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The Charge of Component Layers of Illite-Smectite in Bentonites and the Nature of End-Member Illite

Jan Środoń、E. Zeelmaekers、Arkadiusz Derkowski2009-10-01Clays and Clay Minerals

Abstract The nature of component layers of mixed-layer illite-smectite and their possible evolution in the course of illitization have been debated since the 1960s. The present study is a new attempt to solve these problems, using samples collected from diverse geological formations around the world. Twenty three puri…

Soil and Unsaturated FlowClay minerals and soil interactionsIron oxide chemistry and applications

Lag Periods During the Self-Assembly of {Mo72Fe30} Macroions: Connection to the Virus Capsid Formation Process

Jie Zhang、Dong Li、Guang Liu 等 5 位作者2009-10-01Journal of the American Chemical Society

The kinetic properties of the self-assembly of hydrophilic Keplerate-type polyoxometalate (POM) {Mo(72)Fe(30)} macroanions into single-layer, vesicle-like blackberry structures in solutions were monitored by the static and dynamic laser light scattering techniques. In the presence of additional electrolytes, an obviou…

biodegradable polymer synthesis and propertiesBacteriophages and microbial interactionsNanocluster Synthesis and Applications

Intermediate Temperature Anode‐Supported Fuel Cell Based on BaCe0.9Y0.1O3 Electrolyte with Novel Pr2NiO4 Cathode

Gilles Taillades、Julian Dailly、Mélanie Taillades-Jacquin 等 11 位作者2009-10-01Fuel Cells

Abstract A proton conducting ceramic fuel cell (PCFC) operating at intermediate temperature has been developed that incorporates electrolyte and electrode materials prepared by flash combustion (yttrium‐doped barium cerate) and auto‐ignition (praseodymium nickelate) methods. The fuel cell components were assembled usi…

Advancements in Solid Oxide Fuel CellsFuel Cells and Related MaterialsElectronic and Structural Properties of Oxides

Preparation and Evaluation of CuO/Chitosan Nanocomposite for Antibacterial Finishing Cotton Fabric

Mohamed Gouda、A. Hebeish2009-10-01Journal of Industrial Textiles

Cupric oxide—chitosan nanocomposite was prepared in aqueous solution. Copper ions were adsorbed into the chitosan mainly by chelation to form copper-loaded chitosan. Copper-loaded chitosan was reduced by using sodium hydroxide at specific pH. Copper oxide nanoparticle-loaded chitosan was formed by oxidation of Cu(OH)…

Nanoparticles: synthesis and applicationsNanocomposite Films for Food Packaging

Cancer nanotargeted radiopharmaceuticals for tumor imaging and therapy.

Gann Ting、Chih-Hsien Chang、Hsin‐Ell Wang2009-10-01PubMed

Cancer is the second leading cause of death in the world. Radiolabeled nanocarriers or nanoparticles can be designed and used for cancer diagnostic and therapeutic purposes when tagged with appropriate radionuclides. Current progress in nanotechnology and nanomedicine has exploited the possibility of designing tumor-t…

Nanoparticle-Based Drug DeliveryNanoplatforms for cancer theranosticsRadiopharmaceutical Chemistry and Applications

Chitosan/Sodium Tripolyphosphate Nanoparticles: Preparation, Characterization and Application as Drug Carrier

Wenjing Yang、Fu Jing、Ting Wang 等 4 位作者2009-10-01Journal of Biomedical Nanotechnology

With the existence of amino groups, chitosan (CS) possesses positive charge, so it can self-assemble with tripolyphotspate (TPP) possessing negative charge via ionic gelation. We here synthesized CS/TPP nanoparticles, and then characterized it with the infrared spectra (IR) and scanning electron microscope (SEM) and t…

biodegradable polymer synthesis and propertiesLanthanide and Transition Metal ComplexesPolyoxometalates: Synthesis and Applications

Multistep damage evolution process in cubic zirconia irradiated with MeV ions

S. Moll、L. Thomé、G. Sattonnay 等 7 位作者2009-10-01Journal of Applied Physics

This work reports the study, via the combination of Rutherford backscattering spectrometry and channeling, x-ray diffraction, and transmission electron microscopy experiments, of the damage formation in cubic yttria-stabilized zirconia single crystals irradiated with medium-energy (4 MeV) heavy (Au) ions. The damage b…

Geological and Geochemical AnalysisNuclear materials and radiation effectsElectronic and Structural Properties of Oxides

Enhanced slip on a patterned substrate due to depinning of contact line

Peng Gao、James J. Feng2009-10-01Physics of Fluids

We perform numerical simulations of a shear flow over a periodically patterned substrate with entrapped gas bubbles. A diffuse-interface model is employed to handle the liquid-gas interface deformation and the three-phase contact line. Depending on the shear rate and the pattern geometry, four flow regimes are observe…

Surface Modification and SuperhydrophobicityFluid Dynamics and Heat TransferFluid Dynamics and Thin Films

Nephrogenic Systemic Fibrosis and Its Impact on Abdominal Imaging

Martin R. Prince、Hong Lei Zhang、Joan C. Prowda 等 5 位作者2009-10-01Radiographics

The objective of this article is to review the current knowledge about nephrogenic systemic fibrosis (NSF) and how to prevent it. More than 300 cases of NSF in patients with severe chronic renal insufficiency or acute renal failure or in patients undergoing dialysis have been reported in the peer-reviewed literature,…

Advanced MRI Techniques and ApplicationsLanthanide and Transition Metal ComplexesMRI in cancer diagnosis

Conducting polymers for corrosion protection: a review

Michael Rohwerder2009-10-01International Journal of Materials Research (formerly Zeitschrift fuer Metallkunde)

Abstract Since the first reported publications about their possible application for corrosion protection, conducting polymers are discussed as promising candidates for a new generation of corrosion control coatings. However, although research has started about three decades ago and certainly about a thousand publicati…

Conducting polymers and applicationsElectrochemical Analysis and ApplicationsAnalytical Chemistry and Sensors

Processing and properties of PLA/thermoplastic starch/montmorillonite nanocomposites

O. H. Arroyo、Michel A. Huneault、Basil D. Favis 等 4 位作者2009-10-01Polymer Composites

Abstract Thermoplastic starch (TPS) and polylactic acid (PLA) were compounded with natural montmorillonite (MMT) using a twin‐screw extrusion process to investigate the structure and properties of these nanocomposites and to examine the use of water to enhance clay exfoliation. Tensile and essential work of fracture m…

Nanocomposite Films for Food PackagingPolymer Nanocomposites and Propertiesbiodegradable polymer synthesis and properties

Non-empirical derivation of the parameter in the B88 exchange functional

Peter Elliott、Kieron Burke2009-10-01Canadian Journal of Chemistry

The B88 exchange energy density functional (created by Becke in 1988) is a crucial part of the most popular density functional in use today, B3LYP. B88 contains one empirical parameter which was fitted to Hartree–Fock exchange energies for the noble gas atoms. We show how local approximations to exchange become relati…

Advanced Chemical Physics StudiesBoron and Carbon Nanomaterials ResearchInorganic Chemistry and Materials

Doped Organic Crystals with High Efficiency, Color-Tunable Emission toward Laser Application

Huan Wang、Feng Li、Bing‐Rong Gao 等 13 位作者2009-10-01Crystal Growth & Design

Doping an organic crystal such as an inorganic semiconductor without having a bad influence on crystalline quality is a very difficult task because weak intermolecular interactions and lattice mismatches exist in organic condensed states. We report here the successful growth of tetracene and pentacene-doped trans -1,4…

Organic Electronics and PhotovoltaicsOrganic Light-Emitting Diodes ResearchLuminescence and Fluorescent Materials

Lower limit to the lattice thermal conductivity of nanostructured Bi2Te3-based materials

Catalin Chiritescu、Clay Mortensen、David G. Cahill 等 5 位作者2009-10-01Journal of Applied Physics

We investigate the lower limit to the lattice thermal conductivity of Bi2Te3 and related materials using thin films synthesized by the method of elemental reactants. The thermal conductivities of single layer films of (Bi0.5Sb0.5)2Te3 and multilayer films of (Bi2Te3)m(TiTe2)n and [(BixSb1−x)2Te3]m(TiTe2)n are measured…

Advanced Thermoelectric Materials and DevicesThermal properties of materialsThermal Radiation and Cooling Technologies

Characterization of Quantum Dot/Conducting Polymer Hybrid Films and Their Application to Light‐Emitting Diodes

Jeonghun Kwak、Wan Ki Bae、Matthias Zorn 等 13 位作者2009-10-01Advanced Materials

Quantum dot/conducting polymer hybrid films are used to prepare light-emitting diodes (LEDs). The hybrid films (CdSe@ZnS quantum dots excellently dispersed in a conducting polymer matrix, see figure) are readily prepared by various solution-based processes and are also easily micropatterned. The LEDs exhibit a turn-on…

Perovskite Materials and ApplicationsQuantum Dots Synthesis And PropertiesConducting polymers and applications

Electrospinning-aligned and random polydioxanone–polycaprolactone–silk fibroin-blended scaffolds: geometry for a vascular matrix

Michael J. McClure、Scott A. Sell、Chantal E. Ayres 等 5 位作者2009-10-01Biomedical Materials

Extracellular matrices are arranged with a specific geometry based on tissue type and mechanical stimulus. For blood vessels in the body, preferential alignment of fibers is in the direction of repetitive force. Electrospinning is a controllable process which can result in fiber alignment and randomization depending o…

Electrospun Nanofibers in Biomedical ApplicationsSilk-based biomaterials and applicationsTissue Engineering and Regenerative Medicine

Collagen and Glycosaminoglycans of Wharton’s Jelly

Krzysztof Sobolewski、E Bańkowski、L Chyczewski 等 4 位作者2009-10-01Biology of the Neonate

In this study, we report quantity, solubility and molecular polymorphism of collagen, proportional relationships between various types of collagen, ultrastructure of collagen fibres, the amounts of various glycosaminoglycans (GAGs) and proportional relationships between them in Wharton's jelly of normal umbilical cord…

Proteoglycans and glycosaminoglycans researchDermatologic Treatments and ResearchCollagen: Extraction and Characterization

Mortar and Paste Rheology: Concentration, Polydispersity and Air Entrapment at High Solid Fraction

Hendrickx Roel、Rezeau Martin、Van Balen Koenraad 等 4 位作者2009-10-01Applied Rheology

Rheological characterisation of mortar is complicated by phenomena of slip, the formation of shear bands and depletion. At relatively low solid fractions a typical Couette geometry and a medium-size mixer-type rheometer were used to determine flow curves. At higher solid fractions a large-size coaxial cylinder rheomet…

Intrinsic Viscosity Determination by “Single-Point” and “Double-Point” Equations

Curvale Rolando Antonio、Cesco Juan Carlos2009-10-01Applied Rheology

“Single-point” equations used for intrinsic viscosity determination are greatly used when working with synthetic polymer solution systems. In this work we have applied them to a biological macromolecule in a bovine serum albumin (BSA)/water system. Almost all single-point equations are available and errors can be lowe…

Adhesive and Rheological Properties of Mortar Joints

Kaci A.、Bouras R.、Chaouche M. 等 5 位作者2009-10-01Applied Rheology

Adhesive properties of fresh mortar joints containing different dosage rates of a water-soluble polymer (cellulose ether based) are investigated using the probe tack test. This test consists of measuring the evolution of the normal force required to separate at a given velocity two plates between which a thin layer of…