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Periodic mesoporous organosilica with ionic-liquid framework supported manganese: an efficient and recyclable nanocatalyst for the unsymmetric Hantzsch reaction

Masoud Nasr‐Esfahani、Dawood Elhamifar、T. Amadeh 等 4 位作者2015-01-01RSC Advances

We have described the catalytic application of a manganese containing ionic liquid-based ordered mesoporous organosilica in the synthesis of polyhydroquinolines.

Ionic liquids properties and applicationsMesoporous Materials and CatalysisMulticomponent Synthesis of Heterocycles

Overcoming the concentration-dependence of responsive probes for magnetic resonance imaging

Levi A. Ekanger、Matthew J. Allen2015-01-01Metallomics

In magnetic resonance imaging, contrast agents are molecules that increase the contrast-to-noise ratio of non-invasively acquired images. The information gained from magnetic resonance imaging can be increased using responsive contrast agents that undergo chemical changes, and consequently changes to contrast enhancem…

Advanced MRI Techniques and ApplicationsLanthanide and Transition Metal ComplexesAtomic and Subatomic Physics Research

Exploring the influence of electron beam irradiation on the morphology, physico-mechanical, thermal behaviour and performance properties of EVA and TPU blends

Joyeeta Dutta、Tuhin Chatterjee、Gopal Chandra Dhara 等 4 位作者2015-01-01RSC Advances

Investigation of electron beam irradiated EVA/TPU blends leads to significant improvements in performance properties suitable for various technological applications.

Polymer Nanocomposites and PropertiesPolymer Nanocomposite Synthesis and IrradiationSilicone and Siloxane Chemistry

Dual-responsive shape memory hydrogels with novel thermoplasticity based on a hydrophobically modified polyampholyte

Yujiao Fan、Wanfu Zhou、Akram Yasin 等 5 位作者2015-01-01Soft Matter

Shape memory hydrogels offer the ability to recover their permanent shape from temporarily trapped shapes without application of external forces. Here, we report a novel dual-responsive shape memory hydrogel with characteristic thermoplasticity. The water-insoluble hydrogel is prepared by simple ternary copolymerizati…

Hydrogels: synthesis, properties, applicationsPolymer composites and self-healingAdvanced Materials and Mechanics

Study on key step of 1,3-butadiene formation from ethanol on MgO/SiO 2

Minhua Zhang、Meixiang Gao、Jianyue Chen 等 4 位作者2015-01-01RSC Advances

Adsorption properties of ethanol on different MgO/SiO <sub>2</sub> surfaces were researched using density functional theory and the result is that ethanol is mainly adsorbed on MgO surface. The role of SiO <sub>2</sub> in increasing the MgO crystal defects in the MgO/SiO <sub>2</sub> has been obtained.

Catalytic Processes in Materials ScienceMesoporous Materials and CatalysisCatalysis for Biomass Conversion

Biodegradable and biocompatible soy protein/polymer/adhesive sticky nano-textured interfacial membranes for prevention of esca fungi invasion into pruning cuts and wounds of vines

Soumyadip Sett、M. W. Lee、M. Weith 等 5 位作者2015-01-01Journal of Materials Chemistry B

Adhesive biodegradable membranes (patches) for the protection of pruning locations of plants from esca fungi attacks were developed using electrospun soy protein/polyvinyl alcohol and soy protein/polycaprolactone nanofibers. Several different water-soluble adhesives were either added directly to the electrospinning so…

Nanocomposite Films for Food PackagingElectrospun Nanofibers in Biomedical ApplicationsPlant Surface Properties and Treatments

Spiroboronate Si-rhodamine as a near-infrared probe for imaging lysosomes based on the reversible ring-opening process

Weiwei Zhu、Xiaoyun Chai、Baogang Wang 等 7 位作者2015-01-01Chemical Communications

A cyclic boronate structure was incorporated into Si-rhodamine to design a pH-activatable near-infrared (NIR) probe based on the reversible ring-opening process triggered by H(+). The probe showed general suitability of specific labelling of acidic lysosomes and tracking their pH changes in living cells.

Molecular Sensors and Ion DetectionNanoplatforms for cancer theranosticsLuminescence and Fluorescent Materials

Large resistive switching and switchable photovoltaic response in ferroelectric doped BiFeO 3 -based thin films by chemical solution deposition

Linxing Zhang、Jun Chen、Jiangli Cao 等 5 位作者2015-01-01Journal of Materials Chemistry C

The ferroelectric doped BiFeO <sub>3</sub> thin films exhibit large resistive switching (with ON/OFF ratios ∼10 <sup>4</sup> ) and stably switchable photovoltaic response with good retention properties, providing multiple selections for non-destructive ferroelectric memory diveces.

Ferroelectric and Piezoelectric MaterialsAdvanced Memory and Neural ComputingMultiferroics and related materials

Electrochemical Performance of Carbon/MnO2Nanocomposites Prepared via Molecular Bridging as Supercapacitor Electrode Materials

Claudia Ramirez-Castro、Olivier Crosnier、Laurence Athouël 等 6 位作者2015-01-01Journal of The Electrochemical Society

The chemical binding of amorphous manganese oxide and carbon particles was achieved with the diazonium chemistry. The synthesis was performed in two steps, with a first step consisting in the surface functionnalization of carbon particles with aminophenyl groups and the subsequent attachment of amorphous manganese oxi…

Supercapacitor Materials and FabricationConducting polymers and applicationsAdvanced battery technologies research

Effects of Two Different Cellulose Nanofiber Types on Properties of Poly(vinyl alcohol) Composite Films

Kitti Yuwawech、Jatuphorn Wootthikanokkhan、Supachok Tanpichai2015-01-01Journal of Nanomaterials

This work concerns a study on the effects of fiber types and content of cellulose nanofiber on mechanical, thermal, and optical properties polyvinyl alcohol (PVA) composites. Two different types of cellulose nanofibers, which are nanofibrillated cellulose (NFC) and bacterial cellulose (BC), were prepared under various…

Nanocomposite Films for Food PackagingAdvanced Cellulose Research StudiesElectrospun Nanofibers in Biomedical Applications

Effect of ionic interaction on the mechanochromic properties of pyridinium modified tetraphenylethene

Ting Hu、Bicheng Yao、Xiujuan Chen 等 8 位作者2015-01-01Chemical Communications

Introducing ionic interaction into a soft tetraphenylethene-based AIE-molecule furnished the compound with robust mechanochromic effects while exhibiting aggregation-induced emission enhancement properties.

Molecular Sensors and Ion DetectionLuminescence and Fluorescent MaterialsPolydiacetylene-based materials and applications

Fluorescent chemodosimeter based on spirobenzopyran for organophosphorus nerve agent mimics (DCP)

Shyamaprosad Goswami、Sangita Das、Krishnendu Aich2015-01-01RSC Advances

A new chromogenic as well as fluorogenic protocol based on the spirobenzopyran system for the selective detection of nerve agent mimics (diethyl chlorophosphate or DCP vapour) within a few seconds (∼30 s) is designed, synthesized and characterized in this study.

Molecular Sensors and Ion DetectionLuminescence and Fluorescent MaterialsPhotochromic and Fluorescence Chemistry

Preferential occupancy of strontium in the hydroxyapatite lattice in biphasic mixtures formed from non-stoichiometric calcium apatites

P. Nandha Kumar、Sandeep K. Mishra、R. Udhay Kiran 等 4 位作者2015-01-01Dalton Transactions

The present study reports the variations in phase content of biphasic mixtures and structural changes induced by different levels of strontium addition in calcium-deficient apatite (Ca/P = 1.60) powders during heat treatment. The synthesis was attempted by an in situ aqueous precipitation technique and X-ray diffracti…

Bone Tissue Engineering MaterialsCrystal Structures and PropertiesX-ray Diffraction in Crystallography

Influence of Zn doping on the electrochemical capacitor behavior of MnO 2 nanocrystals

R. Poonguzhali、N. Shanmugam、R. Gobi 等 6 位作者2015-01-01RSC Advances

Herein, we suggest a simple chemical precipitation method for the preparation of bare and different levels of Zn doped MnO <sub>2</sub> nanoparticles as electrodes for supercapacitors.

Advancements in Battery MaterialsSupercapacitor Materials and FabricationConducting polymers and applications

Electric field mediated non-volatile tuning magnetism at the single-crystalline Fe/Pb(Mg 1/3 Nb 2/3 ) 0.7 Ti 0.3 O 3 interface

Chao Zhang、Fenglong Wang、Chunhui Dong 等 7 位作者2015-01-01Nanoscale

We report non-volatile electric-field control of magnetism modulation in Fe/Pb(Mg1/3Nb2/3)0.7Ti0.3O3 (PMN-PT) heterostructure by fabricating an epitaxial Fe layer on a PMN-PT substrate using a molecular beam epitaxy technique. The remnant magnetization with a different electric field shows a non-symmetric loop-like sh…

Ferroelectric and Piezoelectric MaterialsMagnetic and transport properties of perovskites and related materialsMultiferroics and related materials

Ultralight anisotropic foams from layered aligned carbon nanotube sheets

Shaghayegh Faraji、Kelly L. Stano、Özkan Yıldız 等 6 位作者2015-01-01Nanoscale

In this work, we present large scale, ultralight aligned carbon nanotube (CNT) structures which have densities an order of magnitude lower than CNT arrays, have tunable properties and exhibit resiliency after compression. By stacking aligned sheets of carbon nanotubes and then infiltrating with a pyrolytic carbon (PyC…

Carbon Nanotubes in CompositesSupercapacitor Materials and FabricationFiber-reinforced polymer composites

Homogenously hexagonal prismatic AgBiS 2 nanocrystals: controlled synthesis and application in quantum dot-sensitized solar cells

Na Liang、Wenlong Chen、Fang Dai 等 12 位作者2015-01-01CrystEngComm

Homogenously hexagonal prismatic AgBiS2 nanocrystals with sizes of about 7.6 nm have been synthesized by the selective absorption of oleylamine and anisotropic growth in a mixed solvent system. Quantum dot-sensitized solar cells with the as-prepared AgBiS2 nanocrystals as counterelectrode materials showed a conversion…

Advanced Photocatalysis TechniquesQuantum Dots Synthesis And PropertiesChalcogenide Semiconductor Thin Films

Morphological tuning via structural modulations in AIE luminogens with the minimum number of possible variables and their use in live cell imaging

Roop Shikha Singh、Rakesh Kumar Gupta、Rajendra Prasad Paitandi 等 7 位作者2015-01-01Chemical Communications

With intent to fine tune the morphological and photophysical properties, three novel AIE luminogens (BQ1-BQ3) based on quinoline-BODIPY have been synthesized. A judicious choice of substituents (-H, -CH3, -OCH3) in these systems led to nanoballs in BQ1 and BQ2, while in BQ3 it led to reticulated nanofibers with divers…

Molecular Sensors and Ion DetectionNanoplatforms for cancer theranosticsLuminescence and Fluorescent Materials