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Recent developments in the coordination chemistry of porphyrin complexes containing non-metallic and semi-metallic elements

Penelope J. Brothers2002-04-01Journal of Porphyrins and Phthalocyanines

Recent advances in the chemistry of main group porphyrin complexes are surveyed. New, unprecedented structural types for porphyrin complexes which have been revealed from the recent reports of boron and tellurium porphyrins are described. Advances in the preparation and reactivity of Group 14 (silicon and tin) and Gro…

Advanced Chemical Physics StudiesPorphyrin and Phthalocyanine ChemistrySurface Chemistry and Catalysis

Current status of field-emission displays

S. Itoh、Mitsuru Tanaka2002-04-01Proceedings of the IEEE

Field-emission displays (FEDs) promise to provide high-resolution emissive flat-panel displays. Currently, the development of Spindt-type FEDs is at an advanced stage with monocolor FEDs being supplied to the marketplace. Full-color FEDs are getting ready for commercial production. A number of other field-emission ele…

Carbon Nanotubes in CompositesChemical and Physical Properties of MaterialsNanotechnology research and applications

Arterial Replacement with Compliant Hierarchic Hybrid Vascular Graft: Biomechanical Adaptation and Failure

Hongbing He、Takehisa Matsuda2002-04-01Tissue Engineering

Two types of hybrid vascular grafts were hierarchically structured with an autologous smooth muscle cell (SMC)-inoculated collagen gel layer and an endothelial cell (EC) monolayer, and wrapped with different elasomeric scaffolds. Type A graft was wrapped with poly(urethane)-nylon mesh, and type B graft was wrapped wit…

Aortic Disease and Treatment ApproachesElectrospun Nanofibers in Biomedical ApplicationsTissue Engineering and Regenerative Medicine

Gloss Stability of Whey‐Protein/Plasticizer Coating Formulations on Chocolate Surface

Sang‐Yun Lee、Kirsten L. Dangaran、John M. Krochta2002-04-01Journal of Food Science

ABSTRACT: : Four different whey‐protein‐isolate (WPI)/plasticizer formulations were compared to determine which provided the most gloss and which was most stable with time when applied on chocolates. The 4 plasticizers studied were glycerol, polyethylene glycol 400 (PEG 400), propylene glycol (PG), and sucrose, all in…

Nanocomposite Films for Food Packagingbiodegradable polymer synthesis and propertiesMicroencapsulation and Drying Processes

Relating monomer to centre-of-mass distribution functions in polymer solutions

Vincent Krakoviack、J. P. Hansen、Ard A. Louis2002-04-01Europhysics Letters (EPL)

A relationship between the measurable monomer-monomer structure factor, and the centre-of-mass (CM) structure factor of dilute or semi-dilute polymer solutions is derived from Ornstein-Zernike relations within the "polymer reference interaction site model" (PRISM) formalism, by considering the CM of each polymer as an…

Polymer crystallization and propertiesMaterial Dynamics and PropertiesTheoretical and Computational Physics

Effect of a Transverse Tensile Stress on the Electric‐Field‐Induced Domain Reorientation in Soft PZT: In Situ XRD Study

Xiaoping Li、Wan Y. Shih、James S. Vartuli 等 6 位作者2002-04-01Journal of the American Ceramic Society

The effect of a transverse tensile stress on the electric‐field‐induced 90°‐domain reorientation in tetragonal lead zirconate titanate (PZT) near the morphotropic phase boundary was investigated in situ using X‐ray diffraction (XRD). The XRD intensity ratio, I (002) / I (200) , which represents the ratio of the volume…

Ferroelectric and Piezoelectric MaterialsMultiferroics and related materialsElectronic and Structural Properties of Oxides

Effect of Lateral Cracks on Fracture Toughness Determined by the Surface‐Crack‐in‐Flexure Method

George D. Quinn、Jonathan A. Salem2002-04-01Journal of the American Ceramic Society

The surface‐crack‐in‐flexure (SCF) method uses a Knoop indenter to create small, semielliptical surface precracks in beam specimens. Lateral cracks may interfere with the primary median crack and cause errors of up to 10% in determination of fracture toughness, particularly for materials for which the fracture toughne…

Advanced ceramic materials synthesisMetal and Thin Film MechanicsAdvanced Surface Polishing Techniques

Structure and defects of vapor-phase-grown diamond nanocrystals

Xin Jiang、Chun‐Lin Jia2002-04-01Applied Physics Letters

Diamond nanocrystalline films are prepared by the ion bombardment-assisted gas vapor synthesis technique. The phase quality, morphology and microstructure of the films are investigated by means of Raman spectroscopy, scanning electron microscopy, and high-resolution transmission electron microscopy. The grain size in…

High-pressure geophysics and materialsDiamond and Carbon-based Materials ResearchIon-surface interactions and analysis

Mechanism of brittle fracture in nonceramic insulators

Javier Vallejo Montesinos、R.S. Gorur、Barzin Mobasher 等 4 位作者2002-04-01IEEE Transactions on Dielectrics and Electrical Insulation

The results of an investigation concerning a mechanism of brittle fracture in glass reinforced plastic (GRP) rods used in non-ceramic insulators (NCI) are presented. Commercial grade GRP rods and GRP rods from actual insulators were exposed to ultra-pure water (UPW) and acids while being subjected to mechanical stress…

Concrete and Cement Materials ResearchHigh voltage insulation and dielectric phenomenaConcrete Corrosion and Durability

Performance of Hydrotalcite Conversion Treatments on AA2024-T3 When Used in a Coating System

R. B. Leggat、W. Zhang、R. G. Buchheit 等 4 位作者2002-04-01CORROSION

Hydrotalcite (HT) conversion coatings are a possible alternative to chromate conversion coatings (CCC) for the pretreatment of aluminum aerospace alloys, but they must meet several criteria for acceptance. Relevant to acceptance are the abilities of these coatings to provide stand-alone corrosion protection, suitable…

Corrosion Behavior and InhibitionBauxite Residue and UtilizationMaterials Engineering and Processing

Leakage current and charge in RTV coated insulators under pollution conditions

D. Devendranath、Channakeshava Channakeshava、Arun Rajkumar2002-04-01IEEE Transactions on Dielectrics and Electrical Insulation

Room temperature vulcanizing (RTV) silicone rubber coating has excellent leakage current suppression characteristics. It is used extensively on porcelain and glass insulators in pollution prone areas as an anti-pollution measure. A pollution aging chamber has been fabricated and an on line 4-channel personal computer…

Surface Modification and SuperhydrophobicityHigh voltage insulation and dielectric phenomenaThermal Analysis in Power Transmission

Mathematical Simulation of the Perception of Fabric Thermal and Moisture Sensations

Z. Wang、Yi Li、Y.L. Kowk 等 4 位作者2002-04-01Textile Research Journal

A mathematical simulation of the perception of thermal and moisture sensations is developed using mathematical models that describe the physical mechanisms of heat and moisture transfer in fabrics, the neurophysiological responses of thermoreceptors. and the psychoneurophysiological relationships identified from exper…

Thermoregulation and physiological responsesTextile materials and evaluationsColor perception and design

One-Shot-Laser-Pulse-Induced Cooperative Charge Transfer Accompanied by Spin Transition in a Co-Fe Prussian Blue Analog at Room Temperature

Naonobu Shimamoto、Shin‐ichi Ohkoshi、Osamu Sato 等 4 位作者2002-04-01Chemistry Letters

Abstract A one-shot-laser-pulse (6 ns) irradiation converted the electronic state of Na0.68Co1.20[Fe(CN)6]·3.7H2O from FeII(S=0)-CN-CoIII(S=0) to FeIII(S=1/2)-CN-CoII(S=3/2) at room temperature. This photochemical reaction was observed only above the power density of 45 mJ pulse-1 cm-2, and its quantum yield amounted…

Photosynthetic Processes and MechanismsMagnetism in coordination complexesPorphyrin and Phthalocyanine Chemistry

Melamine Formaldehyde Core Decomposition as the Key Step Controlling Capsule Integrity: Optimizing the Polyelectrolyte Capsule Fabrication

Changyou Gao、Sergio Moya、Edwin Donath 等 4 位作者2002-04-01Macromolecular Chemistry and Physics

Capsule integrity as a function of the acid concentration, the acid-adding sequence, the outermost layer of the deposited multilayers, and the capsule wall thickness was investigated using confocal laser scanning microscopy. Optimal conditions for fabricating good quality polyelectrolyte capsules templated on melamine…

Polymer Surface Interaction StudiesDendrimers and Hyperbranched PolymersBlood properties and coagulation

Electroreduction of Molecular Oxygen on Poly-Iron-Tetraaminophthalocyanine Modified Electrodes

Galo Ramı́rez、E. Trollund、Maurício Isaacs 等 7 位作者2002-04-01Electroanalysis

In this work we have investigated the electrocatalytic activity for O2 reduction of monomeric (FePcTA) and polymeric (poly-FePcTA) iron tetraaaminophthalocyanine, deposited on glassy carbon. The activity of the electropolymerized ligand (poly-H2PcTA) was also investigated. Its activity is much lower than the activity…

Electrochemical sensors and biosensorsPorphyrin and Phthalocyanine ChemistryElectrochemical Analysis and Applications

Scattering mechanisms and electronic behavior in transparent conducting ZnxIn2Ox+3 indium–zinc oxide thin films

Corinne Marcel、Negar Naghavi、G. Couturier 等 5 位作者2002-04-01Journal of Applied Physics

Thin films of ZnxIn2Ox+3 (x=2, 3, 4, 5, 7, 9, 11, 13, and 15) were grown by pulsed laser deposition and their electronic properties characterized. Through resistivity, Hall mobility and carrier concentration measurements as a function of temperature, we found that whatever the composition, these films behave as n-type…

ZnO doping and propertiesGa2O3 and related materialsElectronic and Structural Properties of Oxides

Decomposition of Dolomite Monitored by Neutron Thermodiffractometry

Antonio H. De Aza、Miguel Á. Rodríguez、José Luis Rodrı́guez 等 8 位作者2002-04-01Journal of the American Ceramic Society

Dolomite powder from Coín (Spain) was heated in air at a constant rate of 2°C/min to 1000°C, while neutron diffraction patterns were collected every 150 s. Rietveld refinement was applied and raw intensity data were used to monitor decomposition. The full process happened in two stages: dolomite decomposition to give…

High-pressure geophysics and materialsCalcium Carbonate Crystallization and InhibitionX-ray Diffraction in Crystallography

Kinetics of the Initial Stage of Sintering from Shrinkage Data: Simultaneous Determination of Activation Energy and Kinetic Model from a Single Nonisothermal Experiment

Luis A. Pérez‐Maqueda、José M. Criado、C. Real2002-04-01Journal of the American Ceramic Society

A new method for the kinetic analysis of the initial stage of sintering for constant‐heating‐rate data has been proposed. Unlike all of the methods previously reported in the literature, this new method proposed here allows the simultaneous determination of the activation energy and the kinetic model from a single dil…

Iron and Steelmaking ProcessesAdvanced materials and compositesThermal and Kinetic Analysis

Localized relaxation’s strength and its mimicry of glass-softening thermodynamics

G. P. Johari、G. Power、J. K. Vij2002-04-01The Journal of Chemical Physics

The dielectric relaxation strength of the β process, Δεβ, in a rigid-molecular glass of 16.6 mol % chlorobenzene cis-decalin mixture increases slowly with temperature, T, until the glass-softening range is reached, and thereafter it increases rapidly, i.e., (dΔεβ/dT) increases at Tg relatively abruptly. This is remark…

Material Dynamics and PropertiesGlass properties and applicationsThermodynamic properties of mixtures

Dendrimer grafts for delivery of 5-fluorouracil.

Tripathi Pk、Khopade Aj、Surekha Nagaich 等 6 位作者2002-04-01PubMed

Polyamidoamine (PAMAM) dendrimers were prepared by linking methyl methacrylate and ethylenediamine successively on an amine core. Surface modification of PAMAM dendrimer was done by fatty acid grafting converting them to a unimolecular micellar system (Dendrimer grafts). IR, 1H NMR, 13C NMR studies confirmed the struc…

Advanced Polymer Synthesis and CharacterizationDendrimers and Hyperbranched PolymersFerrocene Chemistry and Applications