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Fabrication and Electrical Properties of Lead Zirconate Titanate Thick Films

H. Daniel Chen、Krishna Udayakumar、C.J. Gaskey 等 6 位作者1996-08-01Journal of the American Ceramic Society

Thick films of lead zirconate titanate of the morphotropic phase boundary composition, Pb(Zr 0.52 Ti 0.48 )O 3 , have been fabricated on platinum‐buffered silicon using a modified sol–gel spin‐coating technique. Crack‐free films of 12‐μm thickness can be uniformly deposited on 3‐in.‐diameter wafers with high yield and…

Ferroelectric and Piezoelectric MaterialsAcoustic Wave Resonator TechnologiesDielectric materials and actuators

Experimental evidence for the dynamic Jahn-Teller effect inLa0.65Ca0.35MnO3

Pengcheng Dai、Jiandi Zhang、H. A. Mook 等 6 位作者1996-08-01Physical review. B, Condensed matter

Recently, it has been argued that a strong electron-phonon interaction arising from the Jahn-Teller splitting of the outer Mn $d$ level plays a crucial role in understanding the nonmetal-to-metal transition observed in the ${\mathrm{La}}_{1\ensuremath{-}x}{A}_{x}\mathrm{Mn}{\mathrm{O}}_{3}(A=\mathrm{C}\mathrm{a},\phan…

Magnetic and transport properties of perovskites and related materialsRare-earth and actinide compoundsAdvanced Condensed Matter Physics

Internal acetylene unit linked para to the aromatic ring as a crosslink site for polyimide

Tsutomu Takeichi、Masaaki Tanikawa1996-08-01Journal of Polymer Science Part A Polymer Chemistry

Crosslinking behavior of internal acetylene units linked para to the aromatic rings was investigated by preparing polyimide from 4,4′-diaminodiphenylacetylene (p-intA) and 2,2′-bis(3,4-dicarboxyphenyl)hexafluoropropane dianhydride (6FDA). Polyimide was also prepared from 1,4-phenylenediamine (PDA) and 6FDA for compari…

Fiber-reinforced polymer compositesSynthesis and properties of polymersTribology and Wear Analysis

Crystallization of ZBLAN Glass

S. Aasland、Tor Grande1996-08-01Journal of the American Ceramic Society

The glass transition, onset crystallization, solidus, and liquidus temperatures of a ZBLAN glass have been measured by differential thermal analysis in a sealed Pt ampoule. The onset crystallization was observed at 335°C for a powdered glass, while for a monolithic glass, prepared by in situ quenching in the Pt capsul…

Luminescence Properties of Advanced MaterialsMaterial Dynamics and PropertiesGlass properties and applications

UV-Curable Transparent Adhesives for Fabricating Precision Optical Components

Norio Murata、Shiro Nishi、Shigeru Hosono1996-08-01The Journal of Adhesion

UV-curable transparent epoxy adhesives have been specifically developed for the fabrication of optical communictions precision devices. The newly developed adhesives using cylohexane type fluoro-epoxy as the base resin and speherical quartz filler have extremely low volume shrinkage of 1.2% during curing and the cured…

Semiconductor Lasers and Optical DevicesAdvanced optical system designSynthesis and properties of polymers

Thermal Conductivity Measurements on UO2+x from 300 to 1,400 K

Masaki Amaya、Toshio KUBO、Yoshiaki KOREI1996-08-01Journal of Nuclear Science and Technology

In order to evaluate the thermal conductivity of oxidized fuel pellets of leaker fuel rods, UO2+x samples with x between 0.00 and 0.20 were prepared by an oxidation or a sintering method. Sample thermal diffusivities were measured by using a laser flash method from 300 to 1,400 K and their thermal conductivities were…

Nuclear reactor physics and engineeringNuclear Materials and PropertiesThermal and Kinetic Analysis

A new class of transparent polymeric materials. I. Production and properties of an alternating copolymer ofN-methylmaleimide and isobutene

Toru Doi、Yoshihiko Sugiura、Satoshi Yukioka 等 4 位作者1996-08-01Journal of Applied Polymer Science

An alternating copolymer of N-methylmaleimide and isobutene was produced by a radical precipitation polymerization method. The copolymer thus produced is a new class of transparent polymeric material that shows a unique balance of optical, thermal, and mechanical properties. The visible light transmittance was more th…

Advanced Polymer Synthesis and CharacterizationSynthesis and properties of polymersPhotopolymerization techniques and applications

Formation and Control of Agglomerates in Alumina Powder

Mikito Kitayama、Joseph A. Pask1996-08-01Journal of the American Ceramic Society

High‐purity alumina powder with submicrometer particle size was colloidally dispersed and classified in either water or ethanol to remove agglomerates from as‐received powder. After the slurries were dried, fine alumina particles cohered to form agglomerates, which were “hard” when formed in a water slurry, and “soft”…

Advanced ceramic materials synthesisAdvanced materials and compositesNuclear materials and radiation effects

Aluminium behaviour and stability in electrolyte

Laurent Legrand、A. Tranchant、R. Messina1996-08-01Electrochimica Acta

Cathodic and anodic behaviour of aluminium has been investigated in AlCl3DMSO2—dimethylsulfone—(1 mole/kg) electrolyte at 130 °C by current reversal chronopotentiometry (CRC) and chronoamperometry. Al deposition study showed that a diffusion-limited current density close to 83 mA cm−2 is reached for potentials less th…

Corrosion Behavior and InhibitionExtraction and Separation ProcessesMolten salt chemistry and electrochemical processes

Polyurethane‐elastomer‐actuator

Toshihiro Hirai、Hiroki Sadatoh、Tsutomu Ueda 等 7 位作者1996-08-01Die Angewandte Makromolekulare Chemie

Abstract Polyurethane elastomers were investigated as electrically active materials for actuators. Components in hard segment and soft segment in the elastomers were varied. The elastomers with excellent electrostrictive properties were limited to those which had soft segments of polyesters and polylactones. It turned…

Conducting polymers and applications

Heat capacity and thermodynamic properties of nearly stoichiometric wustite from 13 to 450 K

Svein Stølen、Ronny Glöckner、Fredrik Grønvold 等 5 位作者1996-08-01American Mineralogist

Other| August 01, 1996 Heat capacity and thermodynamic properties of nearly stoichiometric wustite from 13 to 450 K Svein Stolen; Svein Stolen University of Oslo, Department of Chemistry, Oslo, Norway Search for other works by this author on: GSW Google Scholar Ronny Glockner; Ronny Glockner Search for other works by…

Clay minerals and soil interactionsIron oxide chemistry and applicationsMineralogy and Gemology Studies

Correlation between dielectric constant and chemical structure of sodium silicate glasses

C. H. Hsieh、Himanshu Jain、E. I. Kamitsos1996-08-01Journal of Applied Physics

The chemical structure of sodium aluminosilicate glasses is determined by high resolution x-ray photoelectron spectroscopy (XPS) as silicon is gradually replaced by aluminum. A well-defined chemical state is found for silicon, aluminum, and sodium atoms, while three different environments are identified for oxygen ato…

Ferroelectric and Piezoelectric MaterialsGlass properties and applicationsMicrowave Dielectric Ceramics Synthesis

Change in Layer Charge of Smectites and Smectite Layers in Illite/Smectite During Diagenetic Alteration

Tsutomu Satō、Takashi Murakami、Takashi Watanabe1996-08-01Clays and Clay Minerals

Abstract The changes in amount and location of layer charge during diagenetic alteration have been investigated for smectites and smectite layers of illite/smectite interstratified minerals (I/S) by X-ray powder diffraction analysis with various expansion behavior tests: 1) ethylene glycol (EG) solvation (XRD); 2) K-s…

Soil and Unsaturated FlowClay minerals and soil interactionsIron oxide chemistry and applications

Electrochemical Corrosion Potential Models for Boiling-Water Reactor Applications

Chien‐Chung Lin、Y. J. Kim、L. W. Niedrach 等 4 位作者1996-08-01CORROSION

The electrochemical corrosion potential (ECP) of stainless steel (SS) was measured under simulated boiling-water reactor (BWR) coolant circuit conditions using a rotating cylinder electrode (RCE). Based upon those measurements, an empirical model was developed to predict ECP of structure materials in a BWR primary cir…

Corrosion Behavior and InhibitionHydrogen embrittlement and corrosion behaviors in metalsErosion and Abrasive Machining

Analysis of the Excitation and Emission Spectra of Tungstates and Molybdate

Nobuhiro Saito、Noriyuki Sonoyama、Tadayoshi Sakata1996-08-01Bulletin of the Chemical Society of Japan

Abstract The excitation and emission spectra of CaWO4, MgWO4, PbWO4, ZnWO4, and CaMoO4 were analyzed by a configurational coordination model. The spectral line shapes simulated by a configurational coordination model with a singlet ground state and an excited triplet state well explained the line shape of the luminesc…

Luminescence Properties of Advanced MaterialsRadiation Detection and Scintillator TechnologiesNuclear materials and radiation effects

Deep center luminescence in p-type CdTe

J. Krustok、V. Valdna、K. Hjelt 等 4 位作者1996-08-01Journal of Applied Physics

The deep-level photoluminescence (PL) emission in the 1.1 eV spectral region in p-type CdTe:Cl polycrystalline samples was studied as a function of the excitation laser power and temperature. The relatively broad 1.1 eV PL band has a nonsymmetrical shape which can be easily changed by varying the excitation laser powe…

Luminescence Properties of Advanced MaterialsPerovskite Materials and ApplicationsAdvanced Semiconductor Detectors and Materials

A Model to Compute Phase Diagrams in Oxides with Empirical or First‐Principles Energy Methods and Application to the Solubility Limits in the CaO–MgO System

P. D. Tepesch、A. F. Kohan、G. D. Garbulsky 等 11 位作者1996-08-01Journal of the American Ceramic Society

The CaO–MgO system is used as a prototype system to evaluate the accuracy of several energy and entropy approximations for predicting solid‐state phase diagrams in ionic materials. Configurational disorder between the cations is parameterized with the cluster expansion technique. The vibrational contribution to the fr…

High-pressure geophysics and materialsMetallurgical Processes and ThermodynamicsCrystallization and Solubility Studies

Synthesis and Characterization of Liquid Crystalline Molecules Containing the Quinoline Unit

Long‐Li Lai、Chin-Hang Wang、Wei-Pin Hsieh 等 4 位作者1996-08-01Molecular crystals and liquid crystals science technology. Section A, Molecular crystals and liquid crystals/Molecular crystals and liquid crystals science and technology. Section A, Molecular crystals and liquid crystals

A homologous series of heterocyclic liquid crystals containing the quinoline unit have been synthesized and characterized. These compounds show a smectic phase at low temperatures. The quinoline unit containing lone pair electrons introduces a significant dipole moment resulting in attractive forces to form a smectic…

Liquid Crystal Research AdvancementsPorphyrin and Phthalocyanine ChemistrySynthesis and Properties of Aromatic Compounds

Are cured thermoset resins inhomogeneous?

Karel Dušek1996-08-01Die Angewandte Makromolekulare Chemie

Abstract This question was addressed using various methods to monitor the process of curing and state of the final network. Attention was particularly focused on the possible inhomogeneous network formation as a consequence of the crosslinking process. An analysis of experimental data has revealed that some cured resi…

Epoxy Resin Curing ProcessesSynthesis and properties of polymersPhotopolymerization techniques and applications

Internal stress and strain in heavily boron-doped diamond films grown by microwave plasma and hot filament chemical vapor deposition

W. L. Wang、M.C. Polo、G. Sánchez 等 5 位作者1996-08-01Journal of Applied Physics

The internal stress and strain in boron-doped diamond films grown by microwave plasma chemical vapor deposition (MWCVD) and hot filament CVD (HFCVD) were studied as a function of boron concentration. The total stress (thermal+intrinsic) was tensile, and the stress and strain increased with boron concentration. The str…

Metal and Thin Film MechanicsSemiconductor materials and devicesDiamond and Carbon-based Materials Research