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Molecular Orientational Structures in Ferroelectric, Ferrielectric and Antiferroelectric Smectic Liquid Crystal Phases as Studied by Conoscope Observation

Ewa Górecka、A. D. L. Chandani、Yukio Ouchi 等 5 位作者1990-01-01Japanese Journal of Applied Physics

Molecular orientational structures in MHPOBC were studied by means of conoscope observation. Contrary to a ferroelectric response of the conoscope to an electric field in the smectic C * phase, the conoscopic figure in the antiferroelectric smectic C A * phase does not shift its center and is biaxial with its optic pl…

Liquid Crystal Research AdvancementsSurfactants and Colloidal SystemsMolecular spectroscopy and chirality

Structure and Electrical Properties of Polyacetylene Yielding a Conductivity of 105 S/cm

Jun Tsukamoto、Akio Takahashi、Kikuko Kawasaki1990-01-01Japanese Journal of Applied Physics

We have prepared polyacetylene (ν-(CH) x ) yielding a conductivity of more than 10 5 S/cm, by making some modifications on Naarmann et al.'s method. Structural analyses of this polymer were carried out by use of various analysis techniques such as SEM, IR and resonance Raman spectroscopy to characterize ν-(CH) x . No…

Fuel Cells and Related MaterialsConducting polymers and applicationsPolydiacetylene-based materials and applications

Synthesis and chemistry of acyl silanes

Philip C. Bulman Page、Sukhbinder S. Klair、S.E. Rosenthal1990-01-01Chemical Society Reviews

P. C. B. Page, S. S. Klair and S. Rosenthal, Chem. Soc. Rev., 1990, 19, 147 DOI: 10.1039/CS9901900147

biodegradable polymer synthesis and propertiesSynthetic Organic Chemistry MethodsCarbon dioxide utilization in catalysis

Morphology development of polymeric microparticles in aqueous dispersions. I. Thermodynamic considerations

Donald C. Sundberg、Anthony P. Casassa、John Pantazopoulos 等 6 位作者1990-01-01Journal of Applied Polymer Science

Abstract A thermodynamic analysis of polymer particle morphology highlights the role of interfacial tensions in controlling particle structure. The influence of the surfactant and the nature of the incompatible polymers is seen through their individual and collective effects upon these interfacial tensions. It has bee…

Advanced Polymer Synthesis and CharacterizationSurfactants and Colloidal SystemsPickering emulsions and particle stabilization

Consistent porphyrin force field. 2. Nickel octaethylporphyrin skeletal and substituent mode assignments from nitrogen-15, meso-d4, and methylene-d16 Raman and infrared isotope shifts

Xiao Yuan Li、Roman S. Czernuszewicz、James R. Kincaid 等 5 位作者1990-01-01The Journal of Physical Chemistry

Resonance Raman spectra with variable-wavelength excitation are reported for nickel octaethylporphyrin and its isotopomers containing <sup>15</sup>N, and <sup>2</sup>H at the methine (meso-d<sub>4</sub>) and methylene (methylene-d<sub>16</sub>) carbon atoms. The <sup>15</sup>N, meso-d<sub>4</sub> double isotopomer is…

Porphyrin and Phthalocyanine ChemistryMolecular Junctions and NanostructuresSpectroscopy and Quantum Chemical Studies

Consistent porphyrin force field. 1. Normal-mode analysis for nickel porphine and nickel tetraphenylporphine from resonance Raman and infrared spectra and isotope shifts

Xiao Yuan Li、Roman S. Czernuszewicz、James R. Kincaid 等 5 位作者1990-01-01The Journal of Physical Chemistry

Resonance Raman spectra with variable-wavelength excitation are reported for Ni<sup>II</sup> porphine (NiP) and for the pyrrole-d<sub>8</sub>, meso-d<sub>4</sub>, and (pyrrole + meso)-d<sub>12</sub> isotopomers, as well as for Ni<sup>II</sup> meso-tetraphenylporphine (NiTPP) and its pyrrole-<sup>15</sup>N<sub>4</sub>,…

Porphyrin and Phthalocyanine ChemistryPhotochemistry and Electron Transfer StudiesSpectroscopy and Quantum Chemical Studies

Hydrogen effects on material behavior

N. R. Moody、A.W. Thompson1990-01-01OSTI OAI (U.S. Department of Energy Office of Scientific and Technical Information)

This book contains the proceedings of the Fourth International Conference on the Effect of Hydrogen on the Behavior of Metals. Included are the following papers: The influence of microstructure on hydrogen transport in nickel-base alloys, Hydrogen uptake during cadmium electroplating, Hydrogen, embrittlement in lean u…

Hydrogen embrittlement and corrosion behaviors in metalsNon-Destructive Testing Techniques

Cluster-model calculation of the electronic structure of CuO: A model material for the high-Tcsuperconductors

Henk Eskes、L. H. Tjeng、G. A. Sawatzky1990-01-01Physical review. B, Condensed matter

In this paper we describe the details of several model Hamiltonian cluster calculations, suitable for describing various spectroscopic data of CuO. By treating the d-d Coulomb and exchange interactions within the full atomic multiplet theory and using symmetry-dependent Cu-O hybridizations, we do a detailed comparison…

Physics of Superconductivity and MagnetismZnO doping and propertiesCopper-based nanomaterials and applications

Electrochemical, electrochromic, and conductive properties of poly(N-alkyldiphenylamine) polymers

My T. Nguyên、Lê H. Dao1990-01-01Journal of the Chemical Society Chemical Communications

Chemically prepared poly(N-alkyldiphenylamine) polymers are conductive and electrochemically reversibly dopable in organic and aqueous solutions; cast polymer films exhibit multiple, reversible colour changes in 1 M LiCLO4 in acetonitrile or 1 M HClO4 aqueous under potential cycling between 0.0 and 1.0 vs. Ag/AgCl or…

Conducting polymers and applicationsElectrochemical Analysis and ApplicationsAnalytical Chemistry and Sensors

Transcriptional stimulationviaSC site ofBombyxsericin-1 gene through an interaction with a DNA binding protein SGF-3

Kenji Matsuno、Shigeharu Takiya、Chi‐chung Hui 等 7 位作者1990-01-01Nucleic Acids Research

Three protein binding sites have been identified in the upstream region of the sericin-1 gene. Two of them, SA and SC sites, have been known as putative cis-acting elements. Using synthetic oligonucleotides of these binding sites, it was found that silk gland factor-1 (SGF-1) binds to the SA site, and silk gland facto…

Neurobiology and Insect Physiology ResearchPlant Reproductive BiologySilk-based biomaterials and applications

Epitaxial growth of transition metal dichalcogenides on cleaved faces of mica

Keiji Ueno、Koichiro Saiki、Toshihiro Shimada 等 4 位作者1990-01-01Journal of Vacuum Science & Technology A Vacuum Surfaces and Films

We have grown ultrathin films of layered transition metal dichalcogenides (MoSe2,NbSe2) heteroepitaxially on cleaved faces of mica (muscovite). This is the first success in the heteroepitaxial growth between highly heterogeneous layered materials having different crystal structures and lattice constants that differ by…

Graphene research and applications2D Materials and ApplicationsChemical and Physical Properties of Materials

Dependence of the Line Strength of f–f Transitions on the Manifold Energy. II. Analysis of Pr3+ in KPrP4O12

А. А. Корниенко、А. А. Каминский、Е. Б. Дунина1990-01-01physica status solidi (b)

Abstract To describe the experimental data of the line strength and the oscillator strength of electric dipole transition between manifolds a formula is suggested that takes into account the dependence on the energy of manifolds and the effect of electron correlation. It contains four phenomenological parameters and i…

Luminescence Properties of Advanced MaterialsGlass properties and applicationsQuantum optics and atomic interactions

Modification of solidification structures by pulse electric discharging.

Masayuki Nakada、Yuh Shiohara、M. C. Flemings1990-01-01ISIJ International

A new process using pulse electric discharging for modification of solidification structures was investigated. If an extremely high voltage or high current is applied to solidifying metallic alloys by discharging a capacitor bank, large pressure gradients result, which produce strong local shear, and can be expected t…

Aluminum Alloy Microstructure PropertiesSolidification and crystal growth phenomenaMetallurgical and Alloy Processes

A coherent model for the complex permeability in polycrystalline ferrites

M.T. Johnson、Eelco Visser1990-01-01IEEE Transactions on Magnetics

It is demonstrated that a grain size dependence exists for the rotational permeability of a series of MnZn polycrystalline ferrites, analogous to that predicted by the Globus model for wall permeability. To account for this behavior, a model has been developed which considers crystalline ferrite grains with intrinsic…

Metallic Glasses and Amorphous AlloysMagnetic Properties and Synthesis of FerritesElectromagnetic wave absorption materials

Topics in electronic ceramics

Scott Swartz1990-01-01IEEE Transactions on Electrical Insulation

Four topics in the field of electronic ceramics are reviewed: multilayer ceramic capacitors, piezoelectric ceramics, electrooptic ceramics, and ferroelectric thin films. They all are related to ferroelectric ceramic materials. The scope of this review is limited to oxide compounds, because oxide ferroelectrics, for th…

Ferroelectric and Piezoelectric MaterialsAcoustic Wave Resonator TechnologiesMicrowave Dielectric Ceramics Synthesis

Compendium of neutron spectra and detector responses for radiation protection purposes

R. V. Griffith、J. Pálfalvi、U. Madhvanath1990-01-01International Atomic Energy Agency eBooks

This compendium includes a collection of the neutron spectra encountered in various occupational environments and the spectra of calibration neutron sources. It furthermore comprises the response functions of various neutron dosemeters and survey instruments. Finally, it includes the calculated energy responses for ea…

Nuclear Physics and ApplicationsGraphite, nuclear technology, radiation studies

Bronze Disease: A Review of Some Chemical Problems and the Role of Relative Humidity

David Scott1990-01-01Journal of the American Institute for Conservation

A general review of some of the theories proposed to account for the process of “bronze disease” is presented from both the historical and chemical points of view. The corrosion product of most serious concern, cuprous chloride, and its inter-relationship with some of the other important corrosion products of copper a…

Corrosion Behavior and InhibitionHydrogen embrittlement and corrosion behaviors in metalsCultural Heritage Materials Analysis

Primary Bjerknes forces

T.G. Leighton、Alan J. Walton、M J W Pickworth1990-01-01European Journal of Physics

When a bubble in a liquid is subjected to a periodic sound field, the resulting bubble oscillations can interact with the sound field, giving rise to the primary Bjerknes force. A simple undergraduate-level derivation, and a graphical illustration of the underlying processes, are given.

Microfluidic and Bio-sensing TechnologiesUltrasound and Cavitation PhenomenaElectrohydrodynamics and Fluid Dynamics

High-frequency measurement techniques for magnetic cores

V.J. Thottuvelil、Thomas G. Wilson、H. A. Owen1990-01-01IEEE Transactions on Power Electronics

Conventional techniques and new techniques based on digitizing instruments for making high-frequency B-versus-H loop and core-loss measurements on magnetic cores are presented and compared. Potential sources of measurement errors and their magnitudes, limitations imposed by the instrumentation, and thermal considerati…

Magnetic Properties and ApplicationsAdvanced Electrical Measurement TechniquesMagnetic Field Sensors Techniques