Materials Literature
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This investigation is concerned with the effect of thiophene monomer structures on the electrochemical behavior and physical characteristics of electropolymerized poly(thiophenes) and various poly(3‐methylthiophenes). These variations in polymer structure were achieved by employing thiophene and 3‐methylthiophene olig…
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTAnionic ring-opening polymerization of sila- and germacyclopent-3-enesXuehai Zhang, Qingshan Zhou, William P. Weber, Raymond F. Horvath, T. H. Chan, and Georges ManuelCite this: Macromolecules 1988, 21, 6, 1563–1566Publication Date (Print):June 1, 1988Publication History Pub…
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTUV-visible and carbon NMR studies of chloroquine binding to urohemin I chloride and uroporphyrin I in aqueous solutionsI. Constantinidis and James D. SatterleeCite this: J. Am. Chem. Soc. 1988, 110, 13, 4391–4395Publication Date (Print):June 1, 1988Publication History Publis…
The magnetic susceptibilities of a large number of ternary oxides of copper having structural features common to the presently identified phases of high-temperature superconductors have been studied in the temperature range 14-300 K. The systems studied are Ln2CuOP( Ln = La, Pr, Nd, etc.), Sr2CuO2CI2,B i2Cu0,, Ca2Cu03…
The density of dependence of the static structure factor S(Q) of liquid-like ordered colloidal suspensions is investigated by light scattering techniques. We found that variation of the particle number density even by a factor of 8 produced only a modest change of the height of the first peak of S(Q). In order to obta…
High‐purity mullite‐SiC‐whisker composites and mullite‐ZrO 2 ‐SiC‐whisker composites were fabricated in situ by hot‐pressing using a matrix prepared by the alkoxide process. Varying degrees of ZrO 2 stabilization were achieved by varying amounts of Y 2 O 3 or MgO addition. Microstructural characterization was accompli…
Abstract Poly(β‐hydroxyalkanoates) are nature's high molecular weight thermoplastic polyesters. They occur as storage granules in a variety of bacteria. From a plastics, film, and fibres perspective, the statistically random copolyesters based on β‐hydroxybutyrate (HB) and β‐hydroxyvalerate (HV) repeating units have h…
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTEvidence for activation of the carbon-oxygen bond of methanol on the palladium(111) surface after low temperature adsorptionRobert J. Levis, Jiang. Zhicheng, and Nicholas. WinogradCite this: J. Am. Chem. Soc. 1988, 110, 13, 4431–4432Publication Date (Print):June 1, 1988Publi…
The energy transfer protein, green fluorescent protein, from the hydromedusan jellyfish Aequorea victoria has been crystallized in two morphologies suitable for x-ray diffraction analysis. Hexagonal plates have been obtained in the P6122 or P6522 space group with a = b = 77.5, c = 370 A, and no more than three molecul…
A method is presented of using the known Green functions or densities of states (DOS) for a given Hamiltonian H to find Green functions or DOS for any lattice Hamiltonian ${H}_{e}$ in the algebra of H, or ${H}_{e}$=f(H). The procedure is further developed to permit using the known Green functions and DOS of two Hamilt…
Abstract Quantum yields of photoreactions of furylfulgides having Me, Et, n-Pr, or i-Pr on the furylalkylidene moiety were measured. The E–Z isomerization was greatly suppressed and the cyclization was accelerated when the alkyl group (R) became bulkier. When R was i-Pr, no E–Z isomerization was observed and the quant…
Photoelectrochemical techniques have become increasingly popular for in situ measurements related to corrosion studies and have provided a new insight into the electronic structure of passive films. Photoelectrochemical studies of the passive film formed on iron in neutral solutions are presented. The electronic prope…
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTAssociation, photodimerization, and induced-fit types of host-guest complexation of anthracene-appended .gamma.-cyclodextrin derivativesAkihiko. Ueno, Fumio. Moriwaki, Tetsuo. Osa, Fumio. Hamada, and Koichi. MuraiCite this: J. Am. Chem. Soc. 1988, 110, 13, 4323–4328Publicati…
The construction of interpenetrating networks is the fascinating possibility of‐fered by tetracarboxylic acids containing tetrahedrally directed carboxyl groups. In the crystal they can form concatenated, diamondoid networks held together by pairs of hydrogen bonds. The cavities are filled owing to the interpenetratio…
We discuss the dynamics of the formation of liquid crystalline phase of rod-like polymer solutions, particularly the behavior of spinodal decomposition which should be observed when the system is suddenly brought into a thermodynamically unstable region. The growth rate of the concentration fluctuation is calculated a…
MERLOT is an integrated package of computer programs for the determination of initial models of crystal structures using the molecular replacement technique. The package includes two programs for calculating the rotation function, three methods for solving the translation problem (a translation function, a packing fun…
The intrasubband collective excitations in semiconductor superlattice systems have been investigated within a simple model theory with the use of a two-dimensional δ function for the charge-density profiles. In particular, the coupling of the plasmons to the LO (longitudinal optical) phonons is accounted for. The coup…
The NAD-dependent glutamate dehydrogenase from Phycomyces spores was purified more than 300-fold. Estimation of Mr by gel filtration gave a value of 98,000 whereas after SDS-PAGE one major band of Mr 54,000 was found, suggesting that the enzyme is a dimer. The enzyme was virtually dependent on the presence of AMP for…
Following the idea of performing tests in environmental conditions as similar as possible to the real working ones, many sets of partial discharge tests carried out on an epoxy resin within a broad environmental temperature range are reported on. Life tests were carried out on specimens with a calibrated, enclosed cav…
The luminescence and energy transfer properties of the system Gd 1 − x Eu x ( IO 3 ) 3 ( 0.005 ⩽ x ⩽ 1 ) have been investigated. In Eu ( IO 3 ) 3 diffusion limited energy migration occurs at T > 25 K . The diffusion constant has only a weak temperature dependence. The IO 3 − group does not luminesce. A comparison is m…