Materials Literature
按标题、摘要、年份、主题和来源检索公开元数据。结果保留作者、摘要、分类与原始来源链接。
Lors du filage de fibres de cellulose par le procede Lyocell utilisant le melange d'oxyde de N-methylmorpholine et d'eau, la formation de la structure des fibres a ete etudiee. La forme du filament dans l'air apres la filiere a ete mesuree en meme temps que la croissance de la birefringence en utilisant un appareillag…
Photoexcitation of p -nitroaniline (PNA) and its N -alkyl derivatives results in the formation of triplet states with dipole moments considerably larger than that of the ground state, as monitored by time-resolved microwave conductivity (TRMC). The triplet state lifetime, τ T, is only 54 ns for PNA in benzene but incr…
Energy-transfer rate constants between two trivalent lanthanide ions have been determined at a short and fixed distance of ca. 4 Å, by using mixed dimers of tris(acetylacetonato)lanthanide complex, Ln(acac)3, formed in chloroform. The energy-transfer rate constants were obtained by measuring the luminescence decay con…
A recursive approach is used to evaluate the resulting molecular structure of a network-forming system composed of a mixture of bifunctional and monofunctional prepolymer chains reacting with a polyfunctional cross-linker (A f + B 2 + B 1 ). This system can be used to find formulations for model networks with pendant…
The complex [CuNiL][ClO4]2·H2O (SNi= 1) of a dinucleating macrocycle H2L, derived from the [2: 1 : 1] condensation of 2,6-diformyl-4-methylphenol, 1,2-diaminoethane and 1,4-diaminobutane, has been obtained. The efflorescent dimethylformamide (dmf) adduct [CuNiL][ClO4]2·H2O·2dmf crystallizes in the orthorhombic crystal…
The controlled functionalization of polystyrene using a process of metalation with a potassium superbase followed by reaction with electrophiles is described. The method is advantageous because metalation is extremely efficient, occurring rapidly even at room temperature, and the degree of functionalization can be con…
AISI types 304, 316 and 317 stainless steels (SS) containing various levels of nitrogen were evaluated for their pitting corrosion resistance in an acidic chloride medium containing 0.5M NaCl and 0.5M H2SO4. Potentiodynamic anodic polarisation were conducted at room temperature to determine the critical pitting potent…
E. coli dihydrodipicolinate reductase exhibits unusual nucleotide specificity, with NADH being kinetically twice as effective as NADPH as a reductant as evidenced by their relative V/K values. To investigate the nature of the interactions which determine this specificity, we performed isothermal titration calorimetry…
The dispersion and surface structure of molybdena supported on CeO2 have been studied by using XRD, XPS, LRS and FTIR spectroscopies. The samples were prepared by mixing MoO3 and CeO2 and by impregnating CeO2 with an aqueous solution of ammonium polymolybdate. The results indicate that the dispersion capacity of MoO3…
Parameters for the commercially available modeling package SYBYL have been developed for Gd(3+) complexes allowing these to be studied with molecular mechanics. With these parameters and a technique termed the "coordination scan", the coordination numbers of Gd(III) based complexes can be predicted, and thus the hydra…
Nonlinear dielectric spectroscopy is used to study the self-association of 2-pyrrolidinone in benzene solutions up to 0.9 mol/L at 25 °C. The nonlinear dielectric spectra below 100 MHz are recorded using an LC-resonant circuit, while above 100 MHz a partial coaxial resonant cavity is used. Both the kinetic and thermod…
This paper describes an experimental investigation of dipole−dipole interactions between molecules in an orientationally ordered environment. Measurements are reported of the dielectric properties of a series of anisotropic solutions of two structurally similar dipolar solutes (1-cyano-2-fluoro-4-[ trans -4-( trans -4…
The effects of preparation method, nature of the silica support, oxide loading (0.2−7.0 wt %), and pretreatment conditions on the reduction pattern of MoO 3 /SiO 2 catalysts have been systematically investigated by temperature-programmed reduction (TPR) measurements in the range 200−1200 °C. Modeling of TPR spectra of…
Small-angle neutron scattering (SANS) has been used to investigate the thermal concentration fluctuations in a single-phase state of binary polymer mixtures such as deuterated polystyrene (DPS)/poly(vinyl methyl ether) (PVME), deuterated polybutadiene (DPB)/protonated polybutadiene (HPB), and DPB/protonated polyisopre…
X-ray scattering has been used to investigate the structures of Kr, Xe, and N 2 monolayers adsorbed on the basal plane of boron nitride. The results indicate that all three monolayers form a 2D solid of the simple triangular structure. Both Kr and N 2 monolayers are commensurate with respect to the substrate only in v…
The molecular and electronic structures of TCNQ and its π-extended derivatives benzo-TCNQ and TCAQ have been investigated using the semiempirical PM3 method and ab initio 6-31G* calculations. The steric hindrance introduced by lateral benzoannulation determines the loss of planarity of the TCNQ moiety for benzo-TCNQ a…
A new pyrazolate-bridged tetranuclear copper(II) complex [{CuL(H2O)}4]·12H2O (H2L = 5-methoxycarbonylpyrazole-3-carboxylic acid) was synthesized and its crystal structure determined. The molecule has C2 symmetry and consists of four copper atoms bridged by four planar L ligands through the nitrogen atoms of the pyrazo…
Investigations were done on the enhanced aqueous solubility of glibenclamide. Eight kin & of glibenclamide coprecipitates, using two kinds of polyvinylpyrrolidone (PVP) having different molecular weights, were prepared in a solid powdered form by the conventional evaporation method. The formation of coprecipitates was…
Density functional calculations within the Car−Parrinello framework are used to obtain self-consistently the electronic and the geometrical structures of polythiophene derivatives. The relation between the electronic states and quinoid vs aromatic structures is studied on a series of substituted polythiophenes (PTh) a…
New examples of terminal group 5 chalcogenido-substituted polytungstates with the Keggin [PW11O39ME]4- (M = Nb, Ta; E = S, Se) (pictured) and Lindquist [W5O18NbSe]3- structures have been prepared by oxo/chalcogenido ligand substitution reactions. The compounds and their reactions with H2O in nonaqueous solution were c…