Materials Literature
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One of the problems in relation to predicting the rates of defect growth in structures displaying stress corrosion cracking (SCC) is that knowledge relating to realistic stress corrosion crack velocities is very limited. In monotonic slow strain rate tests (SSRTs) taken to total failure at usual strain rates and in te…
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTBroensted basicity of atomic oxygen on the gold(110) surface: reactions with methanol, acetylene, water, and ethyleneDuane A. Outka and Robert J. MadixCite this: J. Am. Chem. Soc. 1987, 109, 6, 1708–1714Publication Date (Print):March 1, 1987Publication History Published onli…
To ascertain the upper limit of protein thermostability and to evaluate the introduction of additional -S-S- bridges for the enhancement of protein thermostability by site-directed mutagenesis, the stability of cystine residues at 100 degrees C has been investigated in a number of unrelated proteins. All proteins stud…
Polycrystalline specimens of the intermetallic compound Al3Ti with the D022-type structure have been deformed under compression at 25–860°C. At temperatures below 620°C, specimens fracture with very small fracture strain since extremely localized deformation occurs and cracks are initiated in intensely deformed region…
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTBinuclear manganese(III) complexes of potential biological significanceJohn E. Sheats, Roman S. Czernuszewicz, G. Charles Dismukes, Arnold L. Rheingold, Vasili Petrouleas, JoAnne Stubbe, William H. Armstrong, Robert H. Beer, and Stephen J. LippardCite this: J. Am. Chem. Soc.…
The Eu3⊕- and Tb3⊕-cryptates of the ligands 1–3 can function as molecular light converters. The complexes give characteristic 1H-NMR spectra, and the Eu3⊕-cryptate can be electrochemically reversibly reduced (−535 mV vs SCE).
The effect of quenching in the stability of the phases of different commercial clinkers and so its flexotraction and compression strength at 7 and 28 days curing time have been studied. The clinkers were reheated at 1.576 ºC, for a period of thirty minutes, and were quenched in two different ways:-outside at air tempe…
The application of fluorescence light microscopy in the textural study of Portland cement clinker, specially its porosity, is presented. Principles and types of the technique are commented and the suggested sample preparation method is described. The use of fluorescence microscopy allows an easier study of the clinker…
In this work, which is the following of others, the performance of a portland cement of a high initial resistance (P-550-ARI) —with a calculated content (Bogue) of 39,2% of C3S, of 25,7% of C2S, of 9,9% of C3A, of 12,0% of C4AF and of 6,9% of CaSO4 — is studied when it is submitted to the action of deionized water run…
In this work, a Venezuelan-bitumen of newtonian nature was modified by Friedel and Crafts reaction, changing it in new materials that present pseudoplastic characteristics, with very different properties from the original product. These new materials are harder and have less thermical susceptibility and allow us to us…
The inexistence of quantitative data on steel behaviour in carbonated mortar and concrete have driven us to carry out a serie of tests to know the kinetic of the corrosion rebars. Polarization Resistance was the technique used to determine the corrosion rate of the rebars. In the present tests a first study with morta…
Abstract This report describes the electrochemical preparation and properties of polyaniline films prepared on a bare platinum electrode and on electrodes precoated with a thin film of inert polymer. Films were prepared and studied in several aqueous acid electrolytes including sulfuric, hydrochloric, nitric, trifluor…
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTThermal DeNOx Controlling nitrogen oxides emissions by a noncatalytic processRichard K. LyonCite this: Environ. Sci. Technol. 1987, 21, 3, 231–236Publication Date (Print):March 1, 1987Publication History Published online1 May 2002Published inissue 1 March 1987https://pubs.ac…
The aperiodic crystal picture associates the glass transition with freezing into a nonperiodic structure. Dynamics in the glassy state involves activated jumps between different aperiodic free energy minima. Activation barriers may be estimated through the use of freezing theory and the theory of dense solids. The res…
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTDual emission from an ortho-metalated iridium(III) complexK. A. King and R. J. WattsCite this: J. Am. Chem. Soc. 1987, 109, 5, 1589–1590Publication Date (Print):March 1, 1987Publication History Published online1 May 2002Published inissue 1 March 1987https://pubs.acs.org/doi/…
The quasi-chemical theory and the quasi-lattice theory are discussed with a view to obtaining information about concentration fluctuations, S CC (0), and the short-range order parameter, α 1 , for regular and compound-forming molten alloys. The influence of the coordination number z and the interchange energy ω on the…
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTThermodynamic study of lanthanide complexes of 1,4,7-triazacyclononane-N,N',N"-triacetic acid and 1,4,7,10-tetraazacyclododecane-N,N',N",N'''-tetraacetic acidW. P. Cacheris, S. K. Nickle, and A. D. SherryCite this: Inorg. Chem. 1987, 26, 6, 958–960Publication Date (Print):Ma…
The electro-optic, linear, and nonlinear optical properties of KDP and its isomorphs are reviewed. Figures of merit for doubling and tripling by sum-frequency generation are presented and used to compare and contrast these crystals for nonlinear optics devices. Current research areas, such as high-average-power applic…