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Synthesis, structure, and magnetic properties of fluoride-bridged copper(II) dimers. Crystal and molecular structures of bis(.mu.-fluoro)bis[tris(3,4,5-trimethylpyrazole-N2)copper(II)] bis(tetrafluoroborate) and bis(.mu.-fluoro)bis[(5-methylpyrazole-N2)bis(3,5-dimethylpyrazole-N2)copper(II)] bis(tetrafluoroborate)

Frederik J. Rietmeijer、R. A. G. de Graaff、J. Reedijk1984-01-01Inorganic Chemistry

ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTSynthesis, structure, and magnetic properties of fluoride-bridged copper(II) dimers. Crystal and molecular structures of bis(.mu.-fluoro)bis[tris(3,4,5-trimethylpyrazole-N2)copper(II)] bis(tetrafluoroborate) and bis(.mu.-fluoro)bis[(5-methylpyrazole-N2)bis(3,5-dimethylpyrazo…

Metal complexes synthesis and propertiesMagnetism in coordination complexesLanthanide and Transition Metal Complexes

The Adsorption and Reaction of Decomposition Products of Zinc Di-Isopropyldiophosphate on Steel

C. H. Bovington、B. Dacre1984-01-01A S L E Transactions

Rates of adsorption and desorption, of di-isopropyldithiophosphoric acid and tetraisopropylthioperoxydiphosphate from hexade-cane on to steel, have been measured wing 14C radiolabelled compounds. Concentration, temperature, and stirring dependence have been examined. The adsorption is surface controlled and the kineti…

Corrosion Behavior and InhibitionLubricants and Their Additives

Polarization colours of collagen fibres: a sign of collagen production activity in fibrotic processes.

M Szendröi、Gábor Vajta、Lajos Kovács 等 5 位作者1984-01-01PubMed

The maturation process of collagen fibres was investigated by the picro-sirius red/polarization light technique in experimental wound healing, in allyl-alcohol induced subacute and chronic liver fibrosis and in human biopsy material. Evidence was obtained that collagen fibres undergo a rapid maturation in fibrotic pro…

Collagen: Extraction and CharacterizationBone and Dental Protein Studies

Pitting Corrosion on Zirconium—A Review

Donald R. Knittel、Arturo Bronson1984-01-01CORROSION

A review is presented on the pitting corrosion of zirconium and Zr alloys when immersed in aqueous solutions at temperatures less than 100 C. The electrochemical methods (potentiokinetic, potentiostatic, and scratch) used to evaluate pitting susceptibility are described briefly. Zirconium is susceptible to pitting in…

Fusion materials and technologiesHydrogen embrittlement and corrosion behaviors in metalsNuclear Materials and Properties

Crystallography of the foliated calcite shell layers of bivalve molluscs

Bruce Runnegar1984-01-01Alcheringa An Australasian Journal of Palaeontology

The foliated calcite of living scallops (Pectinacea), oysters (Ostreacea), window-pane and jingle shells (Anomiacea) consists of approximately 250 nm thick sheets (folia) formed of subparallel laths joined laterally. The surfaces of these very thin folia are not the basal pinacoid of calcite (0001), as has previously…

Marine Bivalve and Aquaculture StudiesCalcium Carbonate Crystallization and InhibitionMollusks and Parasites Studies

Erosion Process of a Glassionomer Cement in Organic Acids

Shigeki Matsuya、Yohko Matsuya、Yasushi YAMAMOTO 等 4 位作者1984-01-01Dental Materials Journal

Erosion of a glass ionomer cement in acetic (AA), lactic (LA), citric (CA) and hydrochloric acids (HA) was investigated by means of chemical analysis, SEM observation and infrared (IR) spectroscopy.The larger stability constants of the complex between the acid anions and Al or Ca, or the lower the pH of the acid solut…

Glass properties and applicationsBuilding materials and conservationSilicone and Siloxane Chemistry

Decomposition of Mn–C Dipoles during Quench-Ageing in Low-Carbon Aluminium-Killed Steels

Hideo Abe、Takeshi Suzuki、Susumu Okada1984-01-01Transactions of the Japan Institute of Metals

Variations in the electrical resistivity and in the deviation from Matthiessen’s rule (DMR) during quench-ageing have been observed on low-carbon aluminium-killed steels containing varied amounts of manganese. The DMR is measured by the difference between the resistivities at 273 K and at the liquid-nitrogen temperatu…

Microstructure and Mechanical Properties of SteelsMetallurgical Processes and ThermodynamicsMagnetic Properties and Applications

First use of GdDTPA/dimeglumine in man.

Michael Laniado、Hanns‐Joachim Weinmann、W. Schörner 等 5 位作者1984-01-01PubMed

The dimeglumine salt of the Gd-DTPA complex has a strong paramagnetic effect and a very low toxicity in animals. This report of its use in human volunteers confirms its low toxicity and indicates its usefulness in the enhancement of signal intensity of the kidney and bladder.

Lanthanide and Transition Metal Complexes

Self-diffusion of water at the protein surface: a measurement

Carl F. Polnaszek、R. G. Bryant1984-01-01Journal of the American Chemical Society

ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTSelf-diffusion of water at the protein surface: a measurementC. F. Polnaszek and R. G. BryantCite this: J. Am. Chem. Soc. 1984, 106, 2, 428–429Publication Date (Print):January 1, 1984Publication History Published online1 May 2002Published inissue 1 January 1984https://pubs.a…

Material Dynamics and PropertiesElectrostatics and Colloid InteractionsChemical and Physical Studies

Crystallography of Stress Corrosion Cracking in Pure Magnesium

Efstathios I. Meletis、R. F. Hochman1984-01-01CORROSION

A crystallographic characterization study has been made of the transgranular stress corrosion cracking in pure Mg tested at room temperature in aqueous NaCl-K2CrO4. Selected area electron channeling and photogrammetry were used to determine the cracking orientation. The fracture surfaces consisted of flat parallel {22…

Corrosion Behavior and InhibitionMetal and Thin Film MechanicsMagnesium Alloys: Properties and Applications

The identification and X-ray structure of the diphosphatotris(nonatungstophosphato)nonacobaltate(II) heteropolyanion

T.J.R. Weakley1984-01-01Journal of the Chemical Society Chemical Communications

The P5Co9W27O119H1716– anion has 3/m symmetry, and contains nine CoO6 octahedra sharing oxygen atoms with one another and with three α-B PW9O34 moietries and two PO4 groups.

Metal-Organic Frameworks: Synthesis and ApplicationsPolyoxometalates: Synthesis and ApplicationsChemical Synthesis and Characterization

Structural characterisation of [Au10Cl3(PCy2Ph)6](NO3)(Cy = cyclohexyl) and the development of a structural principle for high nuclearity gold clusters

Clive E. Briant、Kevin P. Hall、Alison Wheeler 等 4 位作者1984-01-01Journal of the Chemical Society Chemical Communications

[Au10Cl3(PCy2Ph)6](CO3) which has been synthesised in low yield from Au(NO3)(PCy2Ph) and NaBH4 has a toroidal geometry based on a hexagonal ring of edge- and face-sharing tetrahedra which share a common central vertex.

Organometallic Complex Synthesis and CatalysisNanocluster Synthesis and ApplicationsInorganic Chemistry and Materials

Liposomes as drug carriers in cancer therapy.

John N. Weinstein1984-01-01PubMed

Liposomes, microscopic particles composed of lipid bilayer membranes, can carry water-soluble drugs in their aqueous compartments and lipid soluble drugs in their bilayers. Over the last 10 years, they have been studied more intensively than any other type of drug carrier. The first impulse, as with other pharmaceutic…

Nanoparticle-Based Drug Delivery

Early steps in the free radical polymerisation of 3,4-dihydroxyphenylalanine (dopa) into malanin

Miles R. Chedekel、Edward J. Land、Ambler Thompson 等 4 位作者1984-01-01Journal of the Chemical Society Chemical Communications

Pulse radiolysis and flash photolysis-initiated one-electron oxidation of 3,4-dihydroxyphenylalanine (dopa) and other catecholamines have allowed the direct measurement of the kinetics of semiquinone disproportionation leading successively to the corresponding melanin precursors dopaquinones and dopachromes.

melanin and skin pigmentationDyeing and Modifying Textile FibersPhotochromic and Fluorescence Chemistry

5—FABRIC SOFTNESS, HANDLE, AND COMPRESSION

H. M. Elder、Stephen Fisher、K.B. Armstrong 等 4 位作者1984-01-01Journal of the Textile Institute

The result of subjective finger-pressure assessments of fabric softness are compared with objective measurements of compression. Good correlation between them is reported for a set of non-woven and a set of woven fabrics. Relations between the touch, compressibility, mass, thickness, density, and specific volume of th…

Mechanical Behavior of CompositesTextile materials and evaluationsMaterial Properties and Processing

Kinetics of polymorphic solid-state transformations

P T Cardew、Roger J. Davey、Andrew Ruddick1984-01-01Journal of the Chemical Society Faraday Transactions 2 Molecular and Chemical Physics

Solid-state polymorphic transformations can have a profound influence on the processing and storage of some crystalline powders. Using classical models of nucleation and growth a framework is developed which highlights the importance of crystal size on the transformation rate. A key parameter in this theory is the rat…

Energetic Materials and CombustionCrystallization and Solubility StudiesThermal and Kinetic Analysis

L-Sorbose metabolism in Klebsiella pneumoniae and Sor+ derivatives of Escherichia coli K-12 and chemotaxis toward sorbose

Georg A. Sprenger、J W Lengeler1984-01-01Journal of Bacteriology

L-Sorbose degradation in Klebsiella pneumoniae was shown to follow the pathway L-sorbose leads to L-sorbose-1-phosphate leads to D-glucitol-6-phosphate leads to D-fructose-6-phosphate. Transport and phosphorylation of L-sorbose was catalyzed by membrane-bound enzyme IIsor of the phosphoenolpyruvate-dependent carbohydr…

Metabolism and Genetic DisordersEnzyme Structure and FunctionAmino Acid Enzymes and Metabolism

In vivo measurement of regional brain tissue pH using positron emission tomography

David A. Rottenberg、James Z. Ginos、Kimberlee J. Kearfott 等 5 位作者1984-01-01Annals of Neurology

Carbon-11-labeled dimethyloxazolidinedione ([11C]DMO) was injected intravenously into human subjects, and serial positron emission tomographic (PET) scans were obtained until brain-blood equilibration was achieved or could be accurately predicted from dynamic PET and 11C blood data. Knowledge of regional brain-blood p…

Medical Imaging Techniques and ApplicationsTraumatic Brain Injury and Neurovascular DisturbancesLanthanide and Transition Metal Complexes

Luminescence of Pb2+ Centers in SrS and SrSe Phosphors

Nobuhiko Yamashita、Takaharu Ohira、Hitoshi Mizuochi 等 4 位作者1984-01-01Journal of the Physical Society of Japan

The emission and excitation spectra of the SrS: Pb 2+ and SrSe: Pb 2+ phosphors were measured at low temperatures. The 3 A 1u → 1 A 1g emission band at 374 or 392 nm is observed at 80 K in addition to the 3 T 1u → 1 A 1g emission band at 368 or 383 nm for SrS: Pb 2+ or SrSe: Pb 2+ , respectively. On these emission ban…

Luminescence Properties of Advanced MaterialsRadiation Detection and Scintillator TechnologiesSolid-state spectroscopy and crystallography