Materials Literature
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ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTDeuteration effects on the miscibility and phase separation kinetics of polymer blendsHsinjin Yang, Mitsuhiro Shibayama, Richard S. Stein, Nobuyuki Shimizu, and Takeji HashimotoCite this: Macromolecules 1986, 19, 6, 1667–1674Publication Date (Print):June 1, 1986Publication H…
The aim of any diffraction experiment is to obtain reproducible data of high accuracy and precision so that the data can be correctly interpreted and analyzed. Various methods of sample preparation have been devised so that reproducibility, precision and accuracy can be obtained. The success of a diffraction experimen…
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTMorphology control of binary polymer mixtures by spinodal decomposition and crystallization. 1. Principle of method and preliminary results on PP/EPRNobuyuki Inaba, Kazuo Sato, Shyunichi Suzuki, and Takeji HashimotoCite this: Macromolecules 1986, 19, 6, 1690–1695Publication…
CELLULOSE STRUCTURE AND BIOSYNTHESIS: Natural Celluloses Recent X-Ray Crystallographic Studies of Celluloses Structure of Cellulose - Solvent Complexes Pea Cellulose and Xyloglucan: Biosynthesis and Biodegradation The Primary Cell Wall: A New Model Structure, Swelling and Bonding of Cellulose Fibers Cellulose Carbamat…
Abstract New mechanism of cationic polymerization of cyclic ethers and acetals consisting in the activated (e.g. protonated) monomer addition to the electrically neutral macromolecule e.g.: magnified image is discussed. It is shown, that when the ‐OH in the tail‐group is more nucleophilic than monomer itself this mech…
Abstract The processing, structure and properties of polyetheretherketone (PEEK) semicrystalline thermoplastic as matrix polymer for high performance composites has been investigated in this work. In processing PEEK samples with different crystallinities, a specially designed mold capable of cooling the polymer in exc…
. Raman spectra are reported for powdered crystalline anorthite, sanidine, leucite, a-nepheIme, an~ ~-carnegie~te ~nd glasses .ofCaA12Si20s (An), KAlSi30s (Or), and NaAlSiO. (Ne) composItIOns. Quahtatlve compansons between features in the spectra of the isochemical c~stal~ a~d glasses indicate that the glasses maintai…
Etude de l'influence des procedures de reduction de donnees, des modeles de facteur de temperature et des modeles de deformation sur les resultats
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTDisubstituted tungstosilicates. 1. Synthesis, stability, and structure of the lacunary precursor polyanion of a tungstosilicate .gamma.-SiW10O368-Jacqueline Canny, Andre Teze, Rene Thouvenot, and Gilbert HerveCite this: Inorg. Chem. 1986, 25, 13, 2114–2119Publication Date (P…
A Landau-Ginzburg approach to an interface with finite thickness incorporates surface tension, anisotropy, curvature, and dynamics of the interface along with supercooling. Various aspects are rigorous.
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTPolyhedral oligometallasilsesquioxanes (POMSS) as models for silica-supported transition-metal catalysts. Synthesis and characterization of (C5Me5)Zr[(Si7O12)(c-C6H11)7]Frank J. FeherCite this: J. Am. Chem. Soc. 1986, 108, 13, 3850–3852Publication Date (Print):June 1, 1986Pu…
The crystal structure of synthetic BeO, bromellite, has been determined at several pressures to 5.0 GPa and several temperatures to 1183 K. The single variable atomic-positional parameter, z of oxygen, does not vary significantly with pressure, but does undergo a small increase with temperature. The hexagonal axial ra…
The selected research activities on integrated optics components and devices using periodic structures are reviewed, with emphasis on the authors' works employing the electron-beam writing technique. The periodic structures include static gratings and dynamic ones produced through acoustooptic (AO) and electrooptic (E…
The characteristics of electrochemically produced polyaniline as the active material of secondary batteries were studied in aqueous electrolytes. The cell of the type, , has the maximum capacity of 108 Ah/kg and the energy density of 111 Wh/kg. The coulombic efficiency was close to 100% over at least 2000 complete cyc…
Oligonucleotide-directed mutagenesis was used to investigate the nature of transition state stabilization in the catalytic mechanism of the serine protease, subtilisin BPN'. The gene for this extracellular enzyme from Bacillus amyloliquefaciens has been cloned and expressed in Bacillus subtilis. In the transition stat…
We have studied the behavior of a chemically synthesized polypyrrole as electrode material. The different electrochemical methods that we have used for this characterization, namely, cyclic voltammetry, ac impedance measurements, and cyclic chronopotentiometry, have evidenced the role of the low frequency capacitance…
Nb‐doped BaTiO 3 has been prepared with various Ba/(Ti + Nb) ratios such that single‐phase products will be obtained if the charged donor center is assumed to be compensated in turn by Ba vacancies, Ti vacancies, equal concentrations of the two cation vacancies, oxygen interstitials, or electrons. For air‐Fired sample…
Copper single crystals oriented for multiple slip with [001] axes have been deformed in tension and investigated by X-ray line-broadening measurements using {002} Bragg reflections. The intensity distributions of the broadened line profiles of the deformed crystals exhibit an asymmetry whose ‘sign’ depends on the part…
A model was constructed for electromigration failure where both Fickian diffusion and mass transport due to the electromigration driving force are considered concurrently. The solution to the resulting diffusion equation yields a current exponent of 2 and an activation energy consistent with grain-boundary self-diffus…
REVIEWSpresented in this section begin with two papers which sketch how to calculate the forces in hydrodynamic journal bearings and tilting pad bearings.Six papers then address instabilities due to: internal energy dissipation; asymmetries (such as bearing stiffnesses or inertias) which introduce time dependent param…