Materials Literature
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The pse udobinary sys tems Ti02-1rO, and Sn02-lr02 we re studied by x-ray diffraction after treatm e nt at vari ous te mpe ratures in air. Their equilibrium ph ase di agrams we re similar, with no int erm edi ate phases detec ted in eithe r sys tem. Max imum so lid so lution of Ti02 occ urs with th e additi on of abou…
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTStereochemistry of Asymmetric Silicon. Stereospecific Platinum-Catalyzed Hydrosilation of 1-Octene with Optically Active R3Si*HLeo H. Sommer, Keith W. Michael, and Hiroshi. FujimotoCite this: J. Am. Chem. Soc. 1967, 89, 6, 1519–1521Publication Date (Print):March 1, 1967Publi…
Neutron diffraction data of NiCl2·6H2O have been taken at 1.5° and 4.2°K on the (h0l) zone. The magnetic reflections observed at both temperatures indicate that the magnetic structure consists of antiferromagnetic (001) planes, with an antiferromagnetic coupling between planes, to give a magnetic cell with cm = 2c. Us…
Summary Garnets undergo readjustment of ion-assemblages under external mechanical and thermal stresses; this adjustment favours those paths that annul the very cause to which it is due. Metal ions in garnets being replaceable, with rising metamorphism garnets become reluctant to accommodate ions of larger ionic radii.…
Fine‐grained glass‐ceramics containing a large proportion of β‐spodumene solid‐solution crystals were strengthened by immersion in molten sodium and potassium salt baths. An ion‐exchange reaction placed sodium or potassium ions in lithium ion sites in the β‐spodumene structure. The resultant “crowding” of the structur…
Direct x-ray measurements during deformation are compared with single slip and double slip calculations for rotations beyond the symmetry line. Both a literature survey of 152 face-centred cubic tests since 1923 and the present studv of 16 aluminium tests reveal that the use of the automatic double slip calculation fo…
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTRelations connecting molecular properties and electron and x-ray diffraction intensitiesRussell A. BonhamCite this: J. Phys. Chem. 1967, 71, 4, 856–862Publication Date (Print):March 1, 1967Publication History Published online1 May 2002Published inissue 1 March 1967https://pu…
Abstract Synthetic Fe 3 S 4 is cubic, a 0 = 9.90 Å, space group Fd3m, Z = 8. The parameter u of sulfur positions in 32e site is estimated as 3/8, i. e. it has an ideal structure. Fe 3 S 4 was decomposed to tetragonal or hexagonal FeS and free S at below or above 190 °C under hydrothermal conditions. The transition bet…
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTCrystal and molecular structure of yttrium acetylacetonate trihydrateJames A. Cunningham, Donald E. Sands, and William Frederick WagnerCite this: Inorg. Chem. 1967, 6, 3, 499–503Publication Date (Print):March 1, 1967Publication History Published online1 May 2002Published ini…
The light rare-earth dicarbides, CeC2, PrC2, and NdC2, having the tetragonal CaC2-type structure, have been shown by neutron diffraction to become a body-centered first-kind antiferromagnet with the Néel temperatures of 33°, 15°, and 29°K and with the ordered moments being 81%, 44%, and 90% of the free-ion values, res…
The magnetic properties of FexO with long-range order of defects was studied. The crystal structure appears to consist of periodically spaced complexes of vacant octahedral and occupied tetrahedral sites, with most of the octahedral ions in an ideal NaCl-type environment. The Néel temperature, determined from measurem…
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTSpecific heats of nematic, smectic, and cholesteric liquid crystals by differential scanning calorimetryEdward M. Barrall II, Roger Stephen Porter, and Julian Frank JohnsonCite this: J. Phys. Chem. 1967, 71, 4, 895–900Publication Date (Print):March 1, 1967Publication History…
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTChemistry of epoxy compounds. XX. Stereospecific syntheses of cis- and trans-1,2-diaminocyclohexanes and aliphatic vicinal diaminesGraham Swift and Daniel SwernCite this: J. Org. Chem. 1967, 32, 3, 511–517Publication Date (Print):March 1, 1967Publication History Published on…
Microscopic observation of the domain structure in polycrystalline BaTiO 3 is carried out. After the specimen is cooled down to room temperature through the Curie point the domain structure changes gradually from an initial irregular one to a final one consisting of fine stripes of 90°-domains. Such a change is named…
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTInfrared investigation of the adsorption and surface reactions of the C1 through C4 normal alcohols on γ -aluminaRonald O. KagelCite this: J. Phys. Chem. 1967, 71, 4, 844–850Publication Date (Print):March 1, 1967Publication History Published online1 May 2002Published inissue…
Two types of methods have been previously used to relate the macroscopic decay of polarization in a dielectric specimen to a microscopic decay function defined in terms of molecular motions. The first is based on Kubo's theory of non-equilibrium statistical mechanics combined with Kirkwood's theory. The second is base…
A calculation is presented which describes the splitting of doubly degenerate electronic states of tetragonal and trigonal centres in cubic crystals by an applied uniaxial stress. It is shown that the shift and splitting of the states may be expressed in both cases in terms of four independent parameters. The approach…
Imperfection sensitivity of eccentrically axial and ring stiffened cylinderal shells under axial compression and hydrostatic pressure
Abstract Poly (vinyl chloride) (PVC) holds a major position in the consumption of thermoplastics. In the United Kingdom, from humble beginnings, 500 tons in 1941, production has increased rapidly through the last ten years to the 200,000 ton mark in 1966 and now accounts for 30 per cent of the total thermoplastics. Th…
The thermal decomposition process of zirconium sulphate tetrahydrate has been studied. Dehydration, which takes place via a crystalline monohydrate phase, is accompanied by the loss of small amounts of sulphuric acid apparently resulting from internal hydrolysis of the compound. This process gives a non-stoicheiometri…