Materials Literature
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The conditions for the self-organized formation of ordered hexagonal structures in anodic alumina were investigated for both oxalic and sulfuric acid as an electrolyte. Highly ordered pore arrays were obtained for oxidation in both acids. The size of the ordered domains depends strongly on the anodizing voltage. This…
The heat capacities of (NH4)2PbCl6 and (ND4)2PbCl6 were measured at temperatures between 13 K and 300 K. A gradual phase transition was found at 77.8±0.3 K for (NH4)2PbCl6 with an associated transition entropy of 3.0 J K−1 mol−1. The transition temperature shifted to 81.0±0.3 K in (ND4)2PbCl6. A sharp first order tran…
We report an experimental result of the thermally induced morphological transition from lamellar to gyroid phase in a binary blend of polystyrene-block-polyisoprene (SI) diblock copolymers. Two SI copolymers employed in this study have almost the same molecular weights but different volume fractions of polystyrene (PS…
A theoretical description of the six-wave mixing spectroscopy is presented. The six-wave mixing spectroscopic signals in time and frequency domains are expressed in terms of the fifth-order nonlinear response functions. Particularly, the resonant coherent hyper-Raman scattering with wave vector of 4k1−k2 and frequency…
We report on a deuteron NMR study of quadrupolar splittings and spin-lattice relaxation times T1Q and T1Z as a function of temperature and at two different Larmor frequencies in the columnar phase of hexakis(n-hexyloxy)triphenylene (HAT6). The additive potential method is used to model the quadrupolar splittings, from…
Electrical property derivative expressions are presented for the nuclear relaxation contribution to static and dynamic (infinite frequency approximation) nonlinear optical properties. For CF4 and SF6, as opposed to HF and CH4, a term that is quadratic in the vibrational anharmonicity (and not previously evaluated for…
The absorption band (band A) due to the aggregate effect of nanoscale silver particles in silver sol prepared by a modification of the procedure of the original silver sol used in surface-enhanced Raman scattering (SERS) was observed near 435 nm without the presence of any foreign molecules. This band eventually stabi…
We study the magnetic circular dichroism (MCD) of exciton states near the band edge of CdSe nanocrystallites (quantum dots). The experiment probes the difference between left and right circularly polarized transitions in the presence of an external magnetic field. Analysis of the MCD signal determines the sign and mag…
The gas-phase hydrolysis of TiCl 4 has been studied with several laboratory reactors. Unexpectedly, the reaction is clearly split in two steps, an almost instantaneous partial hydrolysis which produces 2 mol of HCl/mol of TiCl 4 together with a salt, identified as Ti(OH) 2 Cl 2 . The latter forms a very fine dust whic…
Polyethersulfone (PES)–[silicon oxide] hybrids were derived via sol–gel reactions for tetraethoxysilane (TEOS) and tetramethoxysilane (TMOS) in dimethylacetamide solutions of the polymer. In one scheme, water was initially present, and condensation reactions between SiOR groups competed with their reactions with —OH g…
Thermal analysis, x-ray diffraction and TEM selected area electron diffraction (SAD) methods were used to investigate the phase evolution of the -C system upon solid state reaction. The experimental results revealed that there were some solid state reactions of carbon with the phase and two new Nd-enriched carbides we…
Intumescent fire-retardant systems have been studied in detail from all points of view. However, all works passed around questions of mechanical stability of foamed chars produced during burning. In the present work, mechanical properties of intumescent chars has been discussed. Technique and method of such investigat…
The antibacterial activity of a series of soluble pyridinium-type polymers with different compositions against Escherichia coli (E. coli) suspended in sterilized distilled water was investigated by a colony count method. The results show that the antibacterial activity of the soluble pyridinium-type polymers is charac…
A new kinetic approach to study the vapor-phase preparation of orthorhombic molybdenum trioxide (MoO 3 ) has been established in this work. Using a simple experimental setup, the vaporization and condensation of MoO 3 can be investigated with sufficient oxygen background to ensure the stoichiometry of the compound. Th…
The reaction of N,N -diisopropylethylamine (Hünig's base) and disulfur dichloride in 1,2-dichloroethane, in the presence of DABCO, gives 4-ethylbis[1,2]dithiolo[5,4- b ][4‘,5‘- e ][1,4]thiazine-3,5-dithione ( 1 ), or, by addition of oxygen donors, the 3-oxo-5-thione 2 or 3,5-dione 3 derivatives are selectively obtaine…
N-Vinylamides: Synthesis, Conformation and Electronic State. Radical Polymerization. Solvation (Hydration) and Conformational Transformations of Macromolecules in Solution. Complex Formation of Macromolecules in Aqueous Solution. Reactions in Poly-N-vinylamide Chains. References. Index.
The results of massively parallel three-dimensional molecular dynamics simulations of the perpendicular intersection of extended dislocations in copper are reported. The intersection process, which involves three of the four possible 111 glide planes in the face-centered cubic lattice, begins with junction formation,…
We study the glassy transition for simple liquids in the hypernetted chain (HNC) approximation by means of an effective potential recently introduced. Integrating the HNC equations for hard spheres, we find a transition scenario analogous to that of the long-range disordered systems with `one-step replica symmetry bre…
The possibility of disappearance of the diffuse-intensity peak splitting induced by the Fermi surface (i.e., of coalescence of the intensity maxima) with decreasing temperature is predicted. The underlying mechanism is the compensation of the reciprocal-space curvatures of the self-energy and the interaction. The theo…
Plasma protein adsorption patterns on colloidal drug carriers acquired after iv administration depend on their surface characteristics and are regarded as key factors for their in vivo organ distribution. Polymeric latex particles with strongly differing surface properties were synthesized as models for colloidal drug…