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Graded composition Cd$_x$Zn$_{1-x}$Te films grown by Isothermal Close Space Sublimation technique

O. de Melo、A. Domínguez、K. Gutiérrez Z-B 等 10 位作者2019-09-18arXiv

Graded composition CdxZn1-xTe films were prepared by growing several alternate layers of CdTe and ZnTe by the Isothermal Close Space Sublimation technique. The thickness of both kinds of layers was modified along the structure to produce an increase of the average concentration of CdTe towards the surface of the films…

Materials Science

Application-oriented strain-hardening engineering of high-manganese steels

Christian Haase、Franz Roters、Angela Quadfasel2019-09-18arXiv

The outstanding mechanical properties of high-manganese steels (HMnS) are a result of their high strain-hardenability. That is facilitated by strong suppression of dynamic recovery, predominant planar glide, and the activation of additional deformation mechanisms, such as transformation-induced plasticity (TRIP) and t…

Materials Science

Semilocal exchange-correlation potentials for solid-state calculations: Current status and future directions

Fabien Tran、Jan Doumont、Leila Kalantari 等 6 位作者2019-09-18Journal of Applied Physics

Kohn-Sham (KS) density functional theory (DFT) is a very efficient method for calculating various properties of solids as, for instance, the total energy, the electron density, or the electronic band structure. The KS-DFT method leads to rather fast calculations; however, the accuracy depends crucially on the chosen a…

Rare-earth and actinide compoundsHeusler alloys: electronic and magnetic propertiesThermal Expansion and Ionic Conductivity

Novel magnetic field tuning of quantum spin excitations in a weakly coupled $S=$1/2 Heisenberg spin chain as seen from NMR

Long Ma、Z. Wang、L. Hu 等 6 位作者2019-09-18arXiv

We report our NMR study of the spin excitations in the quasi-one dimensional (1D) $S=1/2$ quantum magnet CH$_3$NH$_3$Cu(HCOO)$_3$ lying in the 1D-3D dimensional crossover regime with Dzyaloshinskii-Moriya(DM) interactions. Above $T_N$, the spinon excitation is observed from the constant $1/T_1$ at low temperatures con…

Materials ScienceStrongly Correlated Electrons

Cancer‐Targeted Nanomedicine: Overcoming the Barrier of the Protein Corona

Ayan Kumar Barui、Jun Yong Oh、Batakrishna Jana 等 5 位作者2019-09-18Advanced Therapeutics

Abstract Nanomedicines exploit the unusual physicochemical and biological properties of nanoparticles, including their nanoscopic size, high surface‐area‐to‐volume ratio, easy surface modification, and biocompatibility. Among various therapeutic and diagnostic applications of nanomedicines, cancer‐targeted drug delive…

Nanoparticle-Based Drug DeliveryPolymer Surface Interaction StudiesCharacterization and Applications of Magnetic Nanoparticles

Vectorial Holograms with a Dielectric Metasurface: Ultimate Polarization Pattern Generation

Ehsan Arbabi、Seyedeh Mahsa Kamali、Amir Arbabi 等 4 位作者2019-09-18ACS Photonics

High Resolution Image Download MS PowerPoint Slide Controlling the polarization of light has been of interest for various applications in laser materials processing, display systems, and spectroscopy among others. Despite great advancements, the level of control over the polarization of light using naturally birefring…

Metamaterials and Metasurfaces ApplicationsAdvanced Antenna and Metasurface TechnologiesAdvanced Optical Imaging Technologies

Bilayer Lateral Heterostructures of Transition-Metal Dichalcogenides and Their Optoelectronic Response

Prasana K. Sahoo、Shahriar Memaran、Florence A. Nugera 等 11 位作者2019-09-18ACS Nano

Two-dimensional lateral heterojunctions based on monolayer transition-metal dichalcogenides (TMDs) have received increasing attention given that their direct band gap makes them very attractive for optoelectronic applications. Although bilayer TMDs present an indirect band gap, their electrical properties are expected…

Perovskite Materials and Applications2D Materials and ApplicationsMXene and MAX Phase Materials

Machine Learning-Assisted Array-Based Biomolecular Sensing Using Surface-Functionalized Carbon Dots

Subhendu Pandit、Tuseeta Banerjee、Indrajit Srivastava 等 5 位作者2019-09-18ACS Sensors

Fluorescent array-based sensing is an emerging differential sensing platform for sensitive detection of analytes in a complex environment without involving a conventional "lock and key" type-specific interaction. These sensing techniques mainly rely on different optical pattern generation from a sensor array and their…

Advanced biosensing and bioanalysis techniquesCarbon and Quantum Dots ApplicationsBiosensors and Analytical Detection

One-Step Facile Synthesis of Nitrogen-Doped Carbon Dots: A Ratiometric Fluorescent Probe for Evaluation of Acetylcholinesterase Activity and Detection of Organophosphorus Pesticides in Tap Water and Food

Qi Xiao、Jiandong Yao、Xu Chu 等 6 位作者2019-09-18Journal of Agricultural and Food Chemistry

Evaluation of acetylcholinesterase (AChE) activity and determination of organophosphorus pesticides (OPs) are of great importance for the clinical diagnosis of several serious diseases correlated with their variations in human blood serum. In this study, a highly selective and sensitive ratiometric fluorescent probe w…

Electrochemical sensors and biosensorsCarbon and Quantum Dots ApplicationsNanocluster Synthesis and Applications

Unraveling Dual Aggregation‐Induced Emission Behavior in Steric‐Hindrance Photochromic System for Super Resolution Imaging

Hong Yang、Mengqi Li、Chong Li 等 7 位作者2019-09-18Angewandte Chemie International Edition

Unprecedented dual aggregation-induced emission (AIE) behavior based on a steric-hindrance photochromic system is presented, with incorporation one or two bulky aryl groups, resulting in different flexibleness. The dual AIE behavior of open and closed isomers can be explained by restriction of intramolecular rotation…

Porphyrin and Phthalocyanine ChemistryLuminescence and Fluorescent MaterialsPhotochromic and Fluorescence Chemistry

Catalytic Effect on CO2 Electroreduction by Hydroxyl-Terminated Two-Dimensional MXenes

Hetian Chen、Albertus D. Handoko、Jiewen Xiao 等 9 位作者2019-09-18ACS Applied Materials & Interfaces

Electrocatalysis represents a promising method to generate renewable fuels and chemical feedstock from the carbon dioxide reduction reaction (CO 2 RR). However, traditional electrocatalysts based on transition metals are not efficient enough because of the high overpotential and slow turnover. MXenes, a family of two-…

Advanced Photocatalysis TechniquesCO2 Reduction Techniques and CatalystsMXene and MAX Phase Materials

Plasmon-Mediated Chemical Reactions on Nanostructures Unveiled by Surface-Enhanced Raman Spectroscopy

Chao Zhan、Xue‐Jiao Chen、Yifan Huang 等 5 位作者2019-09-18Accounts of Chemical Research

Surface plasmons (SPs) originating from the collective oscillation of conduction electrons in nanostructured metals (Au, Ag, Cu, etc.) can redistribute not only the electromagnetic fields but also the excited carriers (electrons and holes) and heat energy in time and space. Therefore, SPs can engage in a variety of pr…

Gold and Silver Nanoparticles Synthesis and ApplicationsAdvanced biosensing and bioanalysis techniquesElectrochemical Analysis and Applications

Metal Doping of Au 25 (SR) 18 – Clusters: Insights and Hindsights

Wenwen Fei、Sabrina Antonello、Tiziano Dainese 等 8 位作者2019-09-18Journal of the American Chemical Society

The study of the structures and properties of atomically precise gold nanoclusters is the object of active research worldwide. Recently, research has been also focusing on the doping of metal nanoclusters through introduction of noble metals, such as platinum, and less noble metals, such as cadmium and mercury. Previo…

Gold and Silver Nanoparticles Synthesis and ApplicationsNanocluster Synthesis and ApplicationsAdvanced Nanomaterials in Catalysis

Synergistic Effects of Nitrogen Doping on MXene for Enhancement of Hydrogen Evolution Reaction

Thi Anh Le、Quoc Viet Bui、Ngoc Quang Tran 等 7 位作者2019-09-18ACS Sustainable Chemistry & Engineering

Earth-abundant, nonprecious, and efficient electrocatalysts for effective hydrogen evolution reaction (HER) are crucial for future large-scale green energy production. Low-cost two-dimensional MXenes have been widely studied in energy-storage devices owing to their unique chemical and physical properties and have rece…

Electrocatalysts for Energy ConversionAdvanced Photocatalysis TechniquesMXene and MAX Phase Materials

Construction of Hierarchical NiCo 2 O 4 @Ni-MOF Hybrid Arrays on Carbon Cloth as Superior Battery-Type Electrodes for Flexible Solid-State Hybrid Supercapacitors

Geng Li、Haoran Cai、Xiaolong Li 等 7 位作者2019-09-18ACS Applied Materials & Interfaces

Metal–organic frameworks (MOFs) have been considered as a class of promising electrode materials for supercapacitors owing to their large surface area, rich porosity, and variable redox sites; however, direct application of pristine MOFs in energy storage has been largely hindered by their poor electrical conductivity…

Advancements in Battery MaterialsSupercapacitor Materials and FabricationAdvanced battery technologies research

Enabling long-lived organic room temperature phosphorescence in polymers by subunit interlocking

Suzhi Cai、Huili Ma、Huifang Shi 等 19 位作者2019-09-18Nature Communications

Long-lived room temperature phosphorescence (LRTP) is an attractive optical phenomenon in organic electronics and photonics. Despite the rapid advance, it is still a formidable challenge to explore a universal approach to obtain LRTP in amorphous polymers. Based on the traditional polyethylene derivatives, we herein p…

Advanced Sensor and Energy Harvesting MaterialsOrganic Light-Emitting Diodes ResearchLuminescence and Fluorescent Materials

Boosting Performance of Na–S Batteries Using Sulfur-Doped Ti 3 C 2 T x MXene Nanosheets with a Strong Affinity to Sodium Polysulfides

Weizhai Bao、Christopher E. Shuck、Wenxue Zhang 等 6 位作者2019-09-18ACS Nano

Sodium–sulfur batteries using abundant elements offer an attractive alternative to currently used batteries, but they need better sulfur host materials to compete with lithium-ion batteries in capacity and cyclability. We report an in situ sulfur-doping strategy to functionalize MXene nanosheets by introducing heteroa…

Advanced Battery Materials and TechnologiesAdvanced Memory and Neural ComputingMXene and MAX Phase Materials

Oxygen Vacancy Promoted O 2 Activation over Perovskite Oxide for Low-Temperature CO Oxidation

Ji Yang、Siyu Hu、Yarong Fang 等 15 位作者2019-09-18ACS Catalysis

The insights on the primary active oxygen specie and its relation with oxygen vacancy is essential for the design of low-temperature oxidation catalysts. Herein, oxygen vacancy-rich La 0.8 Sr 0.2 CoO 3 with an ordered macroporous structure was integrated on the commercial ceramic monolith in large scale without additi…

Catalytic Processes in Materials ScienceCatalysis and Oxidation ReactionsElectronic and Structural Properties of Oxides

Effects of the Hydrophilic–Lipophilic Balance of Alternating Peptides on Self-Assembly and Thermo-Responsive Behaviors

Abu Bin Ihsan、Mahmuda Nargis、Yasuhito Koyama2019-09-17International Journal of Molecular Sciences

-substituted poly(Gly-alter-Val) peptides were successfully synthesized for the systematic evaluation of the micellization behavior of alternating peptides. Three-component polymerization employing an aldehyde, a primary ammonium chloride, and potassium isocyanoacetate afforded four alternating peptides in excellent y…

Advanced Polymer Synthesis and CharacterizationSurfactants and Colloidal SystemsSupramolecular Self-Assembly in Materials

Spreading Dynamics and the Residence Time of Ellipsoidal Drops on a Solid Surface

Sungchan Yun、Inhyeon Kim2019-09-17Langmuir

Controlling bouncing drops on solid surfaces has gained significant attention because of the benefit of low residence time in anti-icing and self-cleaning strategies. Given that the drop shape at the moment of impact is classically assumed to be spherical, the residence time on a flat surface is bounded by a theoretic…

Surface Modification and SuperhydrophobicityFluid Dynamics and Heat TransferFluid Dynamics Simulations and Interactions