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Understanding and reducing deleterious defects in the metastable alloy GaAsBi

Guangfu Luo、Shujiang Yang、Glen R. Jenness 等 6 位作者2017-01-01NPG Asia Materials

Technological applications of novel metastable materials are frequently inhibited by abundant defects residing in these materials. Using first-principles methods, we investigate the defect thermodynamics and phase segregation in the technologically important metastable alloy GaAsBi. Our calculations predict defect ene…

Advanced Chemical Physics StudiesMachine Learning in Materials Sciencenanoparticles nucleation surface interactions

Quantum–continuum simulation of underpotential deposition at electrified metal–solution interfaces

Stephen E. Weitzner、Ismaila Dabo2017-01-01npj Computational Materials

Thin films: How to overachieve at underpotentials The deposition of atomically thin metal films can be predicted with a comprehensive model incorporating realistic environmental factors. Nanomaterials used as catalysts and sensors are often produced by the spontaneous attachment of metal ions onto inert metal surfaces…

Materials Science

Electronic structure of buried LaNiO3 layers in (111)-oriented LaNiO3/LaMnO3 superlattices probed by soft x-ray ARPES

F. Y. Bruno、Marta Gibert、S. McKeown Walker 等 13 位作者2017-01-01APL Materials

Taking advantage of the large electron escape depth of soft x-ray angle resolved photoemission spectroscopy, we report electronic structure measurements of (111)-oriented [LaNiO3/LaMnO3] superlattices and LaNiO3 epitaxial films. For thin films, we observe a 3D Fermi surface with an electron pocket at the Brillouin zon…

Magnetic and transport properties of perovskites and related materialsAdvanced Condensed Matter PhysicsElectronic and Structural Properties of Oxides

Anomalous resistivity upturn in epitaxial L21-Co2MnAl films

L. J. Zhu、J. H. Zhao2017-01-01arXiv

We report the controllable growth and the intriguing transport behavior of high-spin-polarization epitaxial L21-Co2MnAl films, which exhibit a low-temperature (T) resistivity upturn with pronounced T1/2 dependence, close relevance to structural disorder, and robust independence of magnetic fields. The resistivity uptu…

Materials Science

An integrated approach to doped thin films with strain-tunable magnetic anisotropy: powder synthesis, target preparation and pulsed laser deposition of Bi:YIG

Pathikumar Sellappan、Chi Tang、Jing Shi 等 4 位作者2017-01-01Materials Research Letters

We present a synthesis/processing method for fabricating ferrimagnetic insulator (Bi-doped yttrium iron garnet) thin films with tunable magnetic anisotropy. Since the desired magnetic properties rely on controllable thickness and successful doping, we pay attention to the entire synthesis/processing procedure (nanopow…

Materials Science

Formic acid oxidation on platinum electrodes: a detailed mechanism supported by experiments and calculations on well-defined surfaces

Adolfo Ferre-Vilaplana、Juan V. Perales-Rondón、Carlos Busó‐Rogero 等 5 位作者2017-01-01Journal of Materials Chemistry A

The key elements in the mechanism of the formic acid oxidation reaction on platinum have been completely elucidated, not only for the direct path through an active intermediate, but also for the CO formation route.

Electrocatalysts for Energy ConversionCatalytic Processes in Materials ScienceCatalysis and Oxidation Reactions

Near infrared-to-blue photon upconversion by exploiting direct S–T absorption of a molecular sensitizer

Yōichi Sasaki、Shogo Amemori、Hironori Kouno 等 5 位作者2017-01-01Journal of Materials Chemistry C

Efficient NIR-to-blue photon upconversion was realized for the first time by exploiting sensitizer S–T transition and achieved the largest anti-Stokes shift of 0.97 eV.

Luminescence Properties of Advanced MaterialsPorphyrin and Phthalocyanine ChemistryLuminescence and Fluorescent Materials

A promising single atom catalyst for CO oxidation: Ag on boron vacancies of h-BN sheets

Zhansheng Lu、Peng Lv、Zongxian Yang 等 6 位作者2017-01-01Physical Chemistry Chemical Physics

Due to “CO-Promoted O <sub>2</sub> Activation”, the termolecular Eley–Rideal (TER) mechanism is the most relevant one for CO oxidation over the SAC, Ag <sub>1</sub> /BN.

Catalytic Processes in Materials ScienceHydrogen Storage and MaterialsBoron and Carbon Nanomaterials Research

Engineering hierarchical nanotrees with CuCo 2 O 4 trunks and NiO branches for high-performance supercapacitors

Kangwen Qiu、Min Lü、Yongsong Luo 等 4 位作者2017-01-01Journal of Materials Chemistry A

Hierarchical CuCo <sub>2</sub> O <sub>4</sub> @NiO core–shell nanotree arrays on porous nickel foam substrates are synthesized <italic>via</italic> a simple hydrothermal approach and further investigated as electrode materials for supercapacitors.

Advancements in Battery MaterialsElectrocatalysts for Energy ConversionSupercapacitor Materials and Fabrication

Environmentally friendly nitrogen-doped carbon quantum dots for next generation solar cells

Darragh Carolan、Conor Rocks、Dilli Babu Padmanaban 等 6 位作者2017-01-01Sustainable Energy & Fuels

N-CQDs are synthesized using a green, environmentally friendly microplasma and employed in solar cells, achieving a <italic>V</italic> <sub>OC</sub> of 1.8 V.

Quantum Dots Synthesis And PropertiesCarbon and Quantum Dots ApplicationsNanocluster Synthesis and Applications

Ultraviolet saturable absorption and ultrafast carrier dynamics in ultrasmall black phosphorus quantum dots

Yingwei Wang、Sheng Liu、Bowen Zeng 等 11 位作者2017-01-01Nanoscale

Understanding the photoexcited carrier-relaxation actions in ultrasmall black phosphorus quantum dots (BPQDs) will play a crucial role in the fields of electronics and optoelectronics. Herein, we report the ultraviolet (UV) saturable absorption and ultrafast photoexcited carrier-relaxation dynamics of BPQDs. The ultra…

2D Materials and ApplicationsAdvanced Fiber Laser TechnologiesLuminescence and Fluorescent Materials

Elastic soft hydrogel supercapacitor for energy storage

Bosi Yin、Siwen Zhang、Qingqing Ren 等 6 位作者2017-01-01Journal of Materials Chemistry A

The elastic soft (PVA/PPy) <sub>(−)</sub> //CNTs <sub>(+)</sub> supercapacitor is first designed who exhibits fascinating mechanical properties and realizes a high working voltage.

Supercapacitor Materials and FabricationAdvanced Sensor and Energy Harvesting MaterialsElectrospun Nanofibers in Biomedical Applications

Two fluorescein-based chemosensors for the fast detection of 2,4,6-trinitrophenol (TNP) in water

Zhenhai Fu、Ya‐Wen Wang、Yu Peng2017-01-01Chemical Communications

Two fluorescein-based chemosensors have been developed. They exhibited rapid and selective detection of 2,4,6-trinitrophenol (TNP) via fluorescence quenching both in ethanol and water solution when excited by visible light.

Molecular Sensors and Ion DetectionLuminescence and Fluorescent MaterialsCarbon and Quantum Dots Applications