Materials Literature
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Recently N. Garcia et al. (Phys. Rev. E 67, 046606 (2003)) theoretically studied several acoustic devices with dimensions on de order of several wavelenghts. The authors discussed on experimental results previously reported by several of us (F. Cervera et al., Phys. Rev. Lett. 88, 023902 (2002)). They concluded that d…
The anomalous Hall effect (AHE) of ferromagnetic thin films of Sr$_{1-x}$Ca$_{x}$RuO$_3$ (0 $\leq x \leq$ 0.4) is studied as a function of $x$ and temperature $T$. As $x$ increases, both the transition temperature $T_c$ and the magnetization $M$ are reduced and vanish near $x \sim$ 0.7. For all compositions, the trans…
Molecular-dynamics simulations have been used to compute thermodynamic and kinetic properties of the solid-liquid interface for both the fcc and bcc phases of Fe. Pure Fe was modeled using two different interatomic potentials of the embedded atom type as well as an effective pair potential. Free solidification simulat…
We report a detailed numerical investigation of a recently introduced two dimensional model for square-to-rectangle martensitic transformation that explains several unusual features of the martensitic transformation. This model includes inertial effects, dissipation, long-range interaction between the transformed doma…
Wound healing is a complex process that often requires treatment with antibiotics. This article reports the initial development of a biodegradable polymeric nanofiber-based antibiotic delivery system. The functions of such a system would be (a) to serve as a biodegradable gauze, and (b) to serve as an antibiotic deliv…
The thermodynamic behavior, the morphology, and the molecular structure of systems prepared from exposure to liquid solvent ( cis- and trans -decalin) of solid isotactic polystyrene samples at different temperatures (4−40 °C) are reported. No significant differences are detected when comparison is made with solution-c…
3-Keto-L-gulonate 6-phosphate decarboxylase (KGPDC), a member of the orotidine monophosphate decarboxylase (OMPDC) suprafamily, catalyzes the Mg(2+)-dependent decarboxylation of 3-keto-L-gulonate 6-phosphate to L-xylulose 5-phosphate. Structural and biochemical evidence suggests that the KGPDC reaction proceeds via a…
High-surface-area SiC has unique mechanical and thermal properties for use as a catalyst and sorbent support. A modified sol−gel route was chosen to synthesize SiC, where the precursor (phenyltrimethoxysilane) was hydrolyzed in the presence of a solvent (methanol) in order to enhance reaction rates and control the por…
Electronic relaxation dynamics of photoexcited CdSe quantum rods have been studied with femtosecond transient absorption spectroscopy. Samples with the same length, ∼30 nm, but with different diameters, 2.5 and 8.0 nm, were investigated. We found that the intraband energy relaxation is about 8 times faster in the thin…
Carbon/gold composite nanotubes as well as gold nanorods were synthesized by the impregnation of porous alumina with diluted hydrogen tetrachloroaurate (HAuCl 4 )/acetone solutions and subsequent thermolysis at moderate temperatures. Gold(III) is reduced, whereas carbon provided by the solvent acetone is oxidized. No…
Synthesis and magnetic studies of a new class of organic spin clusters, possessing alternating connectivity of unequal spins, are described. Polyarylmethyl polyether precursors to the spin clusters, with linear and branched connectivity between calix[4]arene-based macrocycles, are prepared via modular, multistep synth…
Polyhydroxyalkanoates (PHAs) are biodegradable polyesters that have a wide variety of physical properties dependent on the lengths of the pendant groups of the monomer units in the polymer. PHAs composed of mostly short-chain-length (SCL) monomers are often stiff and brittle, whereas PHAs composed of mostly medium-cha…
In this paper a method for fabricating nanostructured polymeric surfaces with contrasted chemical functionality is presented. First, a polymer film of acrylic acid (PAA) is deposited by plasma enhanced chemical vapor deposition. It is covered by a monolayer of particles in the 500 nm range. Then oxygen plasma etching…
The interaction of NH 3 and NO 2 with heterogeneous bundles of carbon single-walled nanotubes (SWNTs) has been studied using FTIR spectroscopy and temperature-programmed desorption (TPD). Both NH 3 and NO 2 adsorb at room temperature, and the interaction results in strong shifts of the vibrational modes of the molecul…
In situ low-energy electron microscopy was used to study interlayer mass transport kinetics during annealing of three-dimensional (3D) TiN(111) mounds, consisting of stacked 2D islands, at temperatures T between 1550 and 1700 K. At each T, the islands decay at a constant rate, irrespective of their initial position in…
Dyson orbitals play an important role in understanding quasi-particle effects in the correlated ground state of a many-particle system and are relevant for describing the Compton scattering cross section beyond the frameworks of the impulse approximation (IA) and the independent particle model (IPM). Here we discuss c…
The Kirchhoff's theory for thin, inextensible, elastic rods with nonhomogeneous cross section is studied. The Young's and shear moduli of the rod are considered to vary radially, and it is shown that an analytical solution for the constitutive relations can be obtained for circular cross section and constant Poisson's…
Dilute granular flows are routinely described by collisional kinetic theory, but dense flows require a fundamentally different approach, due to long-lasting, many-body contacts. In the case of silo drainage, many continuum models have been developed for the mean flow, but no realistic statistical theory is available.…
We report experimental and theoretical studies on the plasmon resonances of finite one-dimensional chains of Au nanoparticles excited by evanescent light waves with polarization parallel to the chains. The experimental results show that the plasmon resonance peak wavelengths of these finite 1D chains are significantly…
It is essential to put individual, free-standing nanowires onto insulating substrates and integrate them to useful devices. Here we report a strategy for fabrication of conducting polymer nanowires on thermally oxidized Si surfaces by use of DNA as templates. The direct use of stretched and immobilized DNA strands as…