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Molecularly-mediated assembly of gold nanoparticles with interparticle rigid, conjugated and shaped aryl ethynyl structures

Hong Wei Yan、Stephanie I. Lim、Ying–Jun Angela Zhang 等 9 位作者2010-01-01Chemical Communications

The rigidity, conjugation, and shape-persistent architectures of aryl ethynyls of V, Y, and X shapes serve as an ideal model system for defining interparticle structures, which have been demonstrated for the mediated assembly of gold nanoparticles.

Gold and Silver Nanoparticles Synthesis and ApplicationsQuantum Dots Synthesis And PropertiesNanocluster Synthesis and Applications

Joining of silicon nitride with silicon slurry via reaction bonding and post sintering

Naoki Kondo、Hideki Hyuga、Hideki Kita2010-01-01Journal of the Ceramic Society of Japan

Joining of silicon nitride parts by a silicon nitride joint without mechanical pressure was attempted. Reaction-bonded silicon nitride (RBSN) parts were joined using a silicon slurry by a slip-cast technique, followed by reaction bonding and post-sintering. The sintering process changed the original RBSN parts and the…

Advanced ceramic materials synthesisMetal and Thin Film MechanicsMXene and MAX Phase Materials

Elastic Properties of Green Composites Reinforced with Ramie Twisted Yarn

Rie NAKAMURA、Koichi GODA、Junji NODA 等 4 位作者2010-01-01Journal of Solid Mechanics and Materials Engineering

This paper suggests a theoretical model to estimate Young's modulus of green composites reinforced by natural fiber twisted yarns considering a migration structure. First, we made fully green composites using biodegradable resins and ramie twisted yarns to develop a biodegradable material, and then investigated the ef…

Natural Fiber Reinforced CompositesTextile materials and evaluationsStructural Analysis and Optimization

Photoinduced reduction and heat-induced oxidation of silver in transparent RSiO3/2 and RSiO3/2–TiO2 films

Go Kawamura、Shizuka Sato、Toshihiro Kogure 等 7 位作者2010-01-01Physical Chemistry Chemical Physics

Photoinduced reduction, resulting in nanoparticle formation, and heat-induced oxidation of doped silver have been demonstrated in silsesquioxane (RSiO(3/2)) and RSiO(3/2)-TiO(2) films (R = methyl, vinyl, and glycidoxypropyl) synthesized via the sol-gel method. The occurrence of redox behavior in the doped silver, i.e.…

Gold and Silver Nanoparticles Synthesis and ApplicationsGas Sensing Nanomaterials and SensorsLaser-Ablation Synthesis of Nanoparticles

An extraordinary boron-mediated 16R-channel-containing trivalent vanadium phosphite with unique solid state redox properties

Hui‐Lin Huang、Sue‐Lein Wang2010-01-01Chemical Communications

For the first time, an open-framework oxysalt of trivalent vanadium is demonstrated, prepared from a single tetravalent vanadium source under acidic hydrothermal conditions. The borate-incorporated structure features intersecting 2D 16R channels and unusual solid-state redox properties confirmed by K-edge XANES, EPR s…

Metal-Organic Frameworks: Synthesis and ApplicationsZeolite Catalysis and SynthesisPolyoxometalates: Synthesis and Applications

Thermodynamic analysis and characterization of alloys in Bi-Cu-Sb system

Dragana Živković、Duško Minić、Dragan Manasijević 等 8 位作者2010-01-01Journal of Mining and Metallurgy Section B Metallurgy

The results of thermodynamic analysis and characterization of some alloys in Bi-Cu-Sb lead-free solder system are presented in this paper. Thermodynamic analysis was done using general solution model, while optic microscopy, hardness and electroconductivity measurements were used in order to determine structural, mech…

Electronic Packaging and Soldering TechnologiesMetallurgical Processes and ThermodynamicsMetallurgical and Alloy Processes

Characterization of Interfacial Stress Transfer Ability by Dynamic Mechanical Analysis of Cellulose Fiber Based Composite Materials

Karin Almgren、E. Kristofer Gamstedt2010-01-01Composite Interfaces

The stress transfer ability at the fiber–matrix interface of wood fiber composites is known to affect the mechanical properties of the composite. The evaluation of interface properties at the level of individual fibers is however difficult due to the small dimensions and variability of the fibers. The dynamical mechan…

Mechanical Behavior of CompositesNatural Fiber Reinforced CompositesFiber-reinforced polymer composites

Variation of the ground spin state in homo- and hetero-octanuclear copper(ii) and nickel(ii) double-star complexes with a meso-helicate-type metallacryptand core

Emilio Pardo、Marie‐Claire Dul、Rodrigue Lescouëzec 等 11 位作者2010-01-01Dalton Transactions

Homo- and heterometallic octanuclear complexes of formula Na₂{[Cu₂(mpba)₃][Cu(Me₅dien)]₆}-(ClO₄)₆·12H₂O (1), Na₂{[Cu₂(Mempba)₃][Cu(Me₅dien)]₆}(ClO₄)₆·12H₂O (2), Na₂{[Ni₂(mpba)₃]-[Cu(Me₅dien)]₆}(ClO₄)₆·12H₂O (3), Na₂{[Ni₂(Mempba)₃][Cu(Me₅dien)]₆}(ClO₄)₆·9H₂O (4), {[Ni₂(mpba)₃][Ni(dipn)(H₂O)]₆}(ClO₄)₄·12.5H₂O (5), and {…

Magnetism in coordination complexesLanthanide and Transition Metal ComplexesAdvanced NMR Techniques and Applications

Influence on the Electro-Migration Resistance by Line Width and Average Grain Size along the Longitudinal Direction of Very Narrow Cu Wires

Khyoupin Khoo、Suguru Tashiro、Jin Onuki2010-01-01MATERIALS TRANSACTIONS

The influence of microstructures of Cu wires on electromigration (EM) resistance has been investigated using Cu wires with various line widths from 50 to 280 nm and line heights of 300 nm or 500 nm. A strong line width dependence of median time to failure was observed as the EM resistance decreases substantially with…

Electronic Packaging and Soldering TechnologiesElectrodeposition and Electroless CoatingsCopper Interconnects and Reliability

Determination and evaluation of solubility parameter of satranidazole using dioxane-water system

PB Rathi2010-01-01Indian Journal of Pharmaceutical Sciences

Satranidazole, a potent broad spectrum antiprotozoal, is a poorly water-soluble drug and has low bioavailability on oral administration. One of the important methods to improve the solubility and bioavailability of a less water-soluble drug is by the use of cosolvents. The solubility enhancement produced by binary ble…

Drug Solubulity and Delivery SystemsAnalytical Chemistry and ChromatographyCrystallization and Solubility Studies

Growth Laws of Bilayer Anodized Tantalum Oxide Films Formed in Phosphoric Acid

Jennifer D. Sloppy、Digby D. Macdonald、Elizabeth C. Dickey2010-01-01Journal of The Electrochemical Society

Experimentally determined growth laws of bilayer tantalum oxide films formed by anodizing sputter-deposited tantalum anodes in a 0.1 M phosphoric acid electrolyte are reported. Transmission electron microscopy, Fourier transform IR reflectance spectroscopy, and wet capacitance measurements are used to measure the grow…

Corrosion Behavior and InhibitionHydrogen embrittlement and corrosion behaviors in metalsAnodic Oxide Films and Nanostructures

Novel CrIII dinuclear complexes supported by salicyloylhydrazono dithiolane and dithiane ligands: Synthesis, stability, crystal structures and magnetic properties

Nicolas Clément、Clément Toussaint、Guillaume Rogez 等 10 位作者2010-01-01Dalton Transactions

We hereby report the synthesis, crystal structures and magnetic characterizations of three novel Cr(III) complexes: a mononuclear Cr(III)(HL((1)))₃ species along with two dinuclear μ-methoxo Cr(III)₂(μ-OMe)₂(HL)₄ (H₂L((1)): 2-salicyloylhydrazono-1,3-dithiolane; H₂L((2)): 2-salicyloylhydrazono-1,3-dithiane). EPR studie…

Metal complexes synthesis and propertiesMagnetism in coordination complexesMetal-Catalyzed Oxygenation Mechanisms

Inactivation of Saccharomyces cerevisiae by CO2 Microbubbles at a Lower Pressure and Near Ambient Temperature

Fumiyuki Kobayashi、Y. Hayata、Hiromi Ikeura 等 5 位作者2010-01-01Transactions of the ASABE

The ability of CO2 microbubbles (MB-CO2) to inactivate Saccharomyces cerevisiae suspended in a physiological saline solution at a pressure lower than 2.0 MPa was investigated. A 6-log reduction in the S. cerevisiae population was induced by MB-CO2 at 40C and 2.0 MPa after a 50 min treatment in a physiological saline s…

Microbial Inactivation MethodsPickering emulsions and particle stabilization

Novel liquid crystalline hyperbranched polyesters with interior 4,7-diphenyl-2,1,3-benzothiadiazole units

Moriyuki Sato、Yôko Kobayashi、Toshihiro Shimizu 等 4 位作者2010-01-01Polymer Chemistry

Novel hyperbranched (HB) polyesters with interior 4,7-diphenyl-2,1,3-benzothiadiazole (DBT) units were prepared by melt polycondensation of a dimethyl ester derivative of DBT (BMBT) (A2 monomer) with 2-hydroxymethyl-2-methyl-1,3-propanediol (HMP) (B3 monomer) at various mole ratios (A2/B3) via an A2 + B3 approach. The…

Luminescence and Fluorescent MaterialsDendrimers and Hyperbranched PolymersSynthesis and properties of polymers

Preparation of polycrystalline VO2 films on glass and TiO2/glass substrates by means of excimer laser assisted metal organic deposition

Masami Nishikawa、Tomohiko Nakajima、T. Manabe 等 5 位作者2010-01-01Journal of the Ceramic Society of Japan

An excimer laser assisted metal organic deposition process for the preparation of vanadium dioxide (VO2) films is described. When a precursor film grown on a silica glass substrate by preheating at 300°C was irradiated with a KrF laser at room temperature in air, the film was crystallized into polycrystalline VO2 phas…

Advanced Memory and Neural ComputingTransition Metal Oxide NanomaterialsGa2O3 and related materials

Quantitative Analysis of Semicrystalline Blends SAXS Data: Theoretical Modeling versus Linear Correlation Function

Mohamed Fatnassi、Fadhel Ben Cheikh Larbi、Jean Louis Halary2010-01-01International Journal of Polymer Science

This paper compares the results yielded by two methods of small-angle X-ray scattering data analysis for semicrystalline polymer blends. The first method is based on the use of a theoretical modeling for isotropic samples and a subsequent curve fitting. The second one is a more familiar method, based on the calculatio…

Polymer crystallization and propertiesPolymer Nanocomposites and Propertiesbiodegradable polymer synthesis and properties

Improvement of Durability of Hybrid Ceramic Ball Bearings in Liquid Hydrogen at 3 Million DN (120,000 rpm)

Masataka Nosaka、Satoshi Takada、Makoto Yoshida 等 6 位作者2010-01-01Tribology online

The durability of a hybrid ceramic 25-mm-bore ball bearing having a single outer land-guided retainer was evaluated and improved in liquid hydrogen at speeds up to 120,000 rpm (120,000 min-1) (3 million DN) by comparing the propagation of superficial thermal microcracks on Si3N4 balls at various speeds. To select a to…

Advanced ceramic materials synthesisNuclear Materials and PropertiesAdvanced materials and composites

Prediction of protein-protein interactions in dengue virus coat proteins guided by low resolution cryoEM structures

Rupali A. Gadkari、Narayanaswamy Srinivasan2010-01-01BMC Structural Biology

BACKGROUND: Dengue virus along with the other members of the flaviviridae family has reemerged as deadly human pathogens. Understanding the mechanistic details of these infections can be highly rewarding in developing effective antivirals. During maturation of the virus inside the host cell, the coat proteins E and M…

Protein Structure and DynamicsMosquito-borne diseases and controlEnzyme Structure and Function

Visible Quantum Cutting in Tb[sup 3+]-Doped BaGdB[sub 9]O[sub 16] via Downconversion

Huijuan Zhang、Yuhua Wang、Ye Tao 等 7 位作者2010-01-01Journal of The Electrochemical Society

The photoluminescence properties of under vacuum UV and UV excitation were investigated, and visible quantum cutting through downconversion was observed in this phosphor. Upon excitation, one UV photon absorbed by could be split into more than one visible photon emitted by through cross relaxation and direct energy tr…

Luminescence Properties of Advanced MaterialsGlass properties and applicationsRadiation Detection and Scintillator Technologies

Towards In-line Determination of EVA Gel Content during PV Modules Lamination Processes

Heng‐Yu Li、Laure‐Emmanuelle Perret‐Aebi、Ricardo Théron 等 6 位作者2010-01-01Infoscience (Ecole Polytechnique Fédérale de Lausanne)

Poly (ethylene-co-vinyl acetate) (EVA) is the major polymer used for photovoltaic (PV) modules encapsulation. Its degree of cross-linking (related to its gel content) is taken as a major quality reference. Differential Scanning Calorimetry (DSC) has been proven to be fast and effective but is to determine the gel cont…

Transition Metal Oxide NanomaterialsChemical and Physical Properties of MaterialsNanotechnology research and applications