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ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTPhotoluminescence and photoinduced oxygen adsorption of colloidal zinc sulfide dispersionsWilliam G. Becker and Allen J. BardCite this: J. Phys. Chem. 1983, 87, 24, 4888–4893Publication Date (Print):November 1, 1983Publication History Published online1 May 2002Published inis…
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTSilafunctional compounds in organic synthesis. Part 20. Hydrogen peroxide oxidation of the silicon-carbon bond in organoalkoxysilanesKohei Tamao, Neyoshi Ishida, Tatsu Tanaka, and Makoto KumadaCite this: Organometallics 1983, 2, 11, 1694–1696Publication Date (Print):November…
The fundamental equation of electrostatics, i.e. the integral equation for the polarization of a macroscopic dielectric in an arbitrary external field, is written in a form that allows explicit inclusion of the toroidal boundary conditions as well as the cutoff of dipolar interactions often used in the computer simula…
This paper surveys experimental results concerned with secondary electron emission of surfaces bombarded by primary electrons with respect to scanning electron microscopy. The energy distribution, the angular distribution, and the yield of secondary electrons from metals and insulators are reviewed as well as the esca…
<div class="htmlview paragraph">A combustion engine of a given displacement will develop less power when running on hydrogen compared to gasoline or natural gas operation due to less heating value of the fuel air mixture in the combustion chamber. This drop in output exists for external mixing of hydrogen and ai…
It is pointed out that the stress relaxation time that determines viscosity is partly controlled by the viscosity itself via diffusional structural relaxation. This feedback may make the viscosity of a simple liquid without localised defects diverge at some finite temperature. The feedback is mediated by atomic-scale-…
The nature of the carbon deposits formed on an alumina-supported nickel catalyst have been characterized by their reactivity with H 2 and H 2 O during temperature-programmed surface reaction (TPSR). Carbon deposits formed by exposure to hydrocarbons and carbon monoxide exhibit, depending primarily on the temperature d…
By an alkaline alcoholic hydrolysis, the thyroid proteins are broken into many simpler constituents. These may be separated into two groups: the acid insoluble compounds are designated Group A; those acid soluble, Group B. From Group A a pure crystalline compound, containing 60 per cent of iodin, has been isolated. It…
A cluster expansion of an order parameter distribution function is introduced into the recent theory of crystallization of classical fluids. This allows us to demonstrate the purely geometric origin of the empirical Hansen-Verlet rule of crystallization (max. S(k) ⋍ 2·85 or c(k ⋍ 0·65 with S(k) = (1 - c(k)-1). Using m…
The authors show that phason- and amplitudon-like vibrations can be obtained in one-dimensional incommensurate systems with harmonic interactions between first neighbours only. This is achieved provided a realistic modulation of the force constants is used. The incommensurate systems are approximated by commensurate o…
Strong evidence for the formation of a bound magnetic polaron in $n$-${\mathrm{Cd}}_{0.90}$${\mathrm{Mn}}_{0.10}$Se has been obtained from time-resolved experiments by picosecond laser spectroscopy. In particular, time-varying Stokes shifts associated with a neutral donor bound exciton have been measured to follow the…
The anisotropy of thermal expansion of ZnSiP2, is investigated within 20 to 300 K. For the stronger SiP bond a smaller expansion coefficient and a higher temperature of transition to negative thermal expansion is found than for the weaker ZnP bond. Therefore, similar relations exist between the expansion coefficient…
A simple, thermodynamic model of intercalated graphite which allows for variation of in-plane intercalant density, and takes explicit account of volume variation, is presented. Assuming random occupation of intercalant atoms pressure-temperature-concentration phase diagrams are calculated. The model is capable of expl…
Effects of the lattice dispersion upon anharmonic decay of near-zone-boundary LA phonons in Ge are studied by making reference to the two-phonon density of states in the [100] and [111] directions. As the wave vector approaches Brillouin-zone boundaries, the two-phonon density of states increases more rapidly than ${\…
Using water-in-oil emulsion samples to avoid, for the most part, heterogeneous nucleation, the crystallization of ice from a series of aqueous LiCl solutions has been studied isothermally, using differential calorimetry to monitor the process through the release of the heat of crystallization. The classical form of th…
An x-ray photoemission spectrum of a newly found allotrope of solid selenium, rhombohedral Se containing only ${\mathrm{Se}}_{6}$ ring molecules, has been presented, and compared with those of monoclinic, trigonal, and amorphous forms. The most remarkable points in the density of states of rhombohedral Se are (1) the…
The static and dynamic behavior of the Frederiks transition for twist of a uniform planar nematic sample in an external magnetic field has been studied by monitoring the associated conoscopic figure. In particular, the decay of this figure after the field has been switched off is considered in detail in order to obtai…
We report the polarized Raman spectra of vitreous Ge $^{16}\mathrm{O}_{2}$, Ge $^{18}\mathrm{O}_{2}$, $^{70}\mathrm{Ge}$${\mathrm{O}}_{2}$, and $^{74}\mathrm{Ge}$${\mathrm{O}}_{2}$. This yields the $^{16}\mathrm{O}$\ensuremath{\rightarrow}$^{18}\mathrm{O}$ and $^{70}\mathrm{Ge}$\ensuremath{\rightarrow}$^{74}\mathrm{Ge…
The electronic structures of sodium metasilicate (${\mathrm{Na}}_{2}$Si${\mathrm{O}}_{3}$) and the $\ensuremath{\alpha}$ and $\ensuremath{\beta}$ phases of sodium disilicate (${\mathrm{Na}}_{2}$${\mathrm{Si}}_{2}$${\mathrm{O}}_{5}$) are calculated from first principles by the method of linear combination of atomic orb…
We have measured and interpreted the Raman spectra of bulk $\mathrm{Ge}{({\mathrm{S}}_{x}{\mathrm{Se}}_{1\ensuremath{-}x})}_{2}$ glasses for compositions in the range $0\ensuremath{\le}x\ensuremath{\le}0.25$, both at low power levels and at sufficiently high power levels to induce thermally reversible (at $T\ensuremat…