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Ellipsoidal magnetite nanoparticles: a new member of the magnetic-vortex nanoparticles family for efficient magnetic hyperthermia

Hongxu Gao、Tingbin Zhang、Yifan Zhang 等 13 位作者2019-11-25Journal of Materials Chemistry B

The development of magnetic iron oxide nanoparticles with novel topological magnetic domain structures, such as the vortex-domain structure, is a promising strategy for improving the application performance of conventional superparamagnetic iron oxides while maintaining their good biocompatibility. Here, we fabricated…

Nanoparticle-Based Drug DeliveryIron oxide chemistry and applicationsCharacterization and Applications of Magnetic Nanoparticles

Adiabatic and nonadiabatic energy dissipation during scattering of vibrationally excited CO from Au(111)

Meng Huang、Xueyao Zhou、Yaolong Zhang 等 7 位作者2019-11-25Physical review. B./Physical review. B

A high-dimensional potential energy surface (PES) for CO interaction with the Au(111) surface is developed using a machine-learning algorithm. Including both molecular and surface coordinates, this PES enables the simulations of the recent experiment on scattering of vibrationally excited CO from Au(111). Trapping in…

Advanced Chemical Physics StudiesCatalysis and Oxidation ReactionsMachine Learning in Materials Science

Toward ab Initio Ground States of Gold Clusters via Neural Network Modeling

A. Thorn、Javier Rojas-Nunez、Samad Hajinazar 等 5 位作者2019-11-25The Journal of Physical Chemistry C

Prescreening candidate structures with reliable classical potentials is an effective way to accelerate ab initio ground state searches. Given the growing popularity of machine learning force fields, surprisingly little work has been dedicated to quantifying their advantages over traditional potentials in global struct…

Advanced Chemical Physics StudiesComputational Drug Discovery MethodsMachine Learning in Materials Science

Understanding Film Thickness‐Dependent Block Copolymer Self‐Assembly by Controlled Polymer Dewetting on Prepatterned Surfaces

Katharina Brassat、Daniel Kool、Colin G. A. Nallet 等 4 位作者2019-11-25Advanced Materials Interfaces

Abstract Block copolymer (BCP) lithography is a versatile bottom‐up approach for the creation of regular nanoscale patterns on large surface areas. The pattern morphology evolving during the microphase separation of a BCP is strongly dependent on the polymer film thickness. Thus, surface wetting as well as interfacial…

Block Copolymer Self-AssemblyFluid Dynamics and Thin FilmsCharacterization and Applications of Magnetic Nanoparticles

Wear-resistant and robust superamphiphobic coatings with hierarchical TiO 2 /SiO 2 composite particles and inorganic adhesives

Can Huang、Fengyi Wang、Daheng Wang 等 4 位作者2019-11-25New Journal of Chemistry

Superamphiphobic coatings, which could repel liquids with a surface tension as low as 21.6 mN m −1 ( n -octane), were prepared using a spray-coating method based on a flower-like hierarchical structure and highly fluorinated TiO 2 /SiO 2 composite particles.

Surface Modification and SuperhydrophobicityPolymer Surface Interaction StudiesSilicone and Siloxane Chemistry

Magnetic and silver nanoparticle functionalized calcium carbonate particles—Dual functionality of versatile, movable delivery carriers which can surface-enhance Raman signals

Bogdan V. Parakhonskiy、Anatolii Abalymov、А. Г. Иванова 等 5 位作者2019-11-25Journal of Applied Physics

Multifunctional probes play an increasing role even beyond applications in biomedicine. Multifunctionality introduced by the dual types of complementary probes is always attractive because, in this case, functionalized objects inherit the function of both materials. Porous calcium carbonate microparticles are becoming…

Gold and Silver Nanoparticles Synthesis and ApplicationsBiosensors and Analytical DetectionInnovative Microfluidic and Catalytic Techniques Innovation

Determination of the Aspect-ratio Distribution of Gold Nanorods in a Colloidal Solution using UV-visible absorption spectroscopy

Rahul Kumar、Leonardo Binetti、T. Hien Nguyen 等 7 位作者2019-11-25Scientific Reports

Knowledge of the distribution of the aspect ratios (ARs) in a chemically-synthesized colloidal solution of Gold Nano Rods (GNRs) is an important measure in determining the quality of synthesis, and consequently the performance of the GNRs generated for various applications. In this work, an algorithm has been develope…

Nanoparticles: synthesis and applicationsGold and Silver Nanoparticles Synthesis and ApplicationsElectrochemical Analysis and Applications

Benzoic Acid as an Efficient Organocatalyst for the Statistical Ring-Opening Copolymerization of ε-Caprolactone and L -Lactide: A Computational Investigation

Coralie Jehanno、Leila Mezzasalma、Haritz Sardón 等 6 位作者2019-11-25Macromolecules

Statistical copolymers of l -lactide (L-LA) and ε-caprolactone (CL) are of major interest as a result of the desired combination of properties they exhibit for high-added-value applications, including in the biomedical field and in microelectronics. However, the high difference of reactivity between the two monomers m…

Organometallic Complex Synthesis and Catalysisbiodegradable polymer synthesis and propertiesCarbon dioxide utilization in catalysis

Dually Active Targeting Nanomedicines Based on a Direct Conjugate of Two Purely Natural Ligands for Potent Chemotherapy of Ovarian Tumors

Yu Yan、Yangyang Dong、Shujing Yue 等 6 位作者2019-11-25ACS Applied Materials & Interfaces

Actively targeted nanomedicines have promised to revolutionize cancer treatment; however, their clinical translation has been limited by either low targetability, use of unsafe materials, or tedious fabrication. Here, we developed CD44 and folate receptor (FR) dually targeted nanoparticulate doxorubicin (HA/FA-NP-DOX)…

Nanoparticle-Based Drug DeliveryNanoplatforms for cancer theranosticsLung Cancer Research Studies

Cone-spiral magnetic ordering dominated lattice distortion and giant negative thermal expansion in Fe-doped MnNiGe compounds

Feiran Shen、Houbo Zhou、Fengxia Hu 等 19 位作者2019-11-25Materials Horizons

By utilizing the large lattice distortion caused by incommensurate cone-spiral magnetic ordering and the induced texture effect in Fe-doped MnNiGe alloys, NTE largely exceeding the average crystallographical contribution has been achieved.

Advanced Battery Materials and TechnologiesMagnetic and transport properties of perovskites and related materialsThermal Expansion and Ionic Conductivity

Band structure, phonon spectrum, and thermoelectric properties of β-BiAs and β-BiSb monolayers

C.Y. Wu、Lei Sun、Jinchen Han 等 4 位作者2019-11-25Journal of Materials Chemistry C

First-principles calculation and Boltzmann transport theory have been combined to comparatively investigate the band structures, phonon spectra, and thermoelectric properties of both β-BiSb and β-BiAs monolayers.

2D Materials and ApplicationsAdvanced Thermoelectric Materials and DevicesTopological Materials and Phenomena

Formulation and development of lipid nanoparticle antifungal packaging films to control postharvest disease

Austin McDaniel、Bade Tonyalı、Umut Yücel 等 4 位作者2019-11-25Journal of Agriculture and Food Research

Postharvest loss is a major problem in the produce industry. It is important to find alternative solutions to minimize waste. Therefore, the objective of this study was to evaluate the mechanical, physical, and antifungal properties of packaging films loaded with active essential oil compounds (EOC) in the form of liq…

Essential Oils and Antimicrobial ActivityPostharvest Quality and Shelf Life ManagementNanocomposite Films for Food Packaging

One-pot synthesis of cerium and praseodymium co-doped carbon quantum dots as enhanced antioxidant for hydroxyl radical scavenging

Shengqiang Zou、Fan Guo、Lin Wu 等 11 位作者2019-11-25Nanotechnology

Abstract The antioxidant activity of ceria nanoparticles is tightly regulated by size distribution and heteroatom doping. Inspired by this rule, cerium and praseodymium codoped carbon quantum dots (Ce/Pr-CQDs) were synthesized through the one-pot hydrothermal carbonization method. Taking intrinsic advantage of CQDs, t…

Carbon and Quantum Dots ApplicationsNanocluster Synthesis and ApplicationsAdvanced Nanomaterials in Catalysis

One-directional thermal transport in densely aligned single-wall carbon nanotube films

Shingi Yamaguchi、Issei Tsunekawa、Natsumi Komatsu 等 8 位作者2019-11-25Applied Physics Letters

Individual carbon nanotubes (CNTs) possess extremely high thermal conductivities. However, the thermal conductivities and their anisotropy of macroscopic assemblies of CNTs have so far remained small. Here, we report the results of directional thermal transport measurements on a nearly perfectly aligned CNT film fabri…

Carbon Nanotubes in CompositesAdvanced Thermoelectric Materials and DevicesThermal properties of materials

Chirality Induction through Nano‐Phase Separation: Alternating Network Gyroid Phase by Thermotropic Self‐Assembly of X‐Shaped Bolapolyphiles

Changlong Chen、Robert Kieffer、Helgard Ebert 等 9 位作者2019-11-25Angewandte Chemie International Edition

The single gyroid phase as well as the alternating double network gyroid, composed of two alternating single gyroid networks, hold a significant place in ordered nanoscale morphologies for their potential applications as photonic crystals, metamaterials and templates for porous ceramics and metals. Here, we report the…

Liquid Crystal Research AdvancementsSupramolecular Self-Assembly in MaterialsPickering emulsions and particle stabilization

A theory for the slip and drag of superhydrophobic surfaces with surfactant

Julien R. Landel、François J. Peaudecerf、Fernando Temprano-Coleto 等 6 位作者2019-11-25Journal of Fluid Mechanics

Superhydrophobic surfaces (SHSs) have the potential to reduce drag at solid boundaries. However, multiple independent studies have recently shown that small amounts of surfactant, naturally present in the environment, can induce Marangoni forces that increase drag, at least in the laminar regime. To obtain accurate dr…

Surface Modification and SuperhydrophobicityFluid Dynamics and Thin FilmsFluid dynamics and aerodynamics studies

Additive‐Free Green Light‐Induced Ligation Using BODIPY Triggers

Ming Li、Andrew P. Dove、Vinh X. Truong2019-11-25Angewandte Chemie International Edition

Photochemical ligation is important in biomaterials engineering for spatiotemporal control of biochemical processes. Such reactions however generally require activation by high energy UV or short wavelength blue light, which can limit their use as a consequence of the potential of these high energy light sources to da…

Nanoplatforms for cancer theranosticsLuminescence and Fluorescent MaterialsPhotochromic and Fluorescence Chemistry

Two-step phosphorescent mechanochromism due to intramolecular deformation

Xu Zhang、Liyi Zhang、Jin-Yun Wang 等 5 位作者2019-11-25Journal of Materials Chemistry C

The Pt 2 Cu complex exhibits unusual stepwise phosphorescent changes from green to yellow first and then to orange-red emission when gentle and intense mechanical stimuli are exerted, arising from gradual intramolecular deformation.

Molecular Sensors and Ion DetectionSupramolecular Chemistry and ComplexesLuminescence and Fluorescent Materials

Reversible Tuning of the Plasmoelectric Effect in Noble Metal Nanostructures Through Manipulation of Organic Ligand Energy Levels

Thakshila Liyanage、Malpuri Nagaraju、Merrell A. Johnson 等 5 位作者2019-11-25Nano Letters

Ligand-controlled tuning of localized surface plasmon resonance (LSPR) properties of noble metal nanostructures is fundamentally important for various optoelectronic applications such as photocatalysis, photovoltaics, and sensing. Here we demonstrate that the free carrier concentration of gold triangular nanoprisms (A…

Gold and Silver Nanoparticles Synthesis and ApplicationsAdvanced biosensing and bioanalysis techniquesNanocluster Synthesis and Applications