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Computation of low-energy crystalline arrangements of cellulose triacetate

Romain M. Wolf、Eric Francotte、Leslie Glasser 等 5 位作者1992-01-01Macromolecules

ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTComputation of low-energy crystalline arrangements of cellulose triacetateRomain M. Wolf, Eric Francotte, Leslie Glasser, Istvan Simon, and Harold A. ScheragaCite this: Macromolecules 1992, 25, 2, 709–720Publication Date (Print):January 1, 1992Publication History Published o…

Liquid Crystal Research AdvancementsAdvanced Cellulose Research StudiesDyeing and Modifying Textile Fibers

‘Corrosion resistance of technical ceramics’

R.J. Hand1992-01-01British Corrosion Journal

"‘Corrosion resistance of technical ceramics’." British Corrosion Journal, 27(1), p. 25

Advanced ceramic materials synthesisMaterial Properties and Applications

Thermal degradation of polybutadiene, 2. Overall thermal behaviour of polymers with different microstructures

Maria Paola Luda Di Cortemiglia、Marino Guaita、Oscar Chiantore1992-01-01Die Makromolekulare Chemie

Abstract The thermal decomposition at volatilization temperatures of polybutadiene samples with different initial microstructures was investigated i. vac. and under nitrogen atmosphere by thermogravimetry, differential scanning calorimetry, thermal volatilization analysis and infrared spectroscopy. The decomposition o…

Polymer crystallization and propertiesThermal and Kinetic AnalysisPolymer Science and PVC

Development of a B4C/Al Cermet for Use as an Improved Structural Neutron Absorber

CJ Beidler、W.E. Hauth、Abhishek Goel1992-01-01Journal of Testing and Evaluation

Abstract An aluminum and boron carbide cermet was evaluated for possible application as a neutron absorbing material where structural strength and rigidity will be required. The boron carbide/aluminum composite possessed unique continuous interconnected ceramic and metal phases. Traditional bocon containing neutron ab…

Boron and Carbon Nanomaterials ResearchBoron Compounds in ChemistryGraphite, nuclear technology, radiation studies

Ein Germaniumsesquisulfid der Zusammensetzung (tBuGe)4S6 ohne Adamantanstruktur

Wataru Andō、Tetsuji Kadowaki、Yoshio Kabe 等 4 位作者1992-01-01Angewandte Chemie

Zwei schwefelverbrückte, nahezu planare Ge 2 S 2 ‐Vierringe liegen im neuartigen Sesquichalcogenid 1 vor, das, sich bei der Umsetzung von t uGeCl 3 mit (NH 4 ) 2 S 5 bildet. 1 lagert bei thermischer Belastung in das bereits bekannte ( t BuGe) 4 S 6 ‐Isomer mit Adamantangerüst um. Wird dieses direkt aus t BuGeCl 3 und…

Synthesis and characterization of novel inorganic/organometallic compoundsSilicone and Siloxane ChemistryOrganometallic Compounds Synthesis and Characterization

Effect of Work Roll Materials and Progress of Manufacturing Technology on Cold Rolling and Future Developments in Japan.

Shuichi Iwadoh、Toshikazu Mori1992-01-01ISIJ International

As the fundamental tools in the cold rolling, work rolls have been greatly affected on the quality, production cost and productivity. The issue of the technological innovation about work roll manufacturing have been changed from the original, which was concerned with steel making and ingotting techniques for minimizin…

Microstructure and Mechanical Properties of SteelsMetallurgy and Material FormingMetal Alloys Wear and Properties

Pressure-induced phase transformations in alkali-metal hydrides calculated using an improved linear-muffin-tin-orbital–atomic-sphere-approximation energy scheme

Carlos O. Rodriguez、M. Methfessel1992-01-01Physical review. B, Condensed matter

A scheme for the calculation of total energies from first principles is described which is intermediate between the popular linear muffin-tin-orbital method in the atomic-sphere approximation (LMTO-ASA) and an exact full-potential treatment. The local-density total energy is evaluated accurately for the output charge…

Advanced Chemical Physics StudiesHydrogen Storage and MaterialsInorganic Chemistry and Materials

Spectroelectrochemical observation of poly(benzo[c]thiophene) n- and p-doping

Simone M. Dale、Andrew Glidle、A. Robert Hillman1992-01-01Journal of Materials Chemistry

The deposition and properties of electropolymerised poly(benzo[c]thiophene)(PBCT) films have been studied using in situ UV–VIS spectroscopy. Film stability is enhanced by ‘conditioning’ in background electrolyte [0.2 mol dm–3 tetraethylammonium tetrafluoroborate (TEAT)–CH3CN]; this involves a single potential cycle be…

Conducting polymers and applicationsElectrochemical Analysis and ApplicationsAnalytical Chemistry and Sensors

The Effect of Phosphorus on the Radiation-Induced Microstructure of Stabilized Austenitic Stainless Steels

Philippe Dubuisson、A Maillard、C Delalande 等 5 位作者1992-01-01OpenAlex

This paper deals with the correlation of irradiation behavior and microstructural evolution of mono-(Ti) and multi-(Ti, Mb, V) stabilized Type 316 (UNS S31600) stainless steels with different phosphorus levels. These steels, in the 20% cold-worked condition, were irradiated between 400 and 500°C up to 100 dpa in the P…

Microstructure and Mechanical Properties of SteelsFusion materials and technologiesSurface Treatment and Residual Stress

Evaluation of properties and special features for high-temperature applications of rhenium

Boris D. Bryskin1992-01-01AIP conference proceedings

Sixty‐six years have passes since rhenium was discovered in June 1925 by husband‐and‐wife team Walter and Ida Noddack. The rapid development of rhenium is due to the unique properties of the metal and its alloys. Rhenium has a hexagonal close packed structure as opposed to the body centered cubic structure of other re…

Metal and Thin Film MechanicsIntermetallics and Advanced Alloy PropertiesMetallurgical and Alloy Processes

The Effects of Relative Humidity on Some Physical Properties of Modern Vellum: Implications for the Optimum Relative Humidity for the Display and Storage of Parchment

Eric Hansen、Steve N. Lee、H. Sobel1992-01-01Journal of the American Institute for Conservation

The effects of different relative humidities on some physical properties of three types of calfskin parchment (vellum) were investigated. Standard samples were subjected to (1) tensile fracture, and (2) measurement of the force that developed when the restrained samples were subjected to step decreases in relative hum…

Additive Manufacturing and 3D Printing TechnologiesCollagen: Extraction and Characterization

Infrared Absorption Coefficients of Silica Glasses

Nazanin Sahba、T. J. ROCKETT1992-01-01Journal of the American Ceramic Society

The absorption coefficient values of several silicate glasses in the IR radiation range were determined. Four methods were employed in this study: (1) direct transmission by CO 2 laser, (2) direct transmission through ultrathin sections using an IR spectrometer, (3) glass particle dispersions in KBr pressed pellets, a…

Glass properties and applicationsLaser Material Processing TechniquesBuilding materials and conservation

Investigations of Tribological Characteristics of Solid Lubricants Exposed to Atomic Oxygen

Masashi Arita、Yoshiteru Yasuda、Katsuhiro Kishi 等 4 位作者1992-01-01Tribology Transactions

At low earth orbit (LEO) altitudes of 100–1000 km, pressures are relatively high (10−5 Pa) and the residual atmosphere consists primarily of atomic oxygen (AO). Spacecraft orbital velocities, approximately 8 km/sec, at LEO altitudes result in a reactive chemical environment with 5eV AO. Long-term (10–30 years) operati…

Metal and Thin Film MechanicsDiamond and Carbon-based Materials ResearchSilicone and Siloxane Chemistry

Modulation of Tc–NX (X = O or S) bonds by π-acceptor ligands

Jun Lu、Michael J. Clarke1992-01-01Journal of the Chemical Society Dalton Transactions

Transfer of a sulfur atom from S2Cl2 to cis-[TcN(Cl)(phen)2]PF6(phen = 1,10-phenanthroline) yields cis-[Tc(NS)Cl(phen)2]PF6, which crystallizes in the triclinic space group, P(no. 2), with cell parameters a= 9.850(3), b= 16.293(3), c= 8.349(2)Å, α= 100.06(2), β= 93.84(3) and γ= 106.96(3)°. The Tc–NS bond length is 1.7…

Crystal structures of chemical compoundsLanthanide and Transition Metal ComplexesOrganometallic Compounds Synthesis and Characterization

On the Inhomogeneity of Refractive Index of CaF2 Crystals for High Performance Optics

L. Dressler、Rudolf Rauch、R. H. REIMANN1992-01-01Crystal Research and Technology

Abstract CaF 2 ‐crystals belong to the standard materials, used in optical precision instruments. As well as the traditional optics for microscopy new developments in the field of DUV‐lithography (projecting lenses made out of CaF 2 and quartz) need a homogeneity of the refractive index in the order of 10 −6 , but ove…

Advancements in Photolithography TechniquesAdvanced optical system designOptical Coatings and Gratings

Radiopacity and Physical Properties of Titanium-polymethacrylate Composite

Hideo Matsumura、M. Sueyoshi、Mitsuru Atsuta1992-01-01Journal of Dental Research

Titanium-polymethacrylate composite was prepared as an x-ray-opaque filler for composite core materials. The base monomers of the composite were 2,2-bis [4-(3-methacryloyloxy-2-hydroxypropoxy) phenyl] propane (Bis-GMA) and triethyleneglycol dimethacrylate (TEGDMA). Pure titanium powder was used as a radiopaque element…

Silicone and Siloxane ChemistryMaterial Properties and Applications

Temperature- and axial-ligand-dependent EPR spectra of cobalt porphyrin cation radicals: effects of mixing of the A1u and A2u states and a locally excited triplet state

Satoh、Yasunori Ohba、Seigo Yamauchi 等 4 位作者1992-01-01Inorganic Chemistry

ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTTemperature- and axial-ligand-dependent EPR spectra of cobalt porphyrin cation radicals: effects of mixing of the A1u and A2u states and a locally excited triplet stateSatoh Minoru, Yasunori Ohba, Seigo Yamauchi, and Masamoto IwaizumiCite this: Inorg. Chem. 1992, 31, 2, 298–…

Electrocatalysts for Energy ConversionMetal complexes synthesis and propertiesPorphyrin and Phthalocyanine Chemistry

Development of Cobalt Free Wear Resistant Alloys for Nuclear Applications

W. Barry Burdett1992-01-01Surface Engineering

The major source of shutdown radiation in PWR plant is the 60 Co radio nuclide generated from Stellite alloys used for wear resistance in the circuit. Initial attempts to replace cobalt based alloys with materials based on the nickel-chromium-boron system were unsuccessful in prototype testing. A galling test applied…

Fusion materials and technologiesNuclear Materials and PropertiesGraphite, nuclear technology, radiation studies

Structural phase transitions in [(C2H5)4N]2MX4crystals

Z. Czapla、Sĺwomir Dacko1992-01-01Ferroelectrics

A number of compounds of the chemical formula [(C2H5)4N]2MX4 exhibit structural phase transitions in the temperature range 200–300 K, which were found in calorimetric investigations. Dielectric measurements on pellet samples confirmed the existence of the phase transitions and ferroelectricity in [(C2H5)4N]2 MnCl4 has…

Crystallography and molecular interactionsSolid-state spectroscopy and crystallographyChemical Thermodynamics and Molecular Structure

Corrosion Mechanisms for Copper and Silver Objects in Near-Surface Environments

M. B. McNeil、Brenda J. Little1992-01-01Journal of the American Institute for Conservation

The morphology and mineralogy of corrosion products found on copper and silver artifacts recovered from shallow land or water burial are reviewed. Stability diagrams are used to interpret mechanisms for corrosion phenomena with an emphasis on identification of microbiological action.

Corrosion Behavior and Inhibition