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The effect of melt history, pressure, and crystallization temperature on spherulite size in bulk isotactic polypropylene

J. H. Reinshagen、R. W. Dunlap1973-12-01Journal of Applied Polymer Science

Abstract Melt history, pressure, and crystallization temperature are three variables that may be used to vary spherulite size in polymer systems. In this study, bulk polypropylene samples were given various melt treatments and then isothermally crystallized under constant pressure. Spherulite size was found to increas…

Polymer crystallization and propertiesPolymer Nanocomposites and Propertiesbiodegradable polymer synthesis and properties

Etude de la montée des dislocations au moyen d'expériences de fluage par diffusion dans le magnésium

G. Edelin、Jean Poirier1973-12-01Philosophical magazine

On a utilisé les expériences de fluage pour mesurer la vitesse de montée des dislocations c. On trouve que la vitesse de montée varie avec la température avec une énergie d’activation do 1,80 eV, supérieure à celle de l’autodiffusion, et avec la contrainte, proportionnellement à σ2,7. Les estimations théoriques de la…

Microstructure and mechanical propertiesHigh Temperature Alloys and CreepAdvanced Materials Characterization Techniques

Über Finnlands rezente und subfossile Diatomeen VII

K. Mölder、R. Tynni1973-12-01Bulletin of the Geological Society of Finland

The article deals with the distribution and ecology of the Rhoicosphaenia, Diatomella, Mastogloia, Diploneis, Amphipleura, Frustulia, Brebissonia, Anomoeoneis and Stauroneis species known in Finland.

Paleontology and Stratigraphy of FossilsDiatoms and Algae ResearchMarine and environmental studies

Crystal-structure refinements for orthorhombic boracite, Mg3CIB7O13, and a trigonal, iron-rich analogue

Eric Dowty、Joan R. Clark1973-12-01Zeitschrift für Kristallographie - Crystalline Materials

Article Crystal-structure refinements for orthorhombic boracite, Mg3CIB7O13, and a trigonal, iron-rich analogue was published on December 1, 1973 in the journal Zeitschrift für Kristallographie - Crystalline Materials (volume 138, issue 1-6).

Crystal Structures and PropertiesChemical Synthesis and CharacterizationX-ray Diffraction in Crystallography

Measurement of rotating flux in silicon iron laminations

A.J. Moses、B.W.J. Thomas1973-12-01IEEE Transactions on Magnetics

A method of calculating the magnitude and direction of the instantaneous flux density in a thin lamination of magnetic material is described. The technique was demonstrated by measuring the rotating flux in samples of mild steel, grain-oriented silicon iron, and at a point in the T-joint of a three-phase, three-limbed…

Microstructure and Mechanical Properties of SteelsMagnetic Properties and Applications

An ultrastructural study of shell regeneration in Mytilus edulis (Mollusca: Bivalvia)

V. Meenakshi、Patricia Blackwelder、Karl M. Wilbur1973-12-01Journal of Zoology

The sequence of changes following experimental removal of a central region of one valve of Mytilus edulis included: (1) the secretion of periostracum similar to one of the three layers of normal periostracum; (2) calcification on the periostracum in a pattern corresponding to the form of the periostracal surface; (3)…

Bone Tissue Engineering MaterialsMarine Bivalve and Aquaculture StudiesCalcium Carbonate Crystallization and Inhibition

Stabilization of the higher oxidation states of nickel. Molecular structure of bis(2,6-diacetylpyridine dioximato)nickel(IV)

Gordon Sproul、Galen D. Stucky1973-12-01Inorganic Chemistry

ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTStabilization of the higher oxidation states of nickel. Molecular structure of bis(2,6-diacetylpyridine dioximato)nickel(IV)Gordon Sproul and G. D. StuckyCite this: Inorg. Chem. 1973, 12, 12, 2898–2901Publication Date (Print):December 1, 1973Publication History Published onl…

Metal complexes synthesis and propertiesInorganic and Organometallic ChemistryThermal and Kinetic Analysis

Kinetic studies of the acylation of pig muscle–d-glyceraldehyde 3-phosphate dehydrogenase by 1,3-diphosphoglycerate and of proton uptake and release in the overall enzyme mechanism

P. J. Harrigan、David R. Trentham1973-12-01Biochemical Journal

In the presence of NAD(+) the acylation by 1,3-diphosphoglycerate of the four active sites of pig muscle d-glyceraldehyde 3-phosphate dehydrogenase can be monitored at 365nm by the disappearance of the absorption band present in the binary complex of NAD(+) and the enzyme. A non-specific salt effect decreased the acyl…

Cancer, Hypoxia, and MetabolismMetabolism and Genetic DisordersEnzyme Structure and Function

Depolarization thermocurrents in amorphous polymers

C. Lacabanne、D. Chatain1973-12-01Journal of Polymer Science Polymer Physics Edition

Abstract The depolarization thermocurrent (DTC) method gives the dependence of the dielectric relaxation time on temperature. It has been used for investigations of relaxations obeying an Arrhenius‐like law in crystalline polymers. The analysis of this method shows it is possible to study mechanisms described by the W…

Polymer crystallization and propertiesMaterial Dynamics and PropertiesDielectric materials and actuators

Crystal structure of poly‐p‐xylylene. I. The α form

Reikichi Iwamoto、Bernhard Wunderlich1973-12-01Journal of Polymer Science Polymer Physics Edition

Abstract The molecular conformation and the crystal structure of α‐form poly‐ p ‐xylylene has been determined by x‐ray diffraction. The polymer has a monoclinic unit cell with a = 5.92, b = 10.64, c (fiber axis) = 6.55 Å, and β = 134.7°. Two chains pass through the unit cell, and the space groups is C2/m . The packing…

biodegradable polymer synthesis and propertiesSynthesis and Properties of Aromatic CompoundsSynthesis and properties of polymers

Mica-Derived Vermiculites as Unstable Intermediates

J. A. Kittrick1973-12-01Clays and Clay Minerals

Abstract Stability determinations were made by solubility methods on two trioctahedral mica-derived vermiculites. The phlogopite-derived vermiculite was found to be unstable under acid solution conditions, where stabilities of montmorillonite, kaolinite and gibbsite had previously been determined. An attempt was next…

Arsenic contamination and mitigationClay minerals and soil interactionsMine drainage and remediation techniques

Palladium and Proton Knight Shift in Palladium Hydride

P. Brill、J. Voitländer1973-12-01Berichte der Bunsengesellschaft für physikalische Chemie

Abstract The nuclear magnetic resonance of 105 Pd has been observed in α‐PdH n for the first time. The resonant field was measured at 75°C as a function of hydrogen pressure p within the entire α phase region. A linear relationship between Knight shift and hydrogen concentration has been established by comparison with…

Hydrogen Storage and MaterialsAdvanced NMR Techniques and ApplicationsQuantum, superfluid, helium dynamics

Identification of a Disulfide-Linked Procollagen as the Biosynthetic Precursor of Chick-Bone Collagen

Janet M. Monson、Paul Börnstein1973-12-01Proceedings of the National Academy of Sciences

Chick cranial-bone procollagen, extracted at neutral pH in the presence of inhibitors of proteolytic enzymes, exists as a triple-stranded protein with disulfide bonds linking all three chains. The biosynthetic precursor function of this procollagen was demonstrated by pulsechase experiments. The ratio of radioactive h…

Collagen: Extraction and Characterization

The chemistry of the collagen cross-links. The characterization of Fraction C, a possible artifact produced during the reduction of collagen fibres with borohydride

Simon P. Robins、Allen J. Bailey1973-12-01Biochemical Journal

The present paper describes the isolation and identification of a major radioactive component of borotritide-reduced collagen, previously designated Fraction C. The derived structure for the compound confirms that it is identical with the ;post-histidine' component described by Tanzer et al. (1973) and given the trivi…

Collagen: Extraction and Characterization

Temperature, stress, and annealing effects on the luminescence from electron-irradiated silicon

C. E. Jones、Eric S. Johnson、W. Dale Compton 等 5 位作者1973-12-01Journal of Applied Physics

Low-temperature photoluminescence spectra are presented for Si crystals which have been irradiated with high-energy electrons. Studies of isochronal annealing, stress effects, and the temperature dependences of the luminescence are used to discuss the nature of the luminescent transitions and the properties of defects…

Silicon and Solar Cell TechnologiesSilicon Nanostructures and PhotoluminescenceIon-surface interactions and analysis

Stress Corrosion Cracking of Sensitized Stainless Steel in Oxygenated High Temperature Water

W.E. Berry、Earl L. White、W. K. Boyd1973-12-01CORROSION

The stress corrosion cracking (SCC) behavior of sensitized Type 304 stainless steel has been studied in 288 C (550 F) primary water as a function of oxygen and fluoride contents of the water, stress level, prestrain, heat treatment, and surface preparation (tarnish film, surface ground, or pickled). Susceptibility to…

Corrosion Behavior and InhibitionHydrogen embrittlement and corrosion behaviors in metalsNon-Destructive Testing Techniques

Models for Lattice Defects in Oxide Layers on Passivated Iron and Nickel

Carl Wagner1973-12-01Berichte der Bunsengesellschaft für physikalische Chemie

Abstract Passivity of iron in acidic solutions is ascribed to a thin film of iron‐deficient magnetite with the limiting compositions Fe 3 O 4 and Fe 2.67 O 4 . If the composition at the oxide/solution interface is close to the formula Fe 2.67 O 4 , it follows theoretically that the stationary corrosion current density…

Corrosion Behavior and InhibitionMetallurgical Processes and ThermodynamicsPower Transformer Diagnostics and Insulation

The lon Gene and Degradation of β-Galactosidase Nonsense Fragments

B. Shineberg、David Zipser1973-12-01Journal of Bacteriology

N-terminal beta-galactosidase fragments are rapidly degraded in growing cells of Escherichia coli. Mutations in the lon gene are sufficient to enhance the stability of these polypeptides.

Protein Structure and DynamicsEnzyme Structure and FunctionDiet, Metabolism, and Disease

The fine structure of the periphyton of Chara sp. and Potamogeton natans from Wytham Pond, Oxford, and its significance to the macrophyte‐periphyton metabolic model of R. G. Wetzel and H. L. Allen

B. R. Allanson1973-12-01Freshwater Biology

Summary The fine structure of the periphyton of Chara sp. from Wytham pond, Oxford, is examined using transmission and stereoscan electron microscopy. As a result of this investigation the structural proximity of each periphyte component as required by Wetzel and Allen's metabolic model of macrophyte‐periphyton intera…

Aquatic Ecosystems and Phytoplankton DynamicsMarine Biology and Ecology ResearchDiatoms and Algae Research

The reliability of Michaelis constants and maximum velocities estimated by using the integrated Michaelis–Menten equation

Gordon L. Atkins、I.A. Nimmo1973-12-01Biochemical Journal

1. Experimental progress curves were simulated for a reaction obeying Michaelis-Menten kinetics. 2. K(m) and V were estimated (a) by fitting the integrated Michaelis-Menten equation to the progress curves, and (b) from the initial slopes of the curves (i.e. from initial velocities). 3. The integrated equation could no…

Innovative Microfluidic and Catalytic Techniques InnovationThermal and Kinetic Analysisthermodynamics and calorimetric analyses