Materials Literature
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Soda‐silica and soda‐lime‐silica glasses were prepared with varying amounts of Si 3 N 4 , to produce oxynitride glasses with nitrogen contents up to 3.23 mol%. The glasses were analyzed by Fourier transform infrared spectroscopy and X‐ray photoelectron spectroscopy, and evidence for the formation of tricoordinated nit…
Abstract Solid-state 29 Si and 27 Al NMR spectroscopy with magic-angle spinning was used to study two smectites, two illites and a vermiculite. 27 Al NMR was able to directly observe the coordination of aluminium. 29 Si NMR was sensitive to both the chemical nature of the interlayer species and the presence of alumini…
Four series of polyurethane elastomers were synthesized using diphenylmethane diisocyanate (MDI) and castor oil as the polyol. Two types of MDI (crude and distilled) were used. The temperature of reaction and the effect of excess isocyanate above stoichiometric were also varied. The structure of the polyurethanes was…
The vacuoles of Neurospora crassa, grown in minimal medium, contain a 1:1 ratio of basic amino acids and phosphate, the latter in the form of long-chain, inorganic polyphosphate-P. Vacuoles isolated from cells depleted of polyphosphate retain basic amino acids despite the absence of over 90% of their polyphosphate. Th…
Abstract 1 H and 13 C NMR studies on magnesium anthracene ⋅ 3 THF ( 2a ), which can be recrystallized from THF, indicate that magnesium has the strongest interaction with the 9,10‐positions of anthracene. While the rate of formation of 2a from magnesium and anthracene in THF at 60°C is proportional to both anthracene…
The glass‐transition temperature ( T g ) is a fundamental property of all organic binders, It is illustrated with polyethylene glycol (PEG)‐plasticized polyvinyl alcohol (PVA) binder systems that densification is enhanced when the binder T g , is below the pressing temperature. This is a result of the increased deform…
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTElectronic structures of transition-metal tetrachalcogenides (MSe4)nI (M = Nb, Ta)Pascal Gressier, Myung Hwan Whangbo, Alain Meerschaut, and Jean RouxelCite this: Inorg. Chem. 1984, 23, 9, 1221–1228Publication Date (Print):April 1, 1984Publication History Published online1 M…
The temperature dependence of the pyroelectric coefficient γd of (Na½Bi½)TiO3 ceramics has been measured. It was found that this crystal is a perspective material for using as a sensitive element of the pyroelectric radiation detectors steadily working in the temperature range of ∽ 20—60°C (γd = 2.5 ' 10-8C cm-2 °C-1;…
Abstract The creep behavior of ultrahigh‐modulus polyethylene monofilaments has been studied over the temperature range 20–70°C. A wide range of samples was examined in an attempt to determine the influence of draw ratio, molecular weight, copolymerization, and crosslinking by γ irradiation Prior to drawing. Results a…
Angle-resolved ultraviolet photoemission spectroscopy (ARUPS) has been used to study the p(2×1) oxygen-induced reconstruction of Cu(110). While there is agreement between experimental groups that the O atoms sit in the long-bridge site along the 〈001〉 Cu directions, there are two proposed models for the reconstruction…
Abstract Thin films of polystyrene (PS) are bonded to copper grids and crosslinked with electron irradiation. When the films are strained in tension regions of local plastic deformation, either crazed or plane stress deformation zones (DZs), nucleate and grow from dust particles. the nature of the local deformation, a…
ADVERTISEMENT RETURN TO ISSUEPREVArticleNovel triicosahedral structure of the largest metal alloy cluster: hexachlorododecakis(triphenylphosphine)-gold-silver cluster [(Ph3P)12Au13Ag12Cl6]m+Boon K. Teo and Kelly KeatingCite this: J. Am. Chem. Soc. 1984, 106, 7, 2224–2226Publication Date (Print):April 1, 1984Publicatio…
A new method has been developed to study non-equilibrium transport and energy relaxation phenomena in disordered organic and inorganic semiconductors. Given a distribution of localized states, the mean-square displacement and average energy of the excitation may be evaluated as functions of initial energy and time. Th…
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTPhase transformations of liquid crystalline side-chain oligomersH. Stevens, G. Rehage, and H. FinkelmannCite this: Macromolecules 1984, 17, 4, 851–856Publication Date (Print):April 1, 1984Publication History Published online1 May 2002Published inissue 1 April 1984https://pub…
Alkali metals adsorbed on transition metal surfaces do not only change the electronic properties of these metals but alter also their chemical reactivity. This effect is well known in heterogeneous catalysis as the promotion of metallic catalysts by alkali additives. The more fundamental physics of this effect is bein…
Lower critical solution temperature (LCST) behavior in polymer blends is shown to be the result of the compressible nature of the system, the directional-specific character of the intermolecular interactions, or a combination of both. Certain random copolymer-homopolymer blends are examples of the first possibility. T…
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTRedox conduction in single and bilayer films of redox polymerP. G. Pickup, W. Kutner, C. R. Leidner, and Royce W. MurrayCite this: J. Am. Chem. Soc. 1984, 106, 7, 1991–1998Publication Date (Print):April 1, 1984Publication History Published online1 May 2002Published inissue 1…
A search has been made for regional differences in macromolecular synthesis in the axolotl embryo at a stage when the principal regions have become determined but terminal differentiation has not yet begun. The epidermis of the neurula makes a number of abundant proteins which are not made elsewhere. Some of these are…
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTConcentration dependent relaxation times of linear polymers in dilute solutionsM. MuthukumarCite this: Macromolecules 1984, 17, 4, 971–973Publication Date (Print):April 1, 1984Publication History Published online1 May 2002Published inissue 1 April 1984https://pubs.acs.org/do…
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTOne- and two-electron reduction of aluminum and tin pyridylporphyrins. A kinetic spectrophotometric studyS. Baral, P. Hambright, and P. NetaCite this: J. Phys. Chem. 1984, 88, 8, 1595–1600Publication Date (Print):April 1, 1984Publication History Published online1 May 2002Pub…