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Synthesis and stability of silica-substituted hydrogarnet Ca3Al2 Si3-xO12-4x(OH)4x

T. G. Jappy、F. P. Glasser1991-01-01Advances in Cement Research

A range of garnet structured compositions can be synthesized between the end members C 3 AH 6 (hydrogarnet) and C 3 AS 3 (grossularite) at different temperatures and pressures. The extent of this series at 95°C and a pressure of one bar has been investigated. The synthesis of a range of garnets from C 3 AH 6 to C 3 AS…

High-pressure geophysics and materialsCrystal Structures and PropertiesSolid-state spectroscopy and crystallography

Polyphosphazenes with glucosyl and methylamino, trifluoroethoxy, phenoxy, or (methoxyethoxy)ethoxy side groups

Harry R. Allcock、Shawn R. Pucher1991-01-01Macromolecules

ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTPolyphosphazenes with glucosyl and methylamino, trifluoroethoxy, phenoxy, or (methoxyethoxy)ethoxy side groupsHarry R. Allcock and Shawn R. PucherCite this: Macromolecules 1991, 24, 1, 23–34Publication Date (Print):January 1, 1991Publication History Published online1 May 200…

Flame retardant materials and properties

Electrostatic Lens Systems

D. W. O. Heddle1991-01-01OpenAlex

The optics of simple lenses. The motion of charged particles in an electrostatic field. The determination of the axial potential. The optics of simple lens systems. Aberrations. The LENSYS program. Technical aspects of LENSYS. References.

Electron and X-Ray Spectroscopy Techniques

Electric breakdown strength of aromatic polymers: dependence on film thickness and chemical structure

Bertil Helgée、P. Bjellheim1991-01-01IEEE Transactions on Electrical Insulation

The AC electric breakdown field strength F/sub B/ of aromatic polymer films as a function of sample thickness was investigated. A power-law dependence of F/sub B/ on sample thickness was found. The exponential parameter of the power law was shown to correlate with the electron accepting properties of the polymer. Reas…

High voltage insulation and dielectric phenomenaPower Transformer Diagnostics and InsulationElectrostatic Discharge in Electronics

Optical detection of partial discharges using fluorescent fiber

R. Mangeret、J. Farenc、Bingjian Ai 等 6 位作者1991-01-01IEEE Transactions on Electrical Insulation

An optoelectronic system for detecting partial discharges in a sheltered HV device is described. The system consists of a fluorescent plastic optical fiber, with photomultipliers or photodiodes measuring the light intensity at the end of the fiber. The result depends on various factors that might influence the optical…

High voltage insulation and dielectric phenomenaPlasma Diagnostics and ApplicationsMagneto-Optical Properties and Applications

Diffusion of Brownian particles with hydrodynamic interaction and hard core repulsion

B. Cichocki、B. U. Felderhof1991-01-01The Journal of Chemical Physics

We study diffusion in a dilute system of Brownian particles with hydrodynamic interaction and hard core repulsion. We assume that the hard core has a radius larger than the hydrodynamic one. The short-time and long-time self-diffusion coefficient, as well as the collective diffusion coefficient, are calculated exactly…

Phase Equilibria and ThermodynamicsMaterial Dynamics and PropertiesTheoretical and Computational Physics

Cation distribution and magnetic properties of titanomagnetitesFe3−xTixO4(0≤x<1)

Z. Kąkol、J. Sabol、J. M. Honig1991-01-01Physical review. B, Condensed matter

Magnetization measurements are presented for the ${\mathrm{Fe}}_{3\mathrm{\ensuremath{-}}\mathit{x}}$${\mathrm{Ti}}_{\mathit{x}}$${\mathrm{O}}_{4}$ series in the range 0\ensuremath{\le}x1. A new model of ${\mathrm{Fe}}^{3+\mathrm{\ensuremath{-}}}$${\mathrm{Fe}}^{2+}$ cation distribution is proposed based on saturation…

Multiferroics and related materialsMagnetic Properties and Synthesis of FerritesAdvanced Condensed Matter Physics

Kinetic analysis of coke gasification based on non-crystal/crystal ratio of carbon.

Yoshiaki Kashiwaya、Kuniyoshi Ishii1991-01-01ISIJ International

Gasification of metallurgical coke was studied at 1 000, 1 200 and 1 400°C with Ar-CO-CO2 mixtures. Reaction of coke in blast furnace is dominant from 1 000°C. And at the same time, growth of graphite crystal in coke begins around the temperature.In present paper, two types of carbon structure were classified by means…

Thermochemical Biomass Conversion ProcessesIron and Steelmaking ProcessesGraphite, nuclear technology, radiation studies

Experimental analysis of transmission line parameters in high-speed GaAs digital circuit interconnects

K. Kızıloḡlu、Nadir Dagli、G.L. Matthaei 等 4 位作者1991-01-01IEEE Transactions on Microwave Theory and Techniques

Transmission line properties of typical high-speed interconnects were experimentally investigated by fabricating and characterizing coplanar strips on semi-insulating GaAs substrates. The strips have thicknesses of about 2500 AA or 5000 AA and widths of 4, 6, or 8 mu m so as to be representative of on-chip interconnec…

Electromagnetic Compatibility and Noise Suppression3D IC and TSV technologiesCopper Interconnects and Reliability

Cobalt( II )–tetraphenylporphyrin–pyridine complex fixed on a glassy carbon electrode and its prominent catalytic activity for reduction of carbon dioxide

Takashi Atoguchi、Akiko Aramata、Akio Kazusaka 等 4 位作者1991-01-01Journal of the Chemical Society Chemical Communications

Cobalt(II)–tetraphenylporphyrin (CoIItpp)-fixed glassy carbon (GC) electrodes were prepared using 4-aminopyridine (pyNH2) in the form of CoIItpp–pyNH–CO/GC, which were active for electroreduction of CO2 to CO at potentials 100 mV more positive than water-soluble CoII porphyrins, and the overall turnover number of CoII…

Porphyrin and Phthalocyanine ChemistryMetal-Catalyzed Oxygenation MechanismsCO2 Reduction Techniques and Catalysts

A New DNA Target Model for Track Structure Calculations and Its First Application to I-125 Auger Electrons

Ekkehard Pomplun1991-01-01International Journal of Radiation Biology

A DNA target model has been developed, based on the geometrical co-ordinates of individual atoms. This model is used to analyse DNA damage produced by Auger electron tracks from the decay of 125I. The high resolution of this target model enables the distinction between direct and indirect electron hits, i.e. hits insi…

DNA and Nucleic Acid ChemistryX-ray Spectroscopy and Fluorescence AnalysisElectron and X-Ray Spectroscopy Techniques

Lamb waves in a functionally gradient material plate and its transient response. (Part 1. Theory).

Gui-Rong LIU、Junji Tani、Tadashi OHYOSHI1991-01-01TRANSACTIONS OF THE JAPAN SOCIETY OF MECHANICAL ENGINEERS Series A

The numerical methods which have been proposed by the present authors for Lamb waves in an anisotropic laminated plate and its transient responses are expanded for the wave propagation analysis of functionally gradient material (FGM) plates. The material properties of the plate change gradually in the thickness direct…

Thermoelastic and Magnetoelastic PhenomenaStructural mechanics and materialsElasticity and Wave Propagation

Formation and properties of rate earth aluminosilicate glasses

Jeffrey T. Kohli、James E. Shelby1991-01-01Physics and chemistry of glasses

On etudie les zones de formation vitreuse et differentes proprietes de verres du systeme: Al 2 O 3 −SiO 2 −R 2 O x (ou R 2 O x =Nd 2 O 3 , Sm 2 O 3 , Tb 4 O 7 , Er 2 O 3 , Y 2 O 3 )

Glass properties and applicationsMaterial Science and Thermodynamics

Nitrite-bound five-coordinate low-spin iron(II) model complex for the prosthetic group of nitrite reductase with an unusually large quadrupole splitting. Synthesis, Moessbauer properties, and molecular structure of the complex (nitro)(.alpha.,.alpha.,.alpha.,.alpha.-tetrakis(o-pivalamidophenyl)porphinato)iron(II)

Habib Nasri、Yaning Wang、Huynh Boi Hanh 等 4 位作者1991-01-01Journal of the American Chemical Society

ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTNitrite-bound five-coordinate low-spin iron(II) model complex for the prosthetic group of nitrite reductase with an unusually large quadrupole splitting. Synthesis, Moessbauer properties, and molecular structure of the complex (nitro)(.alpha.,.alpha.,.alpha.,.alpha.-tetrakis…

Metal complexes synthesis and propertiesMagnetism in coordination complexesMetal-Catalyzed Oxygenation Mechanisms

Poly(hydroxybutyrate-hydroxyvalerate) microspheres containing progesterone: Preparation, morphology and release properties

Nutan Gangrade、James C. Price1991-01-01Journal of Microencapsulation

The biodegradable polyesters, poly(hydroxybutyrate) (PHB) and poly(hydroxybutyrate-hydroxyvalerate) (PHBV) were investigated for use as sustained delivery carriers of a model drug, progesterone. Spherical microspheres containing the drug were prepared by an emulsion solvent-evaporation method with gelatin as an emulsi…

Hydrogels: synthesis, properties, applicationsAdvanced Polymer Synthesis and Characterizationbiodegradable polymer synthesis and properties

Quantitative electron probe microanalysis of nitrogen

G. F. Bastin、H. J. M. Heijligers1991-01-01Scanning

Abstract Quantitative electron probe microanalysis of nitrogen has been performed on 18 nitride specimens in the voltage range of 4–30 kV. A conventional lead stearate and a new W/Si multilayer analyzer crystal (2d = 5.98 nm) were used simultaneously. The net peak count rates on the latter crystal were approximately 2…

X-ray Spectroscopy and Fluorescence AnalysisElectron and X-Ray Spectroscopy TechniquesAdvanced Materials Characterization Techniques

The synthesis and crystal structure of a new polyoxovandium cluster anion: [As III 8V IV 14O42(0.5H2O)]4?

Guohe Huan、Mark A. Greaney、Allan J. Jacobson1991-01-01Journal of the Chemical Society Chemical Communications

The dark-brown compound [N(Me)4]4[AsIII8VIV14O42(0.5H2O)] containing a spherical anion [AsIII8VIV14O42(0.5H2O)]4– containing condensed VO5 square pyramids and As 2O5 units, is synthesized hydrothermally from As2O3, V2O5 and (Me)4NOH and structurally characterized by X-ray diffraction.

Metal-Organic Frameworks: Synthesis and ApplicationsPolyoxometalates: Synthesis and ApplicationsVanadium and Halogenation Chemistry

Carbothermal Synthesis of Silicon Nitride: Effect of Reaction Conditions

S. J. P. Durham、K. Shanker、R. A. L. Drew1991-01-01Journal of the American Ceramic Society

Conditions for carbothermal synthesis of α‐Si 3 N 4 are presented with special emphasis on the reaction temperature, C:SiO 2 ratio, and precursor mixing. With pure precursors, the conversion temperature is 1500° to 1550°C. An excess of C is necessary for complete conversion, and a simple sol–gelmixing technique provid…

Advanced ceramic materials synthesisCatalytic Processes in Materials ScienceSemiconductor materials and devices

The first observation of γ-octamolybdate: synthesis, crystal and molecular structure of [Me 3 N(CH 2 ) 6 NMe 3 ] 2 [Mo 8 O 26 ]·2H 2 O

Margaret L. Niven、J. J. Cruywagen、J. Bernard B. Heyns1991-01-01Journal of the Chemical Society Dalton Transactions

The compound [Me3N(CH2)6NMe3]2[Mo8O26]·2H2O crystallizes from an aqueous solution of sodium molybdate and [Me3N(CH2)6NMe3]Cl2, slightly acidified with hydrochloric acid. The crystals are monoclinic, space group P21/n with a= 12.42(1), b= 12.897(3), c= 15.74(1)Å, β= 106.41(5)° and Z= 2. The structure was determined by…

Metal-Organic Frameworks: Synthesis and ApplicationsPolyoxometalates: Synthesis and ApplicationsInorganic Chemistry and Materials