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Direct Basal-Plane Shear in Single-Crystal Graphite

D. E. Soule、C. W. Nezbeda1968-10-01Journal of Applied Physics

The basal-plane shear stress-strain behavior of small, highly anisotropic-annealed natural graphite single crystals was studied at room temperature. A static uniaxial-shear stress was applied directly along the basal plane with a minimum of normal force, incorporating a technique to detect translations down to ∼40 Å.…

Graphene research and applicationsFiber-reinforced polymer compositesGraphite, nuclear technology, radiation studies

Mechanisms for Metal-Nonmental Transitions in Transition-Metal Oxides and Sulfides

David Adler1968-10-01OpenAlex

Transition-metal oxides and sulfides can be insulators, semiconductors, or metals, or undergo metal-nonmetal transitions. The experimental situation in these materials is briefly reviewed. Pure Bloch-Wilson theory predicts that many of the insulators should be metallic, so this class cannot be explained in terms of pu…

Magnetic and transport properties of perovskites and related materialsTransition Metal Oxide NanomaterialsElectronic and Structural Properties of Oxides

Anomalous Transport Phenomena in Eu-Chalcogenide Alloys

T. Kasuya、Akihiko Yanase1968-10-01OpenAlex

Various anomalous optical, magnetic, and transport phenomena have been found in Eu-chalcogenide alloys. Anomalous optical properties are explained by the magnetic exciton in which a hole in the $4f$ conduction band and an electron (for optically active magnetic exciton) in the $5d$ conduction band make a bound state.…

Magnetic and transport properties of perovskites and related materialsRare-earth and actinide compoundsPhase-change materials and chalcogenides

Intrinsic stacking faults in body-centred cubic crystals

V. Vítek1968-10-01OpenAlex

A study of the possibility of the existence of stacking faults in b.c.c. crystals on {110} and {112} planes has been performed, representing the lattice by a central force interaction between atoms. The same study was also carried out for {111} planes in f.c.c. crystals. The results for the f.c.c. lattice are in full…

Microstructure and mechanical propertiesForce Microscopy Techniques and ApplicationsTitanium Alloys Microstructure and Properties

Stereochemical criteria for polypeptides and proteins. V. Conformation of a system of three linked peptide units

C. M. Venkatachalam1968-10-01OpenAlex

Abstract The general conformations of a system of three linked peptide units are studied, and it is found that there are three types of conformations which contain NH…O hydrogen bonding between the first and the third units. One of them is part of a 3 10 ‐helix, while the other two arc nonhelical. The two nonhelical c…

Protein Structure and DynamicsChemical Synthesis and AnalysisEnzyme Structure and Function

Band Structure and Electrical Conductivity of NiO

J. Feinleib、David Adler1968-09-30Physical Review Letters

It is proposed that the dominant mechanism for electrical conduction in NiO and similar materials is by means of holes in the oxygen $2p$ band. A band-structure diagram which takes into account the primarily localized $3d$ states is suggested.

ZnO doping and propertiesGas Sensing Nanomaterials and SensorsTransition Metal Oxide Nanomaterials

Exciton-Magnon Interaction in Magnetic Insulators

Smith Freeman、J. J. Hopfield1968-09-23Physical Review Letters

The one-exciton, one-magnon system is treated for a suitable antiferromagnetic insulator, Mn${\mathrm{F}}_{2}$. Zone-edge excitons and magnons are found to interact quite strongly. Bound states are found to exist under favorable circumstances. The line shapes of magnon sidebands of excitonic transitions are modified.…

Physics of Superconductivity and MagnetismMagnetic and transport properties of perovskites and related materialsAdvanced Condensed Matter Physics

Evidence of Coupling Between One- and Two-Phonon Excitations in Quartz

J. F. Scott1968-09-23Physical Review Letters

We have extended earlier work on the Raman spectrum of quartz to both higher and lower temperatures (6-900\ifmmode^\circ\else\textdegree\fi{}K), and find evidence for the assignment of features in the 130- to ${200\ensuremath{-}\mathrm{c}\mathrm{m}}^{\ensuremath{-}1}$ region as second order. Anomalies in the temperatu…

Spectroscopy and Quantum Chemical StudiesSolid-state spectroscopy and crystallographyQuantum, superfluid, helium dynamics

Effect of Pressure on the Metal-Nonmetal Transition and Conductivity ofFe3O4

G. A. Samara1968-09-16Physical Review Letters

It was recently suggested that the metal-nonmetal transition which occurs in ${\mathrm{Fe}}_{3}$${\mathrm{O}}_{4}$ at \ensuremath{\simeq}120\ifmmode^\circ\else\textdegree\fi{}K may be of the Mott-Wigner type. Present results on the effects of pressure on the transition temperature and the conductivity of the low-tempe…

Theoretical and Computational PhysicsMagnetic Properties and Synthesis of FerritesIron oxide chemistry and applications

Gadolinium Molybdate, a New Type of Ferroelectric Crystal

L. E. Cross、A. Fousková、S. E. Cummins1968-09-16Physical Review Letters

Ferroelectric properties in gadolinium molybdate are shown to originate from a new mechanism completely different from that in conventional ferroelectric materials. In this crystal the spontaneous polarization results from an elastic instability which gives rise to a spontaneous strain in the original piezoelectric pa…

Glass properties and applicationsAcoustic Wave Resonator TechnologiesSolid-state spectroscopy and crystallography

Acoustic Attenuation in Solids

R. Kishore1968-09-15Physical Review

With the help of the correlation-function formula given by McLennan, an expression for the viscosity tensor is obtained within the Hartree-Fock approximation using the cubic anharmonic momentum-flux operator. In the Debye approximation for phonons and with a simple expression for relaxation time, solutions are obtaine…

High-pressure geophysics and materialsMaterial Dynamics and PropertiesThermal properties of materials

Magnetoresistance in Semiconducting Strontium Titanate

O. N. Tufte、E. L. Stelzer1968-09-15Physical Review

The weak-field magnetoresistance coefficients have been measured in niobium-doped SrTi${\mathrm{O}}_{3}$ at 4.2, 77, and 120\ifmmode^\circ\else\textdegree\fi{}K. The results at 77 and 120\ifmmode^\circ\else\textdegree\fi{}K are consistent with a conduction-band structure consisting of minima along the $〈100〉$ reciproc…

Ferroelectric and Piezoelectric MaterialsMagnetic and transport properties of perovskites and related materialsElectronic and Structural Properties of Oxides

Si–Te System: Partial Pressures of Te2 and SiTe and Thermodynamic Properties from Optical Density of the Vapor Phase

R. F. Brebrick1968-09-15The Journal of Chemical Physics

The optical density between 2400 and 7000 Å of the vapor in equilibrium with Si–Te samples containing between 10 and 100 at.% Te was measured for sample temperatures between 500° and 940°C. The partial pressures of Te2(g), pTe2, were obtained from the optical densities at 4357, 5000, and/or 5500 Å, where SiTe(g) does…

Chalcogenide Semiconductor Thin FilmsCrystal Structures and PropertiesPhase-change materials and chalcogenides

Raman Spectra of BaClF, BaBrF, and SrClF

J. F. Scott1968-09-15The Journal of Chemical Physics

The frequencies and symmetries of the even-parity lattice vibrations of BaClF, BaBrF, and SrClF are determined by means of polarized Raman scattering from oriented single crystals. The polarizations and frequencies of the vibrations are interpreted in terms of symmetry coordinates.

Luminescence Properties of Advanced MaterialsSolid-state spectroscopy and crystallographyInorganic Fluorides and Related Compounds

Electro-Optic Measurements of PbS, PbSe, and PbTe

D. E. Aspnes、M. Cardona1968-09-15Physical Review

The band structures of the lead salts PbS, PbSe, and PbTe have been studied by electro-optic methods. Electroabsorption and electroreflectance measurements have been made over the energy ranges 0.25 to 0.65 eV and 0.6 to 5.5 eV, respectively, using an electrolyte to produce electric fields at the surface of these mate…

Quantum Dots Synthesis And PropertiesChalcogenide Semiconductor Thin FilmsMolecular Junctions and Nanostructures

Symmetry and Reststrahlen in Elemental Crystals

R. Zallen1968-09-15Physical Review

Lattice vibrations in elemental crystals can possess a first-order electric moment, and thus exhibit reststrahlen (symmetry-allowed one-phonon infrared absorption), by the mechanism of displacement-induced charge redistribution (dynamic charge). By a group-theoretical investigation of the relation between symmetry and…

Crystallography and molecular interactionsSolid-state spectroscopy and crystallographyX-ray Diffraction in Crystallography

The elastic constants of crystalline native cellulose

M. A. Jaswon、Peter P. Gillis、Richard E. Mark1968-09-10Proceedings of the Royal Society of London A Mathematical and Physical Sciences

Abstract A new theoretical analysis is made of the elastic constants of crystalline native cellulose. Primary interatomic forces are considered in the calculation of the Young modulus in the chain direction, where we retrieve a result identical to that of Treloar. Hydrogen bonds provide the main mechanism for determin…

Biofuel production and bioconversionAdvanced Cellulose Research StudiesLignin and Wood Chemistry

Antiferromagnetism and the Magnetic Phase Diagram of GdAlO3

K. W. Blazey、H. Rohrer1968-09-10Physical Review

Measurements of the magnetization and differential susceptibility of GdAl${\mathrm{O}}_{3}$ have been made in pulsed magnetic fields in the temperature range 1.3-100\ifmmode^\circ\else\textdegree\fi{}K. It is found that GdAl${\mathrm{O}}_{3}$ is a uniaxial antiferromagnet with the easy axis of magnetization along the…

Magnetic and transport properties of perovskites and related materialsAdvanced Condensed Matter PhysicsInorganic Fluorides and Related Compounds

Paramagnetic-Resonance Studies of Rare-Earth Impurities in II-VI Compounds

R. K. Watts、W. C. Holton1968-09-10Physical Review

An electron-paramagnetic-resonance study of rare-earth impurities in II-VI compounds has been made. Isolated trivalent rare-earth ions are found to be substitutional for the metal ion in the zinc-blende crystals. Spectra from trivalent ions both at the isolated substitutional site and incorporated in additional unknow…

Semiconductor Quantum Structures and DevicesPhase-change materials and chalcogenidesOptical properties and cooling technologies in crystalline materials

Diffracted Wave Fields Expressible by Plane-Wave Expansions Containing Only Homogeneous Waves

George C. Sherman1968-09-09Physical Review Letters

A comprehensive study of the properties of "source-free" wave fields (i.e., diffracted wave fields expressible by plane-wave expansions containing only homogeneous waves) is summarized. The theorems proved in the study are stated. A new series mode expansion for "source-free" wave fields in included.

Photonic and Optical DevicesOrbital Angular Momentum in OpticsOptical Coatings and Gratings