Materials Literature
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Nonplanar distortions of tetrapyrroles are prevalent in the hemes of hemoproteins, the pigments of photosynthetic proteins, and cofactor F430 of methylreductase. The nonplanarity of these porphyrin cofactors is currently believed to influence factors in the biological activity of the proteins, in part, because the por…
Steady-state, water-gas-shift kinetics were measured on model, ceria-supported, Pd, Pt, and Rh catalysts and compared to rates obtained on alumina-supported catalysts. When ceria was calcined at low temperatures prior to addition of the precious metal, the specific rates were found to be identical for each of the meta…
Todayto explain or understand.Ball is particularly good at demonstrating how the details fit into the big picture, and how present-day work relates to sometimes faroff goals.Ultimately,
Photocatalytic decomposition of water into H2 and O2 on Cu2O under visible light irradiation is investigated; the photocatalytic water splitting on Cu2O powder proceeds without any noticeable decrease in the activity for more than 1900 h.
We formulate a procedure to reconstruct the structure of general random heterogeneous media from limited morphological information by extending the methodology of Rintoul and Torquato [J. Colloid Interface Sci. 186, 467 (1997)] developed for dispersions. The procedure has the advantages that it is simple to implement…
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Preface List of Symbols CHAPTER 1. DIFFUSIVE FLUXES AND MATERIAL PROPERTIES 1.1 INTRODUCTION 1.2 BASIC CONSTITUTIVE EQUATIONS 1.3 DIFFUSIVITIES FOR ENERGY, SPECIES, AND MOMENTUM 1.4 MAGNITUDES OF TRANSPORT COEFFICIENTS 1.5 MOLECULAR INTERPRETATION OF TRANSPORT COEFFICIENTS 1.6 LIMITATIONS ON LENGTH AND TIME SCALES Ref…
This article reviews recent progress in the study of the transition-metal mediated self-assembly of two- and three-dimensional synthetic receptors. Whereas macrocyclization under kinetic control is undoubtedly an unfavorable process, the self-assembly strategy offers quite efficient methods for constructing macrocycle…
Mechanically challenged tissue-engineered organs, such as blood vessels, traditionally relied on synthetic or modified biological materials for structural support. In this report, we present a novel approach to tissue-engineered blood vessel (TEBV) production that is based exclusively on the use of cultured human cell…
Directing the structure and function of polythiophenes (PTs) can lead to remarkable enhancements in the electronic and photonic properties of the resultant materials, as discussed in this comprehensive review of the chemistry and synthesis of PTs. The Figure illustrates the use of heteroatom-functionalized PTs as chem…
A new class of materials for catalysis have been intensively investigated, that is, ‘bimetallic nanoparticles’. Extensive studies of non-supported bimetallic nanoparticle dispersions, stabilized by polymers or ligands, started only about 10 years ago. Many preparative procedures have been proposed, and detailed charac…
1. Introduction K. Otsuka and C. M. Wayman 2. Mechanism of shape memory effect and superelasticity K. Otsuka and C. M. Wayman 3. Ti-Ni shape memory alloys T. Saburi 4. Cu-based shape memory alloys T. Tadaki 5. Ferrous shape memory alloys T. Maki 6. Fabrication of shape memory alloys Y. Suzuki 7.Characteristics of shap…
We present an introduction to surface-enhanced Raman scattering (SERS) which reviews the basic experimental facts and the essential features of the mechanisms which have been proposed to account for the observations. We then review very recent fundamental developments which include: SERS from single particles and sing…
This is an introductory textbook for graduate students and researchers from various fields of science who wish to learn about carbon nanotubes. The field is still at an early stage, and progress continues at a rapid rate. This book focuses on the basic principles behind the physical properties and gives the background…
The Kawerau geothermal field has supplied steam to heat exchangers, turbines and other engineering plants for more than 40 years. The main construction materials are carbon and low alloy steels which show good performance for well casing and well-head equipment, pipelines and energy plant. These materials form passiva…
An analysis is made of two-stage metallisation of insulator surfaces. Laser ablation of the surfaces of a number of insulators (activation stage) creates, on the irradiated surface, catalytic centres capable of reducing metals (deposition stage) in special solutions. Autocatalytic deposition spreads a metal over the w…
The detection of partial discharge (PD) in high voltage insulation is an effective way to determine dielectric faults in the early stages of development. Partial discharge detection in a power transformer was made possible by use of the acoustic detection technique and also by the UHF detection technique. Floating met…
In this text, radioactivity and the chemical reactions of radionuclons within the different areas of a nuclear power plant are discussed. The text concentrates on commercially-operated light water reactors which currently represent the greatest faction of the world's nuclear power capacity. In 1994, the total electric…
The main purpose of the study was to test the applicability of standard fuel oil methods developed for petroleum-based fuels to pyrolysis liquids. In addition, research on sampling, homogeneity, stability, miscibility and corrosivity was carried out. The standard methods have been tested for several different pyrolysi…
In order to explain the positive temperature coefficient of the visible index of refraction of fused silica I develop a simple model which assumes a single ultraviolet resonance. Assuming thermal broadening and using the Kramers- Kronig relations leads to a temperature coefficient in qualitative, but not quantitative,…