Materials Literature
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Full-thickness skin grafts placed on bare rabbit ear cartilage were revascularized, whereas split-skin grafts on the same kinds of areas failed. The contrast is most likely due to differences in the skin graft thickness and the vascular patterns in the grafts. Full-thickness rat skin grafts placed over the same sized…
Hydrostatic pressure has been known for quite some time to affect the physical and mechanical properties, to help create or synthesize new or known materials, and to enhance the formability of various metals and geological materials [1–19]. Although polymeric materials are far more susceptible to hydrostatic pressure…
There are available to the biologist sophisticated methods for the quantitative determination of many structural parameters of tissues; the methds are covered by the term stereology and are based on statistical sampling techniques introduced by geologists and materials scientists. Methods for determining the volume fr…
Abstract The characterization of eight fully aromatic polyamides are described with the procedures required to yield film‐ and fiber‐forming materials. Solutions of these aromatic polyamides in dimethylacetamide were characterized by NMR and the effects of dissolved lithium chloride on these spectra investigated. The…
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTPolymerization of Hexachlorocyclotriphosphazene. The Role of Phosphorus Pentachloride, Water, and Hydrogen ChlorideH. R. Allcock, J. E. Gardner, and Karen M. SmeltzCite this: Macromolecules 1975, 8, 1, 36–42Publication Date (Print):January 1, 1975Publication History Publishe…
The charge carrier transport properties of a wide variety of quartz single crystals and fused silica have been measured by creating electron-hole pairs in the bulk of the samples with high energy x-rays. The very short x-ray pulses (3 nsec) allowed unprecedented time resolution, and in some cases separate measurements…
Abstract
We consider a solid/nematic interface where long range van der Waals torques favor homeotropic alignment, while a direct steric effect tends to induce a planar alignment. Depending on the relative strength of the two contributions, one may find two transitions : planar ↔ conical and conical ↔ homeotropic. This is remi…
Cubic M 4+ P 2 O 7 pyrophosphates of Ti, Zr, Hf, Sn, and Pb have been examined by X-ray powder diffractometry and by infrared, Raman, and Mössbauer 119 Sn spectroscopy. The tin compound appeared to be of Chaunac's type I (with P 2 O 7 groups oriented at random) and could be converted to type II (with ordered P 2 O 7 g…
Nickel samples have been irradiated at two different dose rates with the same dose of 2.8-MeV 58Ni+ to a peak damage level of 13 dpa. The peak damage dose rates were ∼7 × 10−2 dpa sec−1 (HDR) and ∼7 × 10−4 dpa sec−1 (LDR). An upward shift of ∼75°C in the low-temperature limit for swelling has been observed for this in…
A method is described for removing tritium from liquid lithium fusion reactor blankets by extraction with molten salt. Results of distribution coefficient measurements made with lithium-lithium halide mixtures have demonstrated that tritium is preferentially distributed in the salt phase by a factor >1.0 on a volumetr…
Abstract We have studied by cyclic voltammetry the mechanisms of electron transfer and peak potentials of eleven alkenes, propylene oxide, propylene sulfide, and carbon disulfide. We have also studied the cationic polymerization of styrene in acetonitrile solution initiated by controlled potential electrolysis at the…
Thermal expansion measurements were made for several series of Na2O⋅K2O⋅GeO2 glasses, for one series of Na2O⋅Rb2O⋅GeO2 glasses, and for one series of Na2O⋅Cs2O⋅GeO2 glasses. Negative deviations from additivity were observed in the critical and deformation temperatures in every case, with the deviations increasing with…
Using the single adiabatic wall calorimeter, heats of mixing in the binary liquid alloys of copper and silver, gold, aluminum, gallium, indium, germanium or tin, and also in the binary alloys of gold and silver, aluminum, gallium, indium, germanium or tin were determined at 1100°C.The experimental method and procedure…
Crystals of monellin, a sweet protein from Dioscoreophyllum cumminsii, were grown by vapor diffusion of 20% ethanol into buffered protein solution. The crystals are orthorhombic, belonging to space group P2(1)2(1)2, with a = 54.4 A, b = 113.0 A, c = 40.8 A, and V = 250,300 A(3). The asymmetric unit contains two comple…
The 13C n.m.r. spectra of meso-tetraphenylporphyrin (TPP), the zinc(II), cadmium(II), bis[mercury(II) acetate], and various thallium(III) derivatives, and some related analogues are reported and assigned. In meso-tetra-(o-tolyl)-porphyrin and meso-tetra-(1-naphthyl)porphyrin only one species was observed. The introduc…
Carrier mobilities of several insulating polymers such as PET, PS were studied by the time of flight method using pulsed electron beam bombardment. For example, the mobilities obtained in an electric field of 1∼2 MV/cm were 2×10 -5 cm 2 /V·sec for the electron and 1×10 -4 cm 2 /V·sec for the hole at 27 °C in PET with…
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTCatalyst Deactivation Due to Pore-Plugging by Reaction ProductsEsmond NewsonCite this: Ind. Eng. Chem. Process Des. Dev. 1975, 14, 1, 27–33Publication Date (Print):January 1, 1975Publication History Published online1 May 2002Published inissue 1 January 1975https://pubs.acs.o…
Photoemission from a many-electron system is a many-electron process, even though the transition operator may affect only one electron directly. Relaxation and “shake-up” structure are related by a sum rule: when one is present, the other must also be present. Shake-up structure is shown to be accurately predictable i…
The existence of ferroelectricity in the chiral smectic C phase has been established from polarization measurements in the presence of an electric field [1]. In this article we study the case where the polarization is created by applying a shear velocity parallel to the smectic planes : The helicoidal structure is dis…