Materials Literature
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New analytical diagnostic techniques that are based on signal-amplification mechanisms could significantly improve the sensitivity of detection of various analytes. We have developed a new approach to achieving exponential amplification of a diagnostic signal through a two-component dendritic chain reaction. The chain…
We propose to utilize multiple-graphene-layer structures with lateral p-i-n junctions for terahertz and infrared (IR) photodetection and substantiate the operation of photodetectors based on these structures. Using the developed device model, we calculate the detector dc responsivity and detectivity as functions of th…
It has been shown previously that the thermoelectric properties of the Zintl phase compound YbCd2Sb2 can be finely tuned via Zn substitution at the Cd-site in the anionic (Cd2Sb2)2− framework. Here we report the results of the investigation of isoelectronic substitution of Yb by Ca. The p-type Yb1−xCaxCd2Sb2 (0.2≤x≤0.…
Department of Structural Engineering, Politecnico di Torino, Corso Duca degli Abruzzi 24, 10129, Torino, ItalyWe study the equilibrium core radius of a carbon nanoscroll (CNS) formed from spontaneous rollingof a graphene sheet. By a balance between the elastic bending energy and the van der Waalsinteraction energy in…
Consideration of surface effects in microscaled and nanoscaled materials is important for accurate prediction of their dynamic behavior. In this study, the Timoshenko beam model is modified to include the surface effects and used to analyze the vibration of nanotubes as well as calculate their natural frequencies. The…
Using First-principles calculations, we have studied the structural, electronic and elastic properties of Nb4AlC3, a new compound belonging to the MAX phases. Geometrical optimization of the unit cell is in good agreement with the experimental data. The effect of high pressures, up to 20 GPa, on the lattice constants…
This article reviews the experimental and theoretical aspects of vibrational hyper-Raman scattering from molecules. Particular emphasis is placed on hyper-Raman scattering enhanced by nanostructured metal surfaces and by two-photon electronic resonance.
Silver nanoparticles possess many valuable optical properties that have opened the door to new approaches in sensing and imaging applications, offering a wide range of detection modes such as colorimetric, scattering, SERS, and MEF techniques, at extremely low detection limits. Moreover, nanoparticles have made possib…
Degradation of poly[(1,4-butylene terephthalate)-co-(1,4-butylene adipate)] (Ecoflex, BTA) monofilaments (rods) in standardized sandy soil was investigated. Changes in the microstructure and chemical composition distribution of the degraded BTA samples were evaluated and changes in the pH and salinity of postdegradati…
Abstract Nanoparticles are increasingly being recognized for their potential utility in biological applications including nanomedicine. Here, we have synthesized zinc oxide (ZnO) nanorods using zinc acetate and hexamethylenetetramine as precursors followed by characterizing using X-ray diffraction, fourier transform i…
Highly ordered superlattices assembled from transition metal oxide/sulfide submicrometer particles are difficult to prepare due to lack of monodisperse primary building blocks. In this work, we have successfully synthesized monodisperse Cu(2)O spheres with diameters in the submicrometer regime of 130-135 nm. Using the…
The dynamics of the CdSe nanorod synthesis reaction have been studied, giving attention to the kinetics of magic-sized clusters (MSCs) that form as intermediates in the overall reaction. The MSCs have a distinct absorption peak, and the kinetics of this peak give insight into the overall reaction mechanism. In these s…
A series of La(1-x)Sr(x)M(1-y)Fe(y)O(3) (M = Mn, Co; x = 0, 0.4; y = 0.1, 1.0) perovskite-type oxide catalysts have been fabricated via a strategy of citric acid complexation coupled with hydrothermal treatment. The materials are characterized by a number of analytical techniques. The oxidation of toluene is used as a…
The sol-gel process is very effective for the preparation of new materials with potential applications in optics, sensors, catalyst supports, coatings, and specialty inorganic polymers that can be used as hosts for the accommodation of organic molecules. The low temperature employed in the process is the main advantag…
In this article a comparative study of the behaviour of different commercial anti-graffiti on natural stone and brick is presented. 8 different European substrates were selected and 4 commercial anti-graffiti of different chemical nature were applied on these substrates. The variations of their hydric properties and a…
Despite the interest in identifying systemic effects caused by the metallic particles released from long term metallic implants in the body, few works support reliable conclusions about the effects of those particles in organs. The aim of the present work is to look for damages in tissues of liver, kidney, lung and he…
Equal participation of women and men in industrial research is still a major challenge for the European Union. In most European countries, female graduates proportionately outnumber male graduates. However, scientific research and technological development remain male-dominated, especially in industry. Construction is…
Titania nanofibers were successfully synthesized by sol-gel coating of electrospun polymer nanofibers followed by calcining to form either the pure anatase or rutile phases. Characterization of these materials was carried out using scanning electron microscopy (SEM), transmission electron microscopy (TEM), diffuse ref…
Fluorescent silica nanoparticles, Cornell dots (Cdots), were incorporated into electrospun celluloseacetate (CA) fibers. Two types of C dots were usedin this study. The first type was comprised of afluorescent dye-containing silica core surrounded bya silica shell. These nanoparticles fluoresce at 572nm when exposed t…