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Lead chalcogenide quantum dots for photoelectric devices

Ivan A. Shuklov、В. Ф. Разумов2019-09-27Russian Chemical Reviews

The review concerns the state of the art in methods of synthesis of colloidal lead chalcogenide quantum dots (QDs). The most recent data on the mechanisms of chemical transformations involving various precursors are discussed. Particular attention is paid to the influence of (i) trace impurities in the reactants used…

Quantum Dots Synthesis And PropertiesChalcogenide Semiconductor Thin FilmsNanocluster Synthesis and Applications

Pyridyl Disulfide Reaction Chemistry: An Efficient Strategy toward Redox-Responsive Cyclic Peptide–Polymer Conjugates

Qiao Song、Jie Yang、Stephen C. L. Hall 等 5 位作者2019-09-27ACS Macro Letters

Cyclic peptide–polymer conjugates are capable of self-assembling into supramolecular polymeric nanotubes driven by the strong multiple hydrogen bonding interactions between the cyclic peptides. In this study, we have engineered responsive nanotubes by introducing a cleavable bond that responds to a reductant utilizing…

Chemical Synthesis and AnalysisSupramolecular Self-Assembly in MaterialsClick Chemistry and Applications

Near-Infrared Hybrid Rhodol Dyes with Spiropyran Switches for Sensitive Ratiometric Sensing of pH Changes in Mitochondria and Drosophila melanogaster First-Instar Larvae

Yibin Zhang、Shuai Xia、Logan Mikesell 等 10 位作者2019-09-27ACS Applied Bio Materials

Near-infrared hybrid rhodol dyes (probes A and B ) for sensitive ratiometric visualization of pH changes were prepared by incorporating hemicyanine dyes into traditional rhodol dyes. This approach was based on π-conjugation changes involving a rhodol hydroxyl group as a spiropyran switch upon pH changes. Probes A-2 an…

Molecular Sensors and Ion DetectionPhotochromic and Fluorescence ChemistryPhotoreceptor and optogenetics research

Organic Room‐Temperature Phosphorescence with Strong Circularly Polarized Luminescence Based on Paracyclophanes

Xiao Liang、Tingting Liu、Zhi‐Ping Yan 等 10 位作者2019-09-27Angewandte Chemie

Abstract Pure organic materials with intrinsic room‐temperature phosphorescence typically rely on heavy atoms or heteroatoms. Two different strategies towards constructing organic room‐temperature phosphorescence (RTP) species based upon the through‐space charge transfer (TSCT) unit of [2.2]paracyclophane (PCP) were d…

Perovskite Materials and ApplicationsOrganic Light-Emitting Diodes ResearchLuminescence and Fluorescent Materials

Improved Osseointegration of a TiNbSn Alloy with a Low Young’s Modulus Treated with Anodic Oxidation

Tomonori Kunii、Yu Mori、Hidetatsu Tanaka 等 9 位作者2019-09-27Scientific Reports

Ti6Al4V alloy orthopedic implants are widely used as Ti6Al4V alloy is a biocompatible material and resistant to corrosion. However, Ti6Al4V alloy has higher Young's modulus compared with human bone. The difference of elastic modulus between bone and titanium alloy may evoke clinical problems because of stress shieldin…

Intermetallics and Advanced Alloy PropertiesTitanium Alloys Microstructure and PropertiesMXene and MAX Phase Materials

Synergy of the flow behaviour and disperse phase of cellulose nanoparticles in enhancing oil recovery at reservoir condition

Augustine Agi、Radzuan Junin、Agus Arsad 等 7 位作者2019-09-27PLoS ONE

Ascorbic acid was used for the first time to synthesize cellulose nanoparticles (CNP) extracted from okra mucilage. The physical properties of the CNP including their size distribution, and crystalline structures were investigated. The rheological properties of the cellulose nanofluid (CNF) were compared with the bulk…

Enhanced Oil Recovery TechniquesAdvanced Cellulose Research StudiesElectrohydrodynamics and Fluid Dynamics

Dual pH-responsive “charge-reversal like” gold nanoparticles to enhance tumor retention for chemo-radiotherapy

Xiaolei Zhang、Chuangnian Zhang、Mingbo Cheng 等 6 位作者2019-09-27Nano Research

The strategy of pH-responsive aggregation in tumor micro-environment (TME) provides an intriguing platform for enhancing tumor retention and exerting therapeutic effects sufficiently. In this work, we have designed an intelligent dual pH-responsive self-aggregating nano gold system (Au@PAH-Pt/DMMA) for the combined ch…

Nanoparticle-Based Drug DeliveryGold and Silver Nanoparticles Synthesis and ApplicationsNanoplatforms for cancer theranostics

The Comet Assay as a Tool to Detect the Genotoxic Potential of Nanomaterials

Alba García‐Rodríguez、Laura Rubio、Laura Vila-Vecilla 等 7 位作者2019-09-27Nanomaterials

The interesting physicochemical characteristics of nanomaterials (NMs) has brought about their increasing use and, consequently, their increasing presence in the environment. As emergent contaminants, there is an urgent need for new data about their potential side-effects on human health. Among their potential effects…

Nanoparticles: synthesis and applicationsCarcinogens and Genotoxicity AssessmentMicroplastics and Plastic Pollution

Striated 2D Lattice with Sub‐nm 1D Etch Channels by Controlled Thermally Induced Phase Transformations of PdSe 2

Gyeong Hee Ryu、Taishan Zhu、Jun Chen 等 7 位作者2019-09-27Advanced Materials

Abstract 2D crystals are typically uniform and periodic in‐plane with stacked sheet‐like structure in the out‐of‐plane direction. Breaking the in‐plane 2D symmetry by creating unique lattice structures offers anisotropic electronic and optical responses that have potential in nanoelectronics. However, creating nanosca…

Graphene research and applications2D Materials and ApplicationsMXene and MAX Phase Materials

Toward Interpretable Machine Learning Models for Materials Discovery

Paulius Mikulskis、Morgan R. Alexander、David A. Winkler2019-09-27Advanced Intelligent Systems

Machine learning (ML) and artificial intelligence (AI) methods for modeling useful materials properties are now important technologies for rational design and optimization of bespoke functional materials. Although these methods make good predictions of the properties of new materials, current modeling methods use effi…

Computational Drug Discovery MethodsMachine Learning in Materials ScienceX-ray Diffraction in Crystallography

A nanofluidic device for parallel single nanoparticle catalysis in solution

Sune Levin、Joachim Fritzsche、Sara Nilsson 等 9 位作者2019-09-27Nature Communications

Studying single catalyst nanoparticles, during reaction, eliminates averaging effects that are an inherent limitation of ensemble experiments. It enables establishing structure-function correlations beyond averaged properties by including particle-specific descriptors such as defects, chemical heterogeneity and micros…

Gold and Silver Nanoparticles Synthesis and ApplicationsInnovative Microfluidic and Catalytic Techniques InnovationElectrohydrodynamics and Fluid Dynamics

Rational Design and Fabrication of ZnONPs Functionalized Sericin/PVA Antimicrobial Sponge

Lisha Ai、Huawei He、Peng Wang 等 10 位作者2019-09-27International Journal of Molecular Sciences

The interests of developing antimicrobial biomaterials based on silk sericin from Bombyx mori cocoon, have been shooting up in the last decades. Sericin is a valuable natural protein owing to its hydrophilicity, biodegradability, and biocompatibility. Here, we fabricated a sponge with antibacterial capacities for pote…

Electrospun Nanofibers in Biomedical ApplicationsPolymer Surface Interaction StudiesSilk-based biomaterials and applications

Production, Processes and Modification of Nanocrystalline Cellulose from Agro-Waste: A Review

R.A. Ilyas、S.M. Sapuan、Rushdan Ibrahim 等 7 位作者2019-09-27IntechOpen eBooks

Nanocrystalline cellulose is a renewable nanomaterial that has gained huge attention for its use in various applications from advanced biomedical material to food packaging material due to its exceptional physical and biological properties, such as high crystallinity degree, large specific surface area, high aspect ra…

Nanocomposite Films for Food PackagingAdvanced Cellulose Research Studiesbiodegradable polymer synthesis and properties

Room-Temperature Welding of Silver Telluride Nanowires for High-Performance Thermoelectric Film

Xiangliang Zeng、Xiangliang Zeng、Linlin Ren 等 12 位作者2019-09-27ACS Applied Materials & Interfaces

Flexible thermoelectric materials that can harvest waste heat energy have attracted great attention because of the rapid progress of flexible electronics. Ag 2 Te nanowires (Ag 2 Te NWs) are considered as promising thermoelectric materials to fabricate flexible thermoelectric film and device because of their high Seeb…

Perovskite Materials and Applications2D Materials and ApplicationsAdvanced Thermoelectric Materials and Devices

Mass Spectrometry Reveals Molecular Structure of Polyhydroxyalkanoates Attained by Bioconversion of Oxidized Polypropylene Waste Fragments

Brian Johnston、Iza Radecka、Emo Chiellini 等 14 位作者2019-09-27Polymers

This study investigated the molecular structure of the polyhydroxyalkanoate (PHA) produced via a microbiological shake flask experiment utilizing oxidized polypropylene (PP) waste as an additional carbon source. The bacterial strain Cupriavidus necator H16 was selected as it is non-pathogenic, genetically stable, robu…

biodegradable polymer synthesis and propertiesMicroplastics and Plastic PollutionRecycling and Waste Management Techniques

Compressible All‐In‐One Supercapacitor with Adjustable Output Voltage Based on Polypyrrole‐Coated Melamine Foam

Qifan Liu、Limin Zang、Xuan Qiao 等 8 位作者2019-09-27Advanced Electronic Materials

Abstract Compared with laminated structure supercapacitors, all‐in‐one supercapacitors can reduce the contact resistance of the interface and avoid displacement/delamination of the multilayer structure under deformation, which suggests a highly promising energy‐storage device. However, simplifying the assembly process…

Supercapacitor Materials and FabricationConducting polymers and applicationsAdvanced battery technologies research

Lysosome-Targeting Red-Emitting Aggregation-Induced Emission Probe with Large Stokes Shift for Light-Up in Situ Visualization of β- N -Acetylhexosaminidase

Qiang Wang、Chunbin Li、Qingqing Chen 等 8 位作者2019-09-27Analytical Chemistry

-acetylhexosaminidase (Hex) has been reported to possess unique physiological performances. Detection and visualization of Hex in lysosome will be favorable to reveal the basis of its functions. However, Hex-specific fluorescent probes are rarely reported. In this study, we reported the first lysosome-targeting Hex-li…

Advanced biosensing and bioanalysis techniquesMolecular Sensors and Ion DetectionLuminescence and Fluorescent Materials

Hierarchically Porous Cu-, Co-, and Mn-Doped Platelet-Like ZnO Nanostructures and Their Photocatalytic Performance for Indoor Air Quality Control

Dimitra Papadaki、G.H. Mhlongo、David E. Motaung 等 11 位作者2019-09-27ACS Omega

High Resolution Image Download MS PowerPoint Slide Several parameters, including specific surface area, morphology, crystal size, and dopant concentration, play a significant role in improving the photocatalytic performance of ZnO. However, it is still unclear which of these parameters play a significant role in enhan…

Advanced Photocatalysis TechniquesZnO doping and propertiesGa2O3 and related materials

Elemental Silver Nanoparticles: Biosynthesis and Bio Applications

О. В. Михайлов、Е. О. Михайлова2019-09-27Materials

The data on the specifics of synthesis of elemental silver nanoparticles (Ag-NP) having various geometric shapes (pseudo spherical, prismatic, cubic, trigonal-pyramidal, etc.), obtained by using various biological methods, and their use in biology and medicine have been systematized and generalized. The review covers…

Nanoparticles: synthesis and applicationsGraphene and Nanomaterials ApplicationsLaser-Ablation Synthesis of Nanoparticles

Orbital differentiation in Hund metals

Fabian B. Kugler、Seung‐Sup B. Lee、Andreas Weichselbaum 等 5 位作者2019-09-27Physical review. B./Physical review. B

Orbital differentiation is a common theme in multiorbital systems, yet a complete understanding of it is still missing. Here, we consider a minimal model for orbital differentiation in Hund metals with a highly accurate method: We use the numerical renormalization group as a real-frequency impurity solver for a dynami…

Magnesium Alloys: Properties and ApplicationsRare-earth and actinide compoundsIron-based superconductors research