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Oligomer Electrolytes for Light-Emitting Electrochemical Cells: Influence of the End Groups on Ion Coordination, Ion Binding, and Turn-on Kinetics

Isabelle Gerz、E. Mattias Lindh、Pall Thordarson 等 6 位作者2019-10-17ACS Applied Materials & Interfaces

The electrolyte is an essential constituent of the light-emitting electrochemical cell (LEC), since its operating mechanism is dependent on the redistribution of mobile ions in the active layer. Recent developments of new ion transporters have yielded high-performance devices, but knowledge about the interactions betw…

Organic Electronics and PhotovoltaicsOrganic Light-Emitting Diodes ResearchConducting polymers and applications

In situ Al 3 Ti/Al composites fabricated by high shear technology: microstructure and mechanical properties

Yan Zeng、David Himmler、P. Randelzhofer 等 4 位作者2019-10-17Materials Science and Technology

In situ Al 3 Ti/Al composites were produced by the reaction between Ti powder and Al melt with high shear technology. As Ti powder is starting material, it is important to investigate its size effect on the microstructure and mechanical properties of Al 3 Ti/Al composites. The results indicate that the necessary react…

Microstructure and mechanical propertiesAluminum Alloy Microstructure PropertiesAluminum Alloys Composites Properties

Engineering of Large Third-Order Nonlinearities in Atomic Layer Deposition Grown Nitrogen-Enriched TiO2

Robinson Kuis、Theodosia Gougousi、Isaac Basaldua 等 6 位作者2019-10-17ACS Photonics

The third-order nonlinear optical properties of nitrogen-enriched TiO 2 films deposited by atomic layer deposition (ALD) at a temperature between 100–300 °C on quartz substrates were studied using thermally managed Z-scan technique. TiO 2 oxide films prepared by physical vapor deposition (PVD) at room temperature were…

Semiconductor materials and devicesDiamond and Carbon-based Materials ResearchNonlinear Optical Materials Studies

In Saccharomyces cerevisiae, withdrawal of the carbon source results in detachment of glycolytic enzymes from the cytoskeleton and in actin reorganization

Emilio Espinoza‐Simón、Natalia Chiquete‐Félix、Lilia Morales‐García 等 8 位作者2019-10-17Fungal Biology

Metabolons are dynamic associations of enzymes catalyzing consecutive reactions within a given pathway. Association results in enzyme stabilization and increased metabolic efficiency. Metabolons may use cytoskeletal elements, membranes and membrane proteins as scaffolds. The effects of glucose withdrawal on a putative…

Fungal and yeast genetics researchEnzyme Structure and FunctionBiochemical and Molecular Research

The NEMO Dots Assembly: Single-Particle Tracking and Analysis

Jean-Yves Tinévez、Sébastien Herbert2019-10-17Learning materials in biosciences

The aim of this chapter is to learn the principles and pitfalls of single-particle tracking (SPT). Tracking in general is very important for dynamic studies, as it is about propagating object identities over time, permitting the calculation of dynamic quantities such as object velocities. Tracking is often the first s…

Advanced Fluorescence Microscopy TechniquesAdvanced Electron Microscopy Techniques and ApplicationsElectron and X-Ray Spectroscopy Techniques

Construction of 2D/2D Heterogeneous of ZIF‐8/SnS 2 Composite as a Transfer of Band‐Band System for Efficient Visible Photocatalytic Activity

Xiaoyu Chou、Ye Jin、Mi-Mi Cui 等 7 位作者2019-10-17ChemistrySelect

Abstract Constructing two‐dimensional (2D) heterostructured nanocomposites is an effective method to boost photo‐generated carrier separation efficiently using layer material. In this work, a tightly coupled 2D/2D ZIF‐8/SnS 2 nanosheet heterogeneous composite was successfully prepared. Due to the good heterogeneous in…

Advanced Photocatalysis TechniquesMetal-Organic Frameworks: Synthesis and ApplicationsMXene and MAX Phase Materials

Natural Hydrogels Applied in Photodynamic Therapy

Zhipan Feng、Shiying Lin、Andrew M. McDonagh 等 4 位作者2019-10-17Current Medicinal Chemistry

Natural hydrogels are three-dimensional (3D) water-retaining materials with a skeleton consisting of natural polymers, their derivatives or mixtures. Natural hydrogels can provide sustained or controlled drug release and possess some unique properties of natural polymers, such as biodegradability, biocompatibility and…

Nanoparticle-Based Drug DeliveryHydrogels: synthesis, properties, applicationsNanoplatforms for cancer theranostics

Solid-Form Transition Temperature Prediction from a Virtual Polymorph Screening: A Reality Check

Yuriy A. Abramov、Guangxu Sun、Yunfei Zhou 等 6 位作者2019-10-17Crystal Growth & Design

The focus of this study is an estimation of uncertainty of solid-form transition temperature ( T tr ) prediction based on modern virtual polymorph screening calculations. That was done through error propagation, utilizing estimated uncertainties of the relative free energy predictions at 0 K as well as of finite-tempe…

Crystallography and molecular interactionsCrystallization and Solubility StudiesMachine Learning in Materials Science

Encapsulated Gold Nanoparticles as a Reactive Quasi‐Homogeneous Catalyst in Base‐Free Aerobic Homocoupling Reactions

Wongi Jang、Hongsik Byun、Jun‐Hyun Kim2019-10-17ChemCatChem

Abstract Multiple gold nanoparticles (AuNPs) are physically encapsulated within a poly(N‐isopropylacrylamide) particle at room temperature by an in situ reduction method using trisodium citrate (Cit) and sodium oxalate (Oxa) to serve as quasi‐homogeneous catalysts for carbon−carbon bond‐forming reactions under base‐fr…

Catalytic Processes in Materials ScienceNanocluster Synthesis and ApplicationsNanomaterials for catalytic reactions

Effects of alkylamine chain length on perovskite nanocrystals after washing and perovskite light-emitting diodes

Yuki Tezuka、Kazuki Umemoto、Masaki Takeda 等 15 位作者2019-10-17Japanese Journal of Applied Physics

Abstract Organic–inorganic hybrid lead halide perovskite nanocrystals (PeNCs) have received great attention as a light source for perovskite LEDs (PeLEDs) owing to the superior optical properties. However, PeNCs typically use octylamine (OAm) as capping ligands which have insulating properties. Exploring a desirable s…

Perovskite Materials and ApplicationsOrganic Light-Emitting Diodes ResearchConducting polymers and applications

Molten Salt-assisted Magnesiothermic Reduction Synthesis of Spherical Si Hollow Structure as Promising Anode Materials of Lithium Ion Batteries

Xiaohan Wan、Zehua Tang、Jiale Chen 等 10 位作者2019-10-17Chemistry Letters

To solve the critical issue of the poor cycling stability caused by large volume expansion of Si-based anodes during Li lithiation/delithiation processes, spherical Si hollow nanostructures are prepared based on Kirkendall effect via a simple molten salt-assisted magnesiothermic reduction technique. The hollow structu…

Advancements in Battery MaterialsSupercapacitor Materials and FabricationAdvanced Battery Materials and Technologies

High-Speed Photothermal Patterning of Doped Polymer Films

Zhengliang Su、Zaira I. Bedolla‐Valdez、Letian Wang 等 9 位作者2019-10-17ACS Applied Materials & Interfaces

Organic semiconductors (OSCs) offer a new avenue to the next-generation electronics, but the lack of a scalable and inexpensive nanoscale patterning/deposition technique still limits their use in electronic applications. Recently, a new lithographic etching technique has been introduced that uses molecular dopants to…

Organic Electronics and PhotovoltaicsZnO doping and propertiesThin-Film Transistor Technologies

Exploring a Fused 2-(Thiophen-2-yl)thieno[3,2-b]thiophene (T-TT) Building Block to Construct n-Type Polymer for High-Performance All-Polymer Solar Cells

Ning An、Huijuan Ran、Yanfang Geng 等 9 位作者2019-10-17ACS Applied Materials & Interfaces

In the field of all-polymer solar cells, exploring new electron-donating units (D) to match with electron-accepting units (A) is an important subject to promote the performance of D–A-type polymer acceptors. Herein, we developed a fused D unit 2-(thiophen-2-yl)thieno[3,2- b ]thiophene (T-TT) derivated from the famous…

Organic Electronics and PhotovoltaicsConducting polymers and applicationsSemiconductor materials and interfaces

Hydrazine-Selective Fluorescent Turn-On Probe Based on Ortho-Methoxy-Methyl-Ether (o-MOM) Assisted Retro-aza-Henry Type Reaction

Yuna Jung、Nam Kyoo Park、Jae Seung Kang 等 4 位作者2019-10-17Sensors

Hydrazine (N2H4) is one of the most widely used industrial chemicals that can be utilized as a precursor of pesticides, pharmaceutics, and rocket propellant. Due to its biological and environmental toxicity with potential health risks, various sensing tools have been developed. Among them, fluorescence-based molecular…

Advanced biosensing and bioanalysis techniquesMolecular Sensors and Ion DetectionLuminescence and Fluorescent Materials

Synthesis, structural, mechanical, and in vitro evaluations of NiFe 2 O 4 /ZrO 2 composites

Subina Raveendran、Mohd. Imran K. Khan、Arunkumar Dhayalan 等 4 位作者2019-10-17Journal of the American Ceramic Society

Abstract NiFe 2 O 4 /ZrO 2 composite with varied compositional ratios was formed through solution‐based sol‐gel synthetic route. The ability to retain NiFe 2 O 4 /ZrO 2 composite structures was dependent on the concomitant effect of temperature gradient and precursor concentration. The crystallization of t ‐ZrO 2 alon…

Advancements in Battery MaterialsAluminum Alloys Composites PropertiesMagnetic Properties and Synthesis of Ferrites

Broadband light emission induced by laser absorption and optimized by thermal injection in Nd 3+ :Y 2 SiO 5 ceramic powder

Nikifor Rakov、Glauco S. Maciel2019-10-17Journal of the American Ceramic Society

Abstract Laser‐induced broadband (white) light emission has been studied in different particle systems for use in light‐emitting devices. The photoinduced phenomenon occurs above a certain excitation power threshold and it is generally studied under vacuum conditions. In this work, the phenomenon is studied in neodymi…

Luminescence Properties of Advanced MaterialsSolid State Laser TechnologiesOptical properties and cooling technologies in crystalline materials

Impact of the storage atmosphere enriched with ozone on the quality of Lycopersicon esculentum tomatoes

Anna Onopiuk、Andrzej Półtorak、Iwona Wojtasik‐Kalinowska 等 7 位作者2019-10-17Journal of Food Processing and Preservation

The objective of the paper was to determine ozonization impact on antioxidant activity and physical properties of three tomato cultivars: Reconquista, Rapanui, and Sacher. Tomatoes were subjected to gaseous ozone with concentration of 0.9 and 2.5 mg/L (c1, c2) for 30 and 120 min (t1, t2) and then stored for 15 days in…

Phytochemicals and Antioxidant ActivitiesPostharvest Quality and Shelf Life ManagementNanocomposite Films for Food Packaging

In Situ Generation of Fullerene from a Poly(fullerene)

Hugo Santos Silva、Hasina H. Ramanitra、Bruna Andressa Bregadiolli 等 12 位作者2019-10-17Journal of Polymer Science Part B Polymer Physics

ABSTRACT This article appraises the thermal, photo‐ and photo‐oxidative stability of poly(fullerene)‐alt‐[bismethylbenzene)]s (PFBMBs) prepared by the atom transfer radical addition polymerization (ATRAP) with particular attention paid to their use as additives in organic photovoltaic devices. PFBMBs are of interest d…

Organic Electronics and PhotovoltaicsCarbon Nanotubes in CompositesFullerene Chemistry and Applications

Dielectric anisotropy in PCPB/MBBA mixtures showing the dual frequency characteristic

Yoshinori Takikawa、Kosuke Kaneko、Shunsuke Odani 等 5 位作者2019-10-17Japanese Journal of Applied Physics

Abstract Dielectric dispersions in the homogeneous ( ε ⊥ ) and the homeotropic ( ε ∥ ) aligned cells in the nematic phase of PCPB/MBBA mixtures have been measured in the frequency range between 100 Hz and 1 MHz. The Cole–Cole formula accounting for DC conduction has been found to reproduce dielectric dispersions well…

Material Dynamics and PropertiesMicrowave and Dielectric Measurement TechniquesDielectric materials and actuators

Field theory approach to the quantum transport in Weyl semimetals

Michele Burrello、E. Guadagnini、L. Lepori 等 4 位作者2019-10-17Physical review. B./Physical review. B

We analyze the structure of the surface states and Fermi arcs of Weyl semimetals as a function of the boundary conditions parametrizing the Hamiltonian self-adjoint extensions of a minimal model with two Weyl points. These boundary conditions determine both the pseudospin polarization of the system on the surface and…

Graphene research and applications2D Materials and ApplicationsTopological Materials and Phenomena