Materials Literature
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Benzotriazole is a specific corrosion inhibitor for copper and copper alloys. It is now widely used in industry to reduce the corrosion of these alloys under both atmospheric and immersed conditions. Corrosion of copper may produce a surface stain or tarnish, pitting of surfaces of pipes or promote pitting of other me…
Eigenphases near a resonance are shown to follow an equation which is a simple generalization of the usual equation for the behavior of the phase shift near a resonance in single-channel scattering. The parameters in the equation are shown to have a simple graphical interpretation.
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTThe Structure of Oligomeric Poly(isoprenyllithium)F. Schué, D. J. Worsfold, and S. BywaterCite this: Macromolecules 1970, 3, 5, 509–513Publication Date (Print):September 1, 1970Publication History Published online1 May 2002Published inissue 1 September 1970https://doi.org/10…
My life has been an interesting voyage. I became an astronomer because I could not imagine living on Earth and not trying to understand how the Universe works. My scientific career has revolved around observing the motions of stars within galaxies and the ...Read More
Quartz crystals obtained from three different sources have been strained in air a t atmospheric pressure, using compression rates of 10−3 to 10−5 sec−1. Of the three kinds of quartz tested, only the synthetic sample containing the highest amount of hydrogen-bonded OH groups (163 p.p.m.) was found to yield plastically,…
With a view to elucidating the structure of liquid ZnCl2 and deciding the extent of the analogy to SiO2 and BeF2 (liquid and vitreous) provided by ZnCl2 (liquid and vitreous), a variety of measurements on ZnCl2 have been performed. Density and expansivity measurements and probe ion electronic spectra are used to demon…
Based on the elastic interaction between a solute atom and a tensile crack-tip stress field, a mechanism of stress-corrosion cracking was proposed and analyzed. This elastic interaction provides a potential for solute atoms to migrate toward the tip of a crack. The elastic interaction and the equilibrium concentration…
Samples of polycrystalline (La 1- x Ca x )MnO 3 , where x takes the values ranging from 0.005 to 0.3, were studied experimentally. Stoichiometric specimens were made by carefully controlling the oxygen partial pressure. For specimens with x less than 0.1, the Néel temperature T N is almost constant at 141°K, while the…
From chemical analyses performed on an Arago profile, it met the requirements of the Podzol order, except for exchange properties. The cation exchange capacity was low and the ΔCEC never reached the limit of 8 meq/100 g. Qualitative and quantitative mineralogical analyses showed that illite was the predominant compone…
Oriented Si steel containing up to 6 percent Si was produced by gaseous siliconizing of oriented 3.25-percent Si steel strip. Dc magnetization curves in the with-grain (rolling) direction and ac core loss and magnetostriction measurements in both the with- and cross-grain (transverse) directions were obtained before a…
Sedimentation and diffusion constants of wormlike polymer chains have been calculated using methods of Kirkwood and collaborators. The chain statistics are described according to Hermans and Ullman using the (Kratky–Porod) model. The results are obtained for several chain lengths at varying degrees of flexibility for…
Abstract The primary aggregate structure in high structure blacks is broken down when the blacks are milled in rubber. The breakdown, it is shown further, involves the disruption initially of more easily disrupted forces, and then subsequently of more difficultly disrupted forces. If the total structure breakdown is s…
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTHeteropolyvanadomanganates(IV) with Mn:V=1:11 and 1:4Charles M. Flynn Jr. and Michael T. PopeCite this: Inorg. Chem. 1970, 9, 9, 2009–2014Publication Date (Print):September 1, 1970Publication History Published online1 May 2002Published inissue 1 September 1970https://pubs.ac…
Abstract Hydrogen cyanide is a minor product of degradation of copolymers of styrene and acrylonitrile. The liquid products have been separated and identified by combined gas chromatography and mass spectrometry (GC‐MS), as styrene, acrylonitrile, toluene, and benzene. The ratio of styrene to acrylonitrile monomers in…
A current-controlled negative resistance has been found in thin single-crystal wafers of silicon-doped yttrium-iron garnet (Si-YIG). Switching properties have been examined, and relaxation oscillations in the range 0.5–1 MHz have been established in the negative resistance region. A conductive memory state having a be…
Abstract Mit Hilfe eines quasi-adiabatisch und kontinuierlich arbeitenden Hochtemperatur-Kalori-meters wurde die spezifische Wärme von Aluminium und Wolfram sowie die Schmelzwärme von Aluminium gemessen. Eine atomistische thermodynamische Analyse ermöglicht eine Aussage über den Beitrag der anharmonischen Gitterschwin…
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTRaman Scattering and Polarization Measurements of Isotactic PolypropyleneP. D. Vasko and J. L. KoenigCite this: Macromolecules 1970, 3, 5, 597–601Publication Date (Print):September 1, 1970Publication History Published online1 May 2002Published inissue 1 September 1970https:/…
Abstract Studies of the growth of single ozone cracks show that a critical severity of deformation is required for growth to occur. Above this deformation the rate of single crack growth is essentially independent of strain and for a number of rubbers at normal temperatures is proportional to the ozone concentration.…
Abstract SiH 3 K, SiH 3 Rb und SiH 3 Cs haben bei Raumtemperatur Kristallstrukturen vom NaCl‐Typ (Gitterkonstanten a = 7.23, 7.52 bzw. 7.86 Å). Hieraus resultiert für das Silyl‐Anion, SiH 3 − , ein effektiver Ionenradius von 2.2 6 Å. Die gegenüber CH 3 K (NiAs‐Typ) abweichenden Kristallstrukturen werden auf die mehr k…
Abstract By the use of thermal volatilization analysis (TVA), 292°C was chosen as a suitable temperature for a preliminary experimental survey of the thermal degradation of styrene–acrylonitrile copolymers. TVA also indicated that there is no fundamental change in reaction mechanism as the acrylonitrile content of the…