Materials Literature
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The stoichiometry, stability and polymorphism of the perovskite-related solid solutions, Li0.5 – 3xRE0.5 +xTiO3: RELa, Nd, has been studied. For both series, the data are presented in the form of a temperature vs. composition phase diagram. Unit cell data for the different polymorphs (three in the La system, four in t…
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTAdsorption of Branched and Cyclic Paraffins in Silicalite. 1. EquilibriumCelio L. Jr. Cavalcante and Douglas M. RuthvenCite this: Ind. Eng. Chem. Res. 1995, 34, 1, 177–184Publication Date (Print):January 1, 1995Publication History Published online1 May 2002Published inissue…
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTTriphenylene-Based Discotic-Liquid-Crystalline Polymers: A Universal, Rational SynthesisNeville Boden, Richard J. Bushby, and Andrew N. CammidgeCite this: J. Am. Chem. Soc. 1995, 117, 3, 924–927Publication Date (Print):January 1, 1995Publication History Published online1 May…
Experimental results show that the contamination performance of silicone rubber composite insulators is better than porcelain insulators. This is attributed to the hydrophobicity of the silicone rubber. This suggests that the flashover mechanism of these insulators is different. This paper experimentally investigates…
The ligand 2,6-bis(1′-ethyl-5′-methylbenzimidazol-2′-yl)pyridine (L5) reacts with lanthanide perchlorate in acetonitrile to give the mononuclear triple-helical complexes [Ln(L5)3]3+(Ln = Eu, Gd or Tb). The crystal structure of [Eu(L5)3][ClO4]3·4MeCN has been determined, which shows three unco-ordinated perchlorate ani…
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTThe First Bis(.mu.-oxo)diiron(III) Complex. Structure and Magnetic Properties of [Fe2(.mu.-O)2(6TLA)2](ClO4)2Yan Zang, Yanhong Dong, Lawrence Que Jr., Karl Kauffmann, and Eckard MuenckCite this: J. Am. Chem. Soc. 1995, 117, 3, 1169–1170Publication Date (Print):January 1, 199…
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTNO Reduction by Activated Carbons. 2. Catalytic Effect of PotassiumM. Jose Illan-Gomez, Angel Linares-Solano, Ljubisa R. Radovic, and Concepcion Salinas-Martinez de LeceaCite this: Energy Fuels 1995, 9, 1, 97–103Publication Date (Print):January 1, 1995Publication History Pub…
Part 1 Coating design: thin-film optical coating design. Part 2 Deposition techniques and related topics: starting materials optical monitoring reactive physical vapor deposition processes ion assisted deposition ion beam sputtering plasma impulse chemical vapor deposition molecular beam deposition uniformity. Part 3…
Abstract
A simple model was developed which describes the effect of SiC submicrometer particles on the fracture toughness of alumina–SiC “nanocomposites.” This effect was attributed to the change in the fracture mode observed in alumina on adding SiC submicrometer particles, which was suggested to be a result of both matrix we…
The strength of alumina materials that had been subjected to varying degrees of densification was determined. Significant increases in strength were obtained for these materials even when there was minimal densification. For the most porous materials, the Weibull modulus values were similar but showed a significant in…
The < 2 µm fractions of Cheto (Arizona, USA) and Jelšový Potok (Slovakia) montmorillonites have been treated with 1 mol dm–3 H2SO4 for periods up to 6 h at 95 °C. The materials obtained were investigated by X-ray fluorescence (XRF), X-ray diffraction (XRD), infrared (IR) spectroscopy, and 29Si and 27Al magic-angle spi…
In the course of the mild methylation of 5,10,15,20-tetraphenyl-21-carbaporphyrin (CTPPH2) a novel isomer of N-methyl-5,10,15,20-tetraphenylporphyrin with an inverted N-methylated pyrrole ring, i.e. 2-N-methyl-5,10,15,20-tetraphenyl-21-carbaporphyrin (2-NCH3TPPH) has been synthesised. The protonation of 2-NCH3CTPPH pr…
Abstract The absorption of high kinetic energy by a small amount of material depends not only on the quality of the material but also on the structural design of the elements involved. Using a rapid response microbalance, we measured the tensions of radial threads in webs of the garden cross spider, Araneus diadematus…
This paper presents an artificial-neural-net model for predicting yarn tensile properties. A single hidden-layer neural network trained by using the back-propagation algorithm performs a functional mapping between material properties, process variables, and the resulting yarn tensile properties. The material and proce…
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTThermodynamics of the Hydrothermal Synthesis of Calcium Titanate with Reference to Other Alkaline-Earth TitanatesMalgorzata M. Lencka and Richard E. RimanCite this: Chem. Mater. 1995, 7, 1, 18–25Publication Date (Print):January 1, 1995Publication History Published online1 Ma…
this paper we present a two dimensional dynamic simulation of the fragmentation of granular materials. We establish a two - dimensional model for a deformable, breakable, granular solid by connecting unbreakable, undeformable elements with elastic beams, similar as in Refs. 12,13 . The contacts between the particles c…
Reaction of pseudo-boehmite, [Al(O)(OH)]n, with carboxylic acids (RCO2H) results in the formation of the carboxylatoalumoxanes, [Al(O)x(OH)y(O2CR)z]n where 2x + y + z = 3 and R = C1–C13. The physical properties of the alumoxanes are highly dependent on the identity of the alkyl substituents, R, and range from insolubl…
Article Changes in Cellulose Crystallinity During Kraft Pulping. Comparison of Infrared, X-ray Diffraction and Solid State NMR Results was published on January 1, 1995 in the journal Holzforschung (volume 49, issue 6).
Tetrabenzoporphyrins (TBP) of Zn, Pd, Lu, Y, Sn and Pb have been synthesized and Pd, Sn and Lu complexes characterized by 1H NMR spectroscopy. Phosphorescence at room temperature in DMF solutions was measured for Pd and Lu complexes giving quantum yields of 7.9% and 3.5% and lifetimes of 250 µs and 870 µs, respectivel…