Materials Literature
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Recently, interest in composite manufacturing has shifted towards the use of natural fibres as reinforcement because of their environmental benefits. The use of a biodegradable matrix is worth considering since this would result in a completely biodegradable composite. In order to assess the most suitable matrix polym…
Introduction to Polyoxometalate Chemistry: From Topology via Self-Assembly to Applications M.T. Pope, A. Muller. Synthetic Strategies. 1. Rational Approaches to Polyoxometalate Synthesis R.J. Errington. 2. Functionalization of Polyoxometalates: Achievements and Perspectives A. Proust, R. Villaneau. 3. From the First S…
Mining, production, application and safety issues of cerium-based materials, K. Schermanz structural properties and nonstoichiometric behaviour of CeO2, A. Trovarelli synthesis and modification of ceria-based materials, G. Adachi and T. Masui chemical and nanostructural aspects of the preparation and characterization…
Layered double hydroxides (LDHs) have been investigated for many years as host materials for a range of anion exchange intercalation reactions. In this role they have been used extensively as ion-exchange materials, catalysts, sorbents and halogen absorbers. More recently, there have been a tremendous number of new de…
Abstract Eight persons from five institutions in different countries carried out polymerizations of aniline following the same preparation protocol. In a "standard" procedure, aniline hydrochloride was oxidized with ammonium peroxydisulfate in aqueous medium at ambient temperature. The yield of polyaniline was higher…
Chapter headings. Mechanism of fatigue in the absence of defects and inclusions. Stress concentration. Notch effect and size effect. Effect of size and geometry of small defects on the fatigue limit. Effect of hardness HV on fatigue limits of materials containing defects, and fatigue limit prediction equations. Effect…
LITHOGRAPHY Introduction Historical Note: Lithography's Origins Photolithography Overview Critical Dimension, Overall Resolution, Line-Width Lithographic Sensitivity and Intrinsic Resist Sensitivity (Photochemical Quantum Efficiency) Resist Profiles Contrast and Experimental Determination of Lithographic Sensitivity R…
A broad review of recent research work on the preparation and the remarkable properties of intercalation compounds of graphite, covering a wide range of topics from the basic chemistry, physics and materials science to engineering applications.
The empirical Rothmund–Kornfeld power function approach (in terms of equivalent fractions) was applied to potassium–calcium (K–Ca) exchange equilibrium carried out at 25°C and 0.05 M ionic strength on 4 soils derived from volcanic materials in southern Chile. Results were compared with those obtained by the Gaines–Tho…
The heterogeneous oxidation of cyclooctene with hydrogen peroxide catalyzed by manganese 5,10,15,20-tetrakis(2′,6′-dichlorophenyl)porphyrinate, in the presence of hexafluoroacetone hydrate as co-catalyst, has been studied in supercritical carbon dioxide, at 40 °C and 20 MPa. Under proper conditions, a complete olefin…
Klackenberg, Jens (2001): Revision of the genus Cryptostegia R. Br. (Apocynaceae, Periplocoideae). Adansonia (3) 23 (2): 205-218, DOI: http://doi.org/10.5281/zenodo.5180147
Abstract The polymer bound Schiff‐base ligand (PS‐SalGlu) has been prepared from polystyrene bound salicylaldehyde and glutamic acid, and its complex (PS‐SalGlu‐Co) has also been synthesized. The polymer ligand and its complex were characterized by infrared spectroscopy, small area X‐ray photoelectron spectroscopy, an…
Abstract Aniline was polymerized directly into polyaniline‐sulfate salt without using protonic acid in this work. Polyaniline‐sulfate salt was prepared by emulsion and aqueous polymerization pathways. The dopant i.e. sulfate ion in polyaniline‐sulfate salt was generated from ammonium persulfate which was used for oxid…
Thick cubic boron nitride (cBN) films showing clear crystal facets were achieved by chemical vapor deposition. The films show the highest crystallinity of cBN films ever achieved from gas phase. Clear evidence for the growth via a chemical route is obtained. A growth mechanism is suggested, in which fluorine preferent…
BACKGROUND: Tissue engineering is a promising approach for obtaining lifetime durability in biological heart valves. Basic questions with respect to the selection of suitable cell populations as well as scaffolds remain unsolved. The purpose of this study was to develop a tissue-like substitute in vitro for replacemen…
Zirconia is more chemically stable than silica and γ-alumina, which are commonly used in the preparation of inorganic membranes. However, the hydrolysis of zirconia alkoxides, typical zirconia precursors, proceeds rapidly, leading to difficulties in preparing clear sols. Thus, an attempt was made to reduce the hydroly…
Single-walled carbon nanotubes (SWCNs) encapsulated in multiwalled WS2 nanotubes are produced by pyrolyzing a mixture of WO3−x and SWCNs in N2/H2S atmosphere.
Abstract Fluorosilicone elastomer based on the poly[(3,3,3‐trifluoropropyl)methylsiloxane‐co‐(3,3,4,4,5,5,6,6,6‐nonafluorohexyl)methylsiloxane] was studied. First, the synthesis of fluorosilicone polymer based on the poly[(3,3,4,4,5,5,6,6,6‐nonafluorohexyl)methylsiloxane] (PNFHMS) was examined by the polymerization of…
In this paper we consider the numerical approximation of phase field and sharp interface models for diffusion-induced grain boundary motion. The phase field model consists of a double-obstacle Allen-Cahn equation with a forcing obtained from the solution of a degenerate diffusion equation. On the other hand the sharp…
All articles of this category A general two-step, one-pot-synthesis of meso -triphenylcorrole from 5-phenyldipyrrane is presented. A number of p -phenyl-substituted 5-phenyldipyrranes were condensed with substituted benzaldehydes under acid catalyzed conditions to produce a mixture highly enriched in the corresponding…