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Silber(I)‐orthoborat

Martin Jansen、W. Scheld1981-06-01Zeitschrift für anorganische und allgemeine Chemie

Abstract Die Darstellung von Ag 3 BO 3 gelingt durch Umsetzung der binären Komponenten Ag 2 O und B 2 O 3 unter erhöhtem Sauerstoffdruck. Im Bereich von 180–210°C zeigt Ag 3 BO 3 einen reversiblen Farbumschlag von gelb nach rot, der von einem schwachen endothermen Effekt (DTA), jedoch nicht von Strukturänderungen begl…

Crystal Structures and PropertiesOrganometallic Compounds Synthesis and CharacterizationChemical Synthesis and Characterization

Onset of phase separation in segmented urethane polymerization

José M. Castro、Francisco López‐Serrano、R. E. Camargo 等 5 位作者1981-06-01Journal of Applied Polymer Science

Abstract The development of heterogeneous structure during the polymerization of a polyurethane system using a polyether diol of M̄ n = 2000 as the soft segment and 4,4′‐diphenylmethane disocyanate extended with 1,4‐butanediol as the hard segment was monitored following the amount of light transmitted by the sample an…

Advanced Polymer Synthesis and CharacterizationPolymer composites and self-healingPhotopolymerization techniques and applications

The diatom genus Aulacoseira Thwaites: its structure and taxonomy

Richard M. Crawford1981-06-01Phycologia

The separation of Aulacoseira from Melosira C. Ag. in 1848 by Thwaites is substantiated with new light and electron microscope observations. Differences between the two genera concern the habitat, position of the nucleus, valve and girdle-band structure and, in Aulacoseira, lack of rimoportulae but presence of a disti…

Diatoms and Algae ResearchAquatic Invertebrate Ecology and Behavior

Reactions of poly(phenylene oxide)s with quinones. I. The quinone‐coupling reaction between low‐molecular‐weight poly(2,6‐dimethyl‐1,4‐phenylene oxide) and 3,3′,5,5′‐tetramethyl‐4,4′‐diphenoquinone

Dwain M. White1981-06-01Journal of Polymer Science Polymer Chemistry Edition

Abstract A bifunctional polymer is formed when low‐molecular‐weight poly(2,6‐dimethyl‐1,4‐phenylene oxide) (I) reacts with 3,3′,5,5′‐tetramethyl‐4,4′‐diphenoquinone (II). Infrared (IR), nuclear magnetic resonance (NMR), and gel permeation chromotography (GPC) measurements indicate that the quinone is bound covalently…

Conducting polymers and applicationsPorphyrin and Phthalocyanine ChemistryOxidative Organic Chemistry Reactions

Constitutive Equations of Elastoplastic Materials With Anisotropic Hardening and Elastic-Plastic Transition

Koichi Hashiguchi1981-06-01Journal of Applied Mechanics

Constitutive equations of elastoplastic materials with anisotropic hardening and elastic-plastic transition are presented by introducing three similar surfaces, i.e., a loading surface on which a current stress exists, a subyield surface limiting a size of the loading surface and a distinct-yield surface representing…

Metal Forming Simulation TechniquesElasticity and Material ModelingHigh-Velocity Impact and Material Behavior

Detection of surface and bulk traps

Heinz von Seggern1981-06-01Journal of Applied Physics

A method for determining the geometrical surface trap structure of highly insulating polymer films is presented. We compare ’’open-circuit’’ thermally-stimulated current measurements of corona and electron-beam-charged foils. We present the results for three different polymers: polyfluoroethylenepropylene [Teflon (FEP…

High voltage insulation and dielectric phenomenaPower Transformer Diagnostics and InsulationElectron and X-Ray Spectroscopy Techniques

Spatial aspects of electron energy degradation in atomic oxygen

R. P. Singhal、A. E. S. Green1981-06-01Journal of Geophysical Research Atmospheres

Spatial (radial and longitudinal) yield spectra for electron energy degradation in atomic oxygen have been obtained using a Monte Carlo method for 25 eV to 10 keV incident electrons. Four‐dimensional yield spectra have been analytically represented in terms of a model containing three simple microplumes. We find that…

Catalytic Processes in Materials ScienceCatalysis and Oxidation ReactionsElectron and X-Ray Spectroscopy Techniques

Plasma etching durability of poly(methyl methacrylate)

Katsuhiro Harada1981-06-01Journal of Applied Polymer Science

Abstract The decomposition of poly(methyl methacrylate) (PMMA), as a positive resist, in CF 4 /O 2 plasma etching has been studied in the thin film state in order to clarify the factors influencing the dry etching durability of resists. It becomes clear that the major PMMA decomposition in CF 4 /O 2 plasma etching pro…

Metal and Thin Film MechanicsSemiconductor materials and devicesCopper Interconnects and Reliability

Deformation and Structural Re-formation of Lyotropic Cholesteric Liquid Crystal of Hydroxypropyl Cellulose + Water System

T. Asada、Kentaro Toda、S. Onogi1981-06-01Molecular crystals and liquid crystals

Flow properties and optical properties in applying and stopping shear on a lyotropic cholesteric liquid crystalline system of concentrated aqueous solutions of hydroxypropyl cellulose have been studied. The wave length dependence of transmitted light intensity through a sample subjected to steady shear have been measu…

Liquid Crystal Research AdvancementsSurfactants and Colloidal SystemsNonlinear Dynamics and Pattern Formation

Probable burial diagenetic and provenance effects on Dakota Group clay mineralogy, Denver Basin

Robert C. Rettke1981-06-01Journal of Sedimentary Research

Abstract Illite-smectites in cored Dakota Group (Cretaceous) shales and bentonites of the northern Denver Basin, identified using a modification of Reynolds' and Hower's (1970) X-ray diffraction criteria, show decreasing sample-sample expandability ranges, lower modal expandability, and a change from random to ordered…

Geological and Geochemical AnalysisClay minerals and soil interactionsGeological and Geophysical Studies Worldwide

Evidence for Quasilocalized5fElectronic States inUSbxTe1−x

B. Reihl、N. Mårtensson、P. Heimann 等 5 位作者1981-06-01Physical Review Letters

We have studied the "$5f$, $6d$" electron states of the system $\mathrm{U}{\mathrm{Sb}}_{x}{\mathrm{Te}}_{1\ensuremath{-}x}$ (100) using photoemission spectroscopy with synchrotron radiation. In contrast with the generally accepted picture of uranium chalcogenides and pnictides, we find for UTe that the main $5f$ leve…

Rare-earth and actinide compoundsIron-based superconductors researchInorganic Chemistry and Materials

Significance of cell-to-cell contacts for the directional movement of neural crest cells within a hydrated collagen lattice

Edward M. Davis、John Philip Trinkaus1981-06-01Development

Neural tubes whose neural crest had just begun migration were isolated from stage-14 chick embryos, cleaned with 0.1% trypsin, and cultured in transparent hydrated collagen lattices (HCL) in an effect to stimulate in part the three-dimensional environment through which neural crest cells migrate in situ, in the embryo…

Developmental Biology and Gene RegulationConnective tissue disorders researchCollagen: Extraction and Characterization

The permethylcyclosilanes (Me2Si)5 through (Me2Si)35

Lawrence F. Brough、Robert West1981-06-01Journal of the American Chemical Society

ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTThe permethylcyclosilanes (Me2Si)5 through (Me2Si)35Lawrence F. Brough and Robert WestCite this: J. Am. Chem. Soc. 1981, 103, 11, 3049–3056Publication Date (Print):June 1, 1981Publication History Published online1 May 2002Published inissue 1 June 1981https://doi.org/10.1021/…

Mesoporous Materials and CatalysisSynthesis and characterization of novel inorganic/organometallic compoundsInorganic and Organometallic Chemistry

Reactivity of the [(.eta.5-C5H5)Ti(Mo5O18)]3- anion: synthesis and structure of MoO2Cl+ and Mn(CO)3+ adducts

Victor W. Day、M. F. FREDRICH、Michael R. Thompson 等 6 位作者1981-06-01Journal of the American Chemical Society

ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTReactivity of the [(.eta.5-C5H5)Ti(Mo5O18)]3- anion: synthesis and structure of MoO2Cl+ and Mn(CO)3+ adductsV. W. Day, M. F. Fredrich, M. R. Thompson, W. G. Klemperer, R. S. Liu, and W. ShumCite this: J. Am. Chem. Soc. 1981, 103, 12, 3597–3599Publication Date (Print):June 1,…

Metal-Organic Frameworks: Synthesis and ApplicationsPolyoxometalates: Synthesis and ApplicationsInorganic Chemistry and Materials

Model networks of end‐linked polydimethylsiloxane chains. XII. Dependence of ultimate properties on dangling‐chain irregularities

Anthony L. Andrady、M. A. Llorente、M. A. Sharaf 等 8 位作者1981-06-01Journal of Applied Polymer Science

Abstract Elastomeric networks were prepared by end‐linking vinyl‐terminated polydimethylsiloxane (PDMS) chains having number‐average molecular weights of 11.3 × 10 3 g mol −1 . The tetra‐functional end‐linking agent, Si[OSi(CH 3 ) 2 H] 4 , was used in varying amounts smaller than that corresponding to a stoichiometric…

Corrosion Behavior and InhibitionPolymer Nanocomposites and PropertiesPolymer composites and self-healing

The Reflectivity of a Liquid Crystal Cell in a Surface Plasmon Experiment

G. J. Sprokel1981-06-01Molecular crystals and liquid crystals

This paper provides the mathematical background on which the previous paper entitled: Determination of the Surface Tilt Angle by ATR, is based. The algebra was considered too lengthy to be incorporated as an appendix to that paper.

Liquid Crystal Research AdvancementsPhotonic Crystals and ApplicationsOptical Coatings and Gratings

An occurrence of interstratified kaolinite-smectite minerals in a red-black soil toposequence

A. J. Herbillon、R. Frankart、L. Vielvoye1981-06-01Clay Minerals

Abstract Interstratified kaolinite-smectite minerals form the major part of a pedon transitional between ‘red’ kaolinitic and black smectitic soils in a soil toposequence derived from basalt in Burundi, Central Africa. These interstratified kaolinite-smectites have many X-ray, morphological and chemical features in co…

Clay minerals and soil interactionsIron oxide chemistry and applicationsTherapeutic Uses of Natural Elements

A monohydroxobridged, strongly antiferromagnetically coupled dicopper(II) center in a binucleating macrocycle. Comparisons with binuclear copper sites in biology

Peter K. Coughlin、Stephen J. Lippard1981-06-01Journal of the American Chemical Society

ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTA monohydroxobridged, strongly antiferromagnetically coupled dicopper(II) center in a binucleating macrocycle. Comparisons with binuclear copper sites in biologyPeter K. Coughlin and Stephen J. LippardCite this: J. Am. Chem. Soc. 1981, 103, 11, 3228–3229Publication Date (Pri…

Metal complexes synthesis and propertiesMagnetism in coordination complexesMetal-Catalyzed Oxygenation Mechanisms

Comparison of profile and integrated-intensity methods in powder refinement

E. Prince1981-06-01Journal of Applied Crystallography

If a powder pattern consists of well resolved peaks, and if it is adequately described by a crystallographic model, as determined by statistical tests, the estimates of the parameters and their standard deviations will not be significantly different, in a statistical sense, whether the method of refinement uses peak p…

Crystallization and Solubility StudiesThermal and Kinetic AnalysisX-ray Diffraction in Crystallography

Oxygen Diffusion in Magnesium Aluminate Spinel

Kasala Prabhakar Reddy、Alexandre Cooper1981-06-01Journal of the American Ceramic Society

Oxygen self‐diffusion in MgAl 2 O 4 single crystals was investigated by annealing the samples in 18 O enriched gas at 98 kPa (1 atm) and measuring the tracer concentration profiles using a proton activation technique. The diffusion coefficients in the range 1625 to 1925 K for stoichiometric crystals are represented by…

Glass properties and applicationsMicrowave Dielectric Ceramics SynthesisNuclear materials and radiation effects