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Role of Metal–Support Interactions, Particle Size, and Metal–Metal Synergy in CuNi Nanocatalysts for H2 Generation

Hoang Yen、Yongbeom Seo、Serge Kaliaguine 等 4 位作者2015-08-07ACS Catalysis

Efficient bimetallic nanocatalysts based on non-noble metals are highly desired for the development of new energy storage materials. In this work, we report a simple method for the synthesis of highly dispersed CuNi catalysts supported on mesoporous carbon or silica nanospheres using low-cost metal nitrate precursors.…

Hydrogen Storage and MaterialsAmmonia Synthesis and Nitrogen ReductionNanomaterials for catalytic reactions

Nanometre-scale probing of spin waves using single electron spins

Toeno van der Sar、Francesco Casola、Ronald L. Walsworth 等 4 位作者2015-08-07Nature Communications

Pushing the frontiers of condensed-matter magnetism requires the development of tools that provide real-space, few-nanometre-scale probing of correlated-electron magnetic excitations under ambient conditions. Here we present a practical approach to meet this challenge, using magnetometry based on single nitrogen-vacan…

Diamond and Carbon-based Materials ResearchForce Microscopy Techniques and ApplicationsElectronic and Structural Properties of Oxides

About quantitative EBSD analysis of deformation and recovery substructures in pure Tantalum

Charbel Moussa、Marc Bernacki‫、Rémy Besnard 等 4 位作者2015-08-07IOP Conference Series Materials Science and Engineering

The aim of this work is to present a quantitative analysis of features involved in recovery during annealing of deformed Tantalum.In pure metals where crystalline defects usually have high mobility, dislocation annihilation and rearrangement occur to a great extent prior to recrystallization.Therefore a complete under…

Microstructure and mechanical propertiesMicrostructure and Mechanical Properties of SteelsAdvanced Materials Characterization Techniques

Stretchable and Conductive Polymer Films Prepared by Solution Blending

Pengcheng Li、Kuan Sun、Jianyong Ouyang2015-08-07ACS Applied Materials & Interfaces

Stretchable and conductive materials can have important application in many areas, such as wearable electronics and healthcare devices. Conducting polymers have very limited elasticity because of their rigid conjugated backbone. In this work, highly stretchable and conductive polymer films are prepared by coating or c…

Advanced Sensor and Energy Harvesting MaterialsConducting polymers and applicationsPolymer Nanocomposite Synthesis and Irradiation

Nanodiamonds: The intersection of nanotechnology, drug development, and personalized medicine

Dean Ho、Chung-Huei Katherine Wang、Edward Kai‐Hua Chow2015-08-07Science Advances

The implementation of nanomedicine in cellular, preclinical, and clinical studies has led to exciting advances ranging from fundamental to translational, particularly in the field of cancer. Many of the current barriers in cancer treatment are being successfully addressed using nanotechnology-modified compounds. These…

Nanoparticle-Based Drug DeliveryDiamond and Carbon-based Materials ResearchGraphene and Nanomaterials Applications

Linear Scaling of the Exciton Binding Energy versus the Band Gap of Two-Dimensional Materials

Jin‐Ho Choi、Ping Cui、Haiping Lan 等 4 位作者2015-08-07Physical Review Letters

The exciton is one of the most crucial physical entities in the performance of optoelectronic and photonic devices, and widely varying exciton binding energies have been reported in different classes of materials. Using first-principles calculations within the GW-Bethe-Salpeter equation approach, here we investigate t…

Graphene research and applications2D Materials and ApplicationsGa2O3 and related materials

Germanium-Vacancy Single Color Centers in Diamond

Takayuki Iwasaki、Fumitaka Ishibashi、Yoshiyuki Miyamoto 等 16 位作者2015-08-07OpenAlex

Atomic-sized fluorescent defects in diamond are widely recognized as a promising solid state platform for quantum cryptography and quantum information processing. For these applications, single photon sources with a high intensity and reproducible fabrication methods are required. In this study, we report a novel colo…

Diamond and Carbon-based Materials ResearchIon-surface interactions and analysisElectronic and Structural Properties of Oxides

A steep-slope transistor based on abrupt electronic phase transition

Nikhil Shukla、Arun V. Thathachary、Ashish Agrawal 等 9 位作者2015-08-07OpenAlex

Collective interactions in functional materials can enable novel macroscopic properties like insulator-to-metal transitions. While implementing such materials into field-effect-transistor technology can potentially augment current state-of-the-art devices by providing unique routes to overcome their conventional limit…

2D Materials and ApplicationsAdvanced Memory and Neural ComputingTransition Metal Oxide Nanomaterials

PTE

Jian Tang、Meng Qu、Qiaozhu Mei2015-08-07OpenAlex

Unsupervised text embedding methods, such as Skip-gram and Paragraph Vector, have been attracting increasing attention due to their simplicity, scalability, and effectiveness. However, comparing to sophisticated deep learning architectures such as convolutional neural networks, these methods usually yield inferior res…

Topic ModelingAdvanced Graph Neural NetworksMachine Learning in Materials Science

Iron Oxide Based Nanoparticles for Multimodal Imaging and Magnetoresponsive Therapy

Nohyun Lee、Dongwon Yoo、Daishun Ling 等 6 位作者2015-08-07OpenAlex

The development of magnetic iron oxide nanoparticles as magnetic resonance (MR) imaging agents for sensitive and accurate diagnosis through inorganic materials design and their synergistic integration with other imaging modalities is reviewed. Modulation of the size, composition, and shape allows magnetic nanoparticle…

Nanoparticle-Based Drug DeliveryBiosensors and Analytical DetectionCharacterization and Applications of Magnetic Nanoparticles

X-ray irradiation synthesis of PEG-coated Au-Pd nanoparticles

Min-Tsang Li、Chang-Hai Wang、Sheng-Feng Lai 等 8 位作者2015-08-06Nanotechnology

We demonstrate that the combination of x-ray irradiation and capping by polyethylene glycol (PEG) produces excellent flexibility in controlling the structure of Au-Pd nanoparticles while preserving their catalytic performance. We specifically adopted two different fabrication methods: co-reduction and seed-assisted re…

Gold and Silver Nanoparticles Synthesis and ApplicationsCatalytic Processes in Materials ScienceNanomaterials for catalytic reactions

Crystallographic new light on an old complex: NaMg[Cr(oxalato)3]·9H2O and structure redetermination of the isomorphous aluminum(III) compound

Oscar E. Piro、Gustavo A. Echeverría、Ana C. González‐Baró 等 4 位作者2015-08-06Journal of Coordination Chemistry

The crystal structure of sodium and magnesium tris(oxalato)chromato(III) nona hydrate, NaMg[Cr(C2O4)3]·9H2O, has been determined by X-ray diffraction methods. It crystallizes in the trigonal P3c1 space group with (in the hexagonal setting) a = b = 16.9635(4), c = 12.5247(3) Å, and Z = 6 molecules per unit cell. The Cr…

Crystal structures of chemical compoundsCrystal Structures and PropertiesX-ray Diffraction in Crystallography

Photoactivation of Butyric Acid from 6‐Aminobenzocoumarin Cages

Ana M. S. Soares、Graham Hungerford、Susana P. G. Costa 等 4 位作者2015-08-06European Journal of Organic Chemistry

Abstract A new benzocoumarin bearing an amino group is proposed as a photocleavable protecting group for carboxylic acids. The novel heterocycle, 6‐amino‐4‐chloromethyl‐2‐oxo‐2 H ‐naphtho[1,2‐ b ]pyran was used in the preparation of ester conjugates of butyric acid, and of the corresponding mono‐ and dimethylated or e…

Radical Photochemical ReactionsPhotochromic and Fluorescence ChemistrySynthesis of Indole Derivatives

Near Surface Changes Due to 700 keV Si + Irradiation of Titanium Silicon Carbide

Qiang Qi、Chaozhuo Z. Liu、B.V. King 等 7 位作者2015-08-06Journal of the American Ceramic Society

The radiation damage response of Ti 3 SiC 2 heated from 120°C to 850°C during 700 keV Si + irradiation has been investigated. The samples were analyzed using glancing incidence X‐ray diffraction, Rutherford backscattering spectrometry, Raman spectroscopy, and scanning electron microscopy. For the sample at 120°C, irra…

Advanced ceramic materials synthesisMetal and Thin Film MechanicsMXene and MAX Phase Materials

Luminescence and energy‐transfer properties of color‐tunable Ca2Mg0.25Al1.5Si1.25O7:Ce3+/Eu2+/Tb3+ phosphors for ultraviolet light‐emitting diodes

Bo Yuan、Yanhua Song、Ye Sheng 等 7 位作者2015-08-06Luminescence

A series of Ca2Mg0.25Al1.5Si1.25O7:Ce(3+)/Eu(2+)/Tb(3+) phosphors was been prepared via a conventional high temperature solid-state reaction and their luminescence properties were studied. The emission spectra of Ca2Mg0.25Al1.5Si1.25O7:Ce(3+),Eu(2+) and Ca2Mg0.25Al1.5Si1.25O7:Ce(3+),Tb(3+) phosphors show not only a ba…

Luminescence Properties of Advanced MaterialsRadiation Detection and Scintillator TechnologiesMicrowave Dielectric Ceramics Synthesis

Super-Paramagnetic Particles Chemically Bound to Luminescent Diamond: Single Nanocrystals Probed with Optically Detected Magnetic Resonance

Taras Plakhotnik、Haroon Aman、Shaohua Zhang 等 4 位作者2015-08-06The Journal of Physical Chemistry C

We have synthesized novel composite particles made of single-domain nanomagnets chemically bound to nanocrystals of diamond. Optically detected magnetic resonance spectra of nitrogen-vacancy centers in diamond allowed us to estimate the magnetic field of the nanomagnets and to observe the saturation of their magnetiza…

High-pressure geophysics and materialsDiamond and Carbon-based Materials ResearchNonlinear Optical Materials Studies

Biomimetic approaches for green tribology: from the lotus effect to blood flow control

Nazanin Maani、Vitaliy S Rayz、Michael Nosonovsky2015-08-06Surface Topography Metrology and Properties

The research in Green tribology combines several areas including biomimetic tribomaterials and surfaces for controlled adhesion. Biomimetic surfaces mimic living nature and thus they are eco-friendly. The most famous biomimetic surface effect is the Lotus effect (reduction of water adhesion to a solid surface due to m…

Surface Modification and SuperhydrophobicityPolymer Surface Interaction StudiesAdhesion, Friction, and Surface Interactions

Characterisation of graphene nanoplatelets reinforced hot pressed Ti 3 SiC 2 ceramic

X. Cheng、Rujie He、Zhi Qu 等 4 位作者2015-08-06Advances in Applied Ceramics Structural Functional and Bioceramics

Ti3SiC2 based ceramic reinforced by 5 wt-% graphene nanoplatelets (GNPs) was prepared by hot pressing at 1550°C for 1 h under a uniaxial pressure load of 30 MPa. The effects of GNPs on the strengthening and toughening of the hot pressed Ti3SiC2 based ceramic were investigated. Comparing with t monolithic Ti3SiC2 ceram…

Aluminum Alloys Composites PropertiesMXene and MAX Phase MaterialsAdvanced materials and composites

Neutron-scattering-based evidence for interacting magnetic excitons inLaCoO3

S. El-Khatib、Daniel Phelan、J. G. Barker 等 6 位作者2015-08-06Physical Review B

For several decades LaCoO${}_{3}$ attracted interest due the unconventional thermally-driven spin-state crossover from a nonmagnetic to paramagnetic state. More recently, it was realized that the ``nonmagnetic'' ground state harbors some form of magnetism that is likely due to local magnetic entities forming at oxygen…

Physics of Superconductivity and MagnetismMagnetic and transport properties of perovskites and related materialsAdvanced Condensed Matter Physics

Electric field-induced tuning of magnetism in PbFe0.5Nb0.5O3 at room temperature

Sudhindra Rayaprol、S. Mukherjee、S. D. Kaushik 等 5 位作者2015-08-06Journal of Applied Physics

We study the influence of electrical poling, carried out at room temperature, on the structure and magnetism of Pb(Fe0.5Nb0.5)O3 by analyzing the differences observed in structural and magnetic properties before and after the electrical poling. The changes observed in magnetization of Pb(Fe0.5Nb0.5)O3 before and after…

Ferroelectric and Piezoelectric MaterialsMagnetic and transport properties of perovskites and related materialsMultiferroics and related materials