Materials Literature
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An examination has been made of the mechanism of breakdown of passive films on iron in borate buffer solution caused by chloride ions. Various electrochemical kinetic criteria were measured. XPS, SIMS, and ISS studies were made of the systems used in the electrochemical work. The rate of breakdown was found to be prop…
Many different nonsilica-based fiber materials are presently being examined as possible candidates for use in extremely low loss fibers for infrared communications. One useful figure of merit in estimating fiber potential for low absorption is the total intrinsic scattering loss at the minimum dispersion wavelength. I…
Abstract Samples of isotactic polypropylene in the α form may have different degrees of order in the up and down positioning of the chains. By suitable programming of the crystallization history of unoriented samples it is possible to show, from DSC and WAXS data, that a strict correlation exists between the melting b…
Electroactive and electrochromic films of electropolymerized polyazulene and polythiophene have been found to be surprisingly insensitive to common solvents and temperature. As electrodes in all‐organic batteries these thin polymeric films allow current densities of 2 mA/cm 2 at open‐circuit voltages of 2.3V. The elec…
Abstract The new industrial strategy in the polymer field requires the transformation of plastic “commodities” into “specialties”. From this point of view, polypropylene (PP) plays an important role both for its intrinsic properties such as high melting temperature, low density, high chemical inertness and for its cap…
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTFire retardancy of thermoplastic materials by intumescenceYuval Halpern, Donna M. Mott, and Ronald H. NiswanderCite this: Ind. Eng. Chem. Prod. Res. Dev. 1984, 23, 2, 233–238Publication Date (Print):June 1, 1984Publication History Published online1 May 2002Published inissue…
Abstract In the past decade, polymer blend technology has achieved an important position in the field of polymer science. With increased academic and industrial research interest, the application of polymer blend technology to commercial utility has grown significantly. This review on the applications of polymer blend…
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTNew preparations of lanthanide alkoxides and their catalytical activity in Meerwein-Ponndorf-Verley-Oppenauer reactionsJ. L. Namy, J. Souppe, J. Collin, and H. B. KaganCite this: J. Org. Chem. 1984, 49, 11, 2045–2049Publication Date (Print):June 1, 1984Publication History Pu…
Abstract Using Garfield, Washington, nontronite as the model mineral system, methods and apparatus were developed to prepare reduced suspensions in citrate-bicarbonate-dithionite (CBD) solution. These techniques were effective in removing excess, undesired solutes from reduced suspensions while maintaining a high Fe 2…
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTEquilibrium adsorption of polycyclic aromatic hydrocarbons from water onto activated carbonRichard W. Walters and Richard G. LuthyCite this: Environ. Sci. Technol. 1984, 18, 6, 395–403Publication Date (Print):June 1, 1984Publication History Published online1 May 2002Publishe…
Abstract The mechanical properties of a variety of immiscible binary blends, with and without third component polymeric compatibilizers, are reviewed and qualitatively related to the degree of adhesion between blend components as determined by lap shear testing. Generally, blends comprised of components which adhere w…
Abstract Results of an investigation on the morphology, the crystallization and the thermal behavior of several binary crystallizable blends are reported. The composition, molecular mass and crystallization conditions strongly influence the crystallization and the thermal behavior as well as the overall morphology of…
SUMMARY Samples of six soils were incubated at 60°C for 24 h with several levels of either calcium carbonate or hydrochloric acid. Phosphate sorption was then measured on sub‐samples of the treated soils over 24 h at 25°C. In one set of measurements on all soils, 0.01 M calcium chloride was used as the background elec…
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTIon gate electrodes. Polypyrrole as a switchable ion conductor membranePaul Burgmayer and Royce W. MurrayCite this: J. Phys. Chem. 1984, 88, 12, 2515–2521Publication Date (Print):June 1, 1984Publication History Published online1 May 2002Published inissue 1 June 1984https://p…
Abstract On the basis of the extended Hückel molecular orbital calculation, the intermolecular overlaps of the highest occupied molecular orbitals are calculated for α-(BEDT-TTF)2I3 reported by Bender et al., and for superconducting β-(BEDT-TTF)2I3 reported by Yagubskii et al. (BEDT-TTF: bis(ethylenedithio)tetrathiafu…
Modern physicochemical biology steadily enriches our knowledge of the functional role of proteins and their elements-amino acids and peptides. These substances are involved in all essential molecular processes occurring in the living cell and perform key regulatory functions at the cellular and organismic levels. Thei…
Abstract Atomic standards of binding energies are presented for the calibration of X‐ray photoelectron spectrometers. The binding energies are measured using a VG Scientific ESCA 3 Mk II for which the photoelectron peak positions can be established with a measurement precision standard deviation of 5 meV. The absolute…
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTAnalysis of stress-induced phase separations in polymer solutionsC. Rangel-Nafaile, A. B. Metzner, and K. F. WissbrunCite this: Macromolecules 1984, 17, 6, 1187–1195Publication Date (Print):June 1, 1984Publication History Published online1 May 2002Published inissue 1 June 19…
Oxygen-derived free radicals have been proposed as general mediators of tissue injury in a variety of disease states. Recent interest has focused on the possibility that free radicals may be involved in ischemic myocardial damage. However, the exact types of damage that result from myocardial exposure to free radicals…
A great deal of information exists on the retraction occurring in pastes, mortars and concrete, twenty-four hours after being mixed; we have very little information, however, concerning the volumetric changes which take place in a shorter period of time, this being mainly due to the difficulties which arise in measuri…