Materials Literature
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In this Letter, we calculate the density of states of graphene under a highly uniform magnetic field and white-noise random potential. We discover that the disorder-broadened zero-energy Landau band has a Gaussian shape and its width is proportional to the random potential variance and the square root of magnetic fiel…
A method to determine the thickness of a nonabsorbing thin film on an absorbing substrate is presented. A linear relation between the thin-film thickness and the tangent wavelength of the reflectance spectrum for a specific interference order is revealed, which permits the calculation of the thickness provided that th…
This paper reports the accurate measurement of the ReO 3 cell parameter as a function of temperature. The thermal expansion is confirmed to be negative over most of the temperature range from 5 to 300 K. The main problems with the measurements are the very small variations (in the range of 10 −5 Å) in the cell paramet…
Abstract A comparative study of ethylene vinyl acetate nanocomposites based on expanded graphite, multiwalled carbon nanotubes, and carbon nanofibers has been carried out to investigate the effect of different carbon nanofillers on the electrical properties of the corresponding composites. The composites were prepared…
A tetragonal perovskite PbMnO(3) was obtained by treating the 6H hexagonal perovskite phase at 15 GPa and 1273 K. Structural analysis using synchrotron X-ray diffraction suggested that PbMnO(3) crystallizes in the centrosymmetric space group P4/mmm, unlike PbTiO(3) and PbVO(3) which have a polar structure in space gro…
Manganese(II/III) complexes of a phenol-based tetradentate ligand L(2-) [H(2)L = N,N'-dimethyl-N,N'-bis(2-hydroxy-3,5-dimethylbenzyl)-ethylenediamine], namely, [Mn(4)(L)(2)(PhCOO)(6)] (1), [Mn(3)(L)(2)(CH(3)CH(2)COO)(2)(OMe)(2)].H(2)O (2), and [Mn(L){(CH(3))(3)CCOO}(CH(3)OH)].CH(3)OH (3), have been synthesized. The ba…
Abstract Two valencies instead of one! Stoichiometric valence and structural valence are two distinct properties of atoms. The former, stoich V , is derived from the composition of a compound and has integer values; the latter, struct V , depends on the structure of a compound and has non‐integer values. The scheme sh…
Control yourself! The mesoporous silica nanofibers (MSNFs) from dual structure-directing agents were fabricated inside the pores of porous alumina (AAO, see figure) by using vapor phase synthesis. The pore structures could be controlled to form a range of structures from mesocellular foams to cylindrical mesopores wit…
We report the results of a fast thermal desorption spectroscopy study of the H/D isotopic exchange kinetics in a few micrometer thick, pure polycrystalline ice film and in ice films doped with HCl. Using the isotopic exchange reaction as a probe of transport processes in ice, we determined the effective H/D interdiffu…
A pH-insensitive fluorophore is made to give pH-driven responses through its covalent incorporation within a nanostructure derived from pH-responsive polymers. Fluorophore-shell-crosslinked nanoparticles (SCKs) demonstrate notable enhancement of photophysical properties, in the physiological pH region. Fluorophore-SCK…
Whether adsorbates might effectively lower the ionization potential (IP) of open-ended boron nitride nanotubes (BNNTs) in order to design BNNTs based on flat-panel display devices is an unanswered question. In the present work, through density functional theory (DFT) calculations we present the first attempt on the ef…
Abstract Preparation of E‐glass/waterborne epoxy prepregs containing natural nanoclay and properties of their composites are presented. Prepregs were prepared by wetting randomly oriented, chopped glass fiber preforms with aqueous dispersion of EpiRez 3522‐W‐60 resin, dicyandiamide, 2‐methylimidazole and natural nanoc…
Abstract In order to prevent the properties, especially transparency, color and health security, of PET/clay nanocomposites from being deteriorated due to the thermal degradation of clay organo‐modifer, we had directly modified sodium montmorillonite (Na + ‐MMT) with PET's monomer, bis (hydroxyethyl) terephthalate (BH…
In this study the bio-degradation behavior of a Mg-Y-RE alloy in different heat treatment states with respect to the alloy's potential application as biodegradable implant material was investigated by electrochemical impedance spectroscopy in two body-similar fluids. The heat treatments increase the degradation resist…
Selected compositions of the Ba–Sr–Co–Fe–O system were synthesized from powders by the solid-state reaction method. Samples were equilibrated at 1273 K for 36 000 s in air. The resulting powders were characterized by X-ray diffraction (XRD) at room temperature and by high-temperature in situ XRD. The phases present in…
We report a new available strategy for fabricating 2-dimensional petal-like CdS/dodecylamine (DDA) hybrids with enhanced photoluminescence (PL) by using a method of oil/water interfacial self-assembly. First, water-soluble CdS nanocrystals (NCs) were controllably prepared at the two-phase interface by injecting the Na…
We studied the structural properties of (Ge+SiO2)/SiO2 multilayer films, especially the influence of the deposition temperature and the parameters of subsequent annealing on the formation and spatial correlation of Ge quantum dots in an amorphous silica matrix. We showed that in-layer and inter-layer spatial correlati…
Abstract In this investigation, expandable graphite was functionalized using a coupling agent to produce covalent bonds between the organic and inorganic phases, enhancing the thermal stability of the composites. The modified expandable graphite had an OEt function group that reacted with methyl methacrylate‐ co ‐3‐(…
In this paper, the synthesized surfactant of copper dodecyl sulfate (Cu(DS)2) was used as a special metal-ion source for the morphological control of copper oxide (CuO) architectures. During the fabrication processes, the ribbon-shaped intermediates of basic copper salt with lamellar structures were observed at 60.0 d…
The cyclodextrin (CD) molecule, a host for a variety of smaller molecular guests, and hyperbranched polymers both possess molecule cavities in their molecular architectures. If the hyperbranched poly(β - cyclodextrin)s are established using modified β-CD molecules as monomers, their molecular inclusion capabilities fo…