudiesPolymer Foaming and Composites

Exploring grain size as a cause for “dead-layer” effects in thin film capacitors

L. J. Sinnamon、M. Saad、R. M. Bowman 等 4 位作者2002-07-22Applied Physics Letters

Pulsed laser deposition was used to make a series of Au/Ba0.5Sr0.5TiO3 (BST)/SrRuO3/MgO thin film capacitors with dielectric thickness ranging from ∼15 nm to ∼1 μm. Surface grain size of the dielectric was monitored as a function of thickness using both atomic force microscopy and transmission electron microscopy. Gra…

Ferroelectric and Piezoelectric MaterialsSemiconductor materials and devicesElectronic and Structural Properties of Oxides

Electronic structure, magnetic ordering, and optical properties of GaN and GaAs doped with Mn

E. Kulatov、Hiroshi Nakayama、H. Mariette 等 5 位作者2002-07-22Physical review. B, Condensed matter

The electronic structure and the properties of superdoped GaN(As):Mn (a concentration of Mn from 1.56% to 12.5%) are studied by using the tight-binding linear-muffin-tin-orbital method. Calculations show that the ferromagnetic state is lower in energy than the paramagnetic and antiferromagnetic states for both materia…

ZnO doping and propertiesGaN-based semiconductor devices and materialsMetal and Thin Film Mechanics

Structural characterization of a porous low-dielectric-constant thin film with a non-uniform depth profile

Eric K. Lin、Hae‐Jeong Lee、Gary W. Lynn 等 5 位作者2002-07-22Applied Physics Letters

High-resolution x-ray reflectivity (XR) and small-angle neutron scattering (SANS) are applied to characterize both the nonuniform depth profile and pore structure of a low-dielectric-constant (low-k) thin film as prepared on a silicon substrate. The XR data show that the density depth profile has a multilayered struct…

Advanced ceramic materials synthesisSemiconductor materials and devicesCopper Interconnects and Reliability