Materials Literature
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Polyaniline/crosslinked cellulose conductive interpenetrating polymer networks (IPNs) were prepared by oxidative polymerization of aniline within the self-synthesized cellulose network using ammonium persulphate as oxidant. The conductivity of the IPN increases and then decreases with decrease in the aniline/(NH4)2S2O…
In a search for a generic synthesis methodology to produce microporous, nonoxide ceramics, pyrolysis of silicon-based preceramic polymers has been studied in inert (He or Ar) and reactive (NH 3 ) atmospheres over the temperature range 25−1300 °C. Pyrolysis of polysilazanes in an inert atmosphere in the absence of addi…
This paper discusses a novel plasma‐spraying process for depositing dense LaCrO 3 ‐based interconnection for solid oxide fuel cells (SOFCs). Calcium aluminate was mixed with LaCrO 3 in a slurry containing PVA binder and spray dried to form free‐flowing agglomerates. These free‐flowing agglomerates were plasma sprayed…
Among the large number of processes parameters in Carbon Black (CB) manufacturing, temperature is certainly one of the most important. Whatever the process and the feedstock are, all the processes have in common a limited temperature, as a result of the feedstock energy contain. In the first part of this paper, we est…
OBJECTIVE: The success of liposome-based drug delivery systems for tumor targeting relies on maximum extravasation of liposomes into tumor interstitium, as well as optimal release of contents from the liposomes once within the tumor Liposome extravasation and content release are two separate processes that can be indi…
The beneficial effect of the presence of Bi atoms on the rechargeability of can be explained through a reaction viewpoint. Bi(III) and Mn(X) atoms (X = IV, III, or II) give stable complexes. Furthermore, the formation of can be viewed as a stepwise 3D polymerization, i.e. , as a reaction chain composed of basic additi…
Abstract The kinetics of crystallization have been studied for a series of novel poly(ether ether sulfide)s based on a biphenyl moiety in the backbone ( M n = 14.3K, 19.1K), referred to as biphenyl sulfide ( T g = 142°C, T m = 347°C) and phenyl moieties in the backbone ( M n = 8.1K, 19.9K, 34K), referred to as phenyl…
Abstract Spurious x‐ray signals, which previously prevented high‐resolution energy‐dispersive x‐ray analysis (EDS) in the environmental scanning electron microscope (ESEM), can be corrected using a simple method presented here. As the primary electron beam travels through the gas in the ESEM chamber, a significant fra…
NO x reduction with hydrocarbons is studied at temperatures around 150 °C to develop an easy retrofit NO x removal process to be located downstream of the particulate control device for flue gas cleanup. Acetone is the most active hydrocarbon reductant for NO reduction in the presence of O 2 and H 2 O. At 150 °C, 35%…
Bayum hexaferrites are anisotropic iron oxides which can present high values of permeability. We have studied Ba(Co,Ti)xFe12-2xO19 ( M type) and Ba3Co2Fe24O41 (Z type) compositions. Powders are synthetized using a classical ceramic method (M type) or a chemical one (Z type) consisting in the coprecipitation of carbona…
Solution equilibria and optical spectra of several metallooctaethylporphyrin π-cation radicals have been examined in methylene chloride solution. The several π-cation radical species, [M(OEP • )]Y (M = Cu, Ni, Zn, Pd, or VO; Y = ClO 4 - or SbCl 6 - ), are found to dimerize to form [M(OEP • )] 2 2+ . These dimeric spec…
Small-angle light scattering and scanning electron microscopy (SEM) have been used to study morphology development in poly(methyl methacrylate) membranes formed by the thermal inversion method. Analysis of the early time behavior of the scattered intensity in terms of Cahn−Hilliard theory establishes spinodal decompos…
The Bacillus subtilis araC locus, mapped at about 294 degrees on the genetic map, was defined by mutations conferring an Ara- phenotype to strains bearing the metabolic araA, araB, and araD wild-type alleles (located at about 256 degrees on the genetic map) and by mutants showing constitutive expression of the three g…
The unusual magnetic properties of La0.5Ca0.5MnO3 were found to be associated with structural and magnetic ordering phenomena, resulting from the close interplay between charge, orbital, and magnetic ordering. Analysis of synchrotron x-ray and neutron powder diffraction data indicates that the anomalous and hysteretic…
Experiments were conducted to determine the effect of changing the acid volume, acid normality, and incubation time on in vitro solubility values of various test calcium samples. A 200 mL volume of 0.2N HC1 solution combined with 2.0 g sample size and 10 min incubation time at 42°C produced a limestone solubility rang…
Rate coefficients of the reaction of hydroxyl (OH) radicals with CH 3 OCH 3 ( k 1 ) and CH 3 OC(CH 3 ) 3 ( k 2 ) over an extended temperature range are reported. Measurements were performed using a laser photolysis−laser-induced fluorescence technique under slow flow conditions at a total pressure of 740 ± 10 Torr. Ar…
Experimental solubilities are reported at 25.0 °C for trans-stilbene dissolved in 28 different organic nonelectrolyte solvents containing methyl, ether, hydroxy, and tert-butyl functional groups. Results of these measurements are used to test the applications and limitations of expressions derived from Mobile Order th…
The nature of extrinsic point defects in lead zirconate titanate (PZT) ceramics of various compositions prepared by solution chemistry has been explored. Using electron paramagnetic resonance (EPR), several impurity sites have been identified in the as‐received materials, which include Fe 3+ oxygen vacancy (V O ‥ ) co…
Since the early study by Galasso and Pyle, the structure of complex perovskite compounds with 1:2 ordering of B-site ions, ordered perovskite compounds, has been thought to be Ba(Sr 1/3 Ta 2/3 )O 3 -type hexagonal. Recently, a structural phase transformation has been found in A-site substituted ordered perovskite comp…
Amorphous SixGeyOz alloy films of different chemical composition and SiOx/GeOy multilayers are prepared by dc magnetron sputtering. The formation of Ge nanocrystals in the alloy matrix is induced by annealing at temperatures ranging from 700 to 900 °C. In contrast, the crystallization in the Ge sublayers in the multil…