Materials Literature
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The structural role of Mn was investigated in a relatively simple non-stoichiometric lithium disilicate (Li2Si2O5) based glass composition. Glasses were prepared by partially replacing SiO2 by MnO2 from the base glass belonging to the system Li2O–K2O–Al2O3–SiO2. An overall depolymerization of the glass network was obs…
Porous microfibrous-structured ZSM-5 membrane catalyst possesses excellent catalytic activity and stability.
Composite nanostructures of tungsten oxide and polyaniline (PANI) were fabricated on carbon electrode by electrocodeposition using sodium dodecylbenzene sulfonate (SDBS) as the template. The morphology of the composite can be controlled by changing SDBS surfactant and aniline monomer concentrations in solution. With i…
H NMR and FT-IR analyses, while the molecular weights and molecular weight distributions were measured by gel permeation chromatography (GPC). The micelles self-assembled from these block copolymers could simultaneously encapsulate anti-cancer drug doxorubicin (DOX) and DNA to form a micelleplex with the hydrophilic b…
The inhibition of corrosion on AA2024-T351 in NaCl solutions, mitigated by either in-situ permanganate ions (MnO 4 − ) or permanganate pretreatment, was examined. Both room temperature pretreatment and solution phase additions were studied as a function of inhibitor concentration. The roles of the inhibitor during ano…
Molecular imaging is utilised in modern medicine to aid in the diagnosis and treatment of disease by allowing its spatiotemporal state to be examined in vivo. This study focuses on the development of novel multimodal molecular imaging agents based on hyperbranched polymers that combine the complementary capabilities o…
and MRSA at concentrations as low as 0.1 mg NP per ml consistent with an antibiotic load of 1-2% w/w as determined through TGA. No antimicrobial activity was exhibited by the unconjugated nanoparticles. The release of gentamicin from the conjugates was monitor in buffer solutions at pH = 7 and the antibiotic concentra…
The lack of a fibrocartilage layer between graft and bone remains the leading cause of graft failure after anterior cruciate ligament (ACL) reconstruction. The objective of this study was to develop a gene-modified silk cable-reinforced chondroitin sulfate-hyaluronate acid-silk fibroin (CHS) hybrid scaffold for recons…
Introducing electron-withdrawing groups into BODIPY enhanced <sup>1</sup> O <sub>2</sub> sensitization properties, promoted intense light-harvesting ability and significantly improved the photostability of SOPs in aqueous solution.
3-D bouquets of nickel hydroxide nitrate were processed into high surface area electrodes for supercapacitor applications.
Biosynthesis of silver nanoparticles (AgNPs) was achieved using extract of Chenopodium ambrosioides as a reducer and coating agent at room temperature (25°C). Two molar solutions of AgNO 3 (1 mM and 10 mM) and five extract volumes (0.5, 1, 2, 3, and 5 mL) were used to assess quantity, shape, and size of the particles.…
Herein we demonstrated the effect of oligomer chain length on the electropolymerization and properties of the resulting polyfuran films.
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The use of Rosmarinus officinalis as a corrosion inhibitor for 1018 carbon steel in 0.5 M H2SO4 has been evaluated by using weight loss, potentiodynamic polarization curves and electrochemical impedance spectroscopy techniques at 25°. Inhibitor concentrations were included within the range between 0 and 1000 ppm C usi…
Open structures can display a number of unusual properties, including a negative Poisson's ratio, negative thermal expansion, and holographic elasticity, and have many interesting applications in engineering. However, it is a grand challenge to self-assemble open structures at the colloidal scale, where short-range in…
Density functional theory (DFT) calculations were employed to investigate the energetics of carbon dioxide migration within hydrated or anhydrous graphene oxides (GOs). When anhydrous GO structures contain a carbon dioxide molecule, the carbon dioxide interacts repulsively with the GO layers to increase the interlayer…
Rotational molding of foamed polyethylene has increasingly become an important process in industry because of its thicker walls, low sound transfer, high stiffness and good thermal insulation. However, the foaming process of polyethylene during rotational molding has not been well studied. The focus of thisarticle is…
An efficient and green dimeric BODIPY-catalyzed sulfide oxidation under visible light is described.
An efficient, high-yielding route to β-methyl-α-methylene-γ-butyrolactone (βMMBL)—a monomer for the production of high-performance engineering bioplastics—from biorenewable and inexpensive itaconic acid has been developed. The monomer prepared by this new route is of high purity as isolated without purification, as ev…
We prepared crystalline [RE(III)(hfac)3(TEMPO)2] (RE = Gd, La, Y), where TEMPO and hfac stand for 2,2,6,6-tetramethylpiperidin-1-oxyl and 1,1,1,5,5,5-hexafluoropentane-2,4-dionate, respectively. The X-ray crystal structure of TEMPO-coordinated RE compounds was determined for the first time. The Gd and Y analogues are…