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Exchange interaction in multinuclear transition-metal complexes. 1. Synthesis, x-ray structure, and magnetic and spectroscopic properties of di-.mu.-methoxy-dichloro[1,4-piperazinebis(N-ethylenesalicylaldiminato)]diiron(III), Fe2L(OCH3)2Cl2

B. Chiari、O. Piovesana、T. Tarantelli 等 4 位作者1982-04-01Inorganic Chemistry

ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTExchange interaction in multinuclear transition-metal complexes. 1. Synthesis, x-ray structure, and magnetic and spectroscopic properties of di-.mu.-methoxy-dichloro[1,4-piperazinebis(N-ethylenesalicylaldiminato)]diiron(III), Fe2L(OCH3)2Cl2B. Chiari, O. Piovesana, T. Tarante…

Magnetism in coordination complexesLanthanide and Transition Metal ComplexesElectron Spin Resonance Studies

Molybdenum(IV)-oxo complexes with oxygen, nitrogen and sulfur ligands. Syntheses and electrochemical studies

Ian W. Boyd、Jack T. Spence1982-04-01Inorganic Chemistry

ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTMolybdenum(IV)-oxo complexes with oxygen, nitrogen and sulfur ligands. Syntheses and electrochemical studiesI. W. Boyd and J. T. SpenceCite this: Inorg. Chem. 1982, 21, 4, 1602–1606Publication Date (Print):April 1, 1982Publication History Published online1 May 2002Published…

Electrocatalysts for Energy ConversionPolyoxometalates: Synthesis and ApplicationsMetalloenzymes and iron-sulfur proteins

Mechanisms of formation of volatile aromatic pyrolyzates from poly(vinyl chloride)

Robert P. Lattimer、William J. Kroenke1982-04-01Journal of Applied Polymer Science

Abstract The formation of volatile aromatic pyrolyzates in poly(vinyl chloride) has been studied by pyrolysis–gas chromatography–mass spectroscopy. Results from isotopic labeling experiments with perdeutero‐PVC suggest that the aromatic pyrolyzates can be divided into three general classes with respect to their format…

Thermal and Kinetic AnalysisPolymer Science and PVCPolymer Synthesis and Characterization

Strengthening of a Sintered Silicon Nitride by a Post‐Fabrication Heat Treatment

David R. Clarke、F. F. Lange、G. D. Schnittgrund1982-04-01Journal of the American Ceramic Society

The strength improvement of an injection‐molded and sintered silicon nitride ceramic (15.5 wt% Y 2 O 3 +10.1 wt% SiO 2 ) produced by an oxidation heat treatment at 1500°C is reported. The ceramic retains its strength after prolonged intermediate temperature exposure in air, whereas the untreated material suffers vario…

Advanced ceramic materials synthesisMetal and Thin Film MechanicsSemiconductor materials and devices

Heat-Stable and Fructose 1,6-Bisphosphate-Activated L-Lactate Dehydrogenase from an Extremely Thermophilic Bacterium1

Hayao Taguchi、Minoru YAMASHITA、Hiroshi Matsuzawa 等 4 位作者1982-04-01The Journal of Biochemistry

Heat-stable L-lactate dehydrogenase [EC 1.1.1.27] was purified from an extremely thermophilic bacterium belonging to the genus Thermus, and it showed an allosteric nature dependent on fructose 1,6-bisphosphate as an effector. The enzyme had a molecular weight of approximately 120,000 with a subunit molecular weight of…

Microbial Metabolic Engineering and BioproductionEnzyme Structure and FunctionAmino Acid Enzymes and Metabolism

Novel unusually stable peroxotitanium(IV) compounds. Molecular and crystal structure of peroxobis(picolinato)(hexamethylphosphoric triamide)titanium(IV)

Hubert Mimoun、Michèle Postel、F. CASABIANCA 等 5 位作者1982-04-01Inorganic Chemistry

ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTNovel unusually stable peroxotitanium(IV) compounds. Molecular and crystal structure of peroxobis(picolinato)(hexamethylphosphoric triamide)titanium(IV)Hubert Mimoun, Michele Postel, Francis Casabianca, Jean Fischer, and Andre MitschlerCite this: Inorg. Chem. 1982, 21, 4, 13…

Metal-Organic Frameworks: Synthesis and ApplicationsPolyoxometalates: Synthesis and ApplicationsChemical Synthesis and Characterization

Polymerization of pyrrole by potassium persulfate

K.C. Khulbe、R. S. Mann、C. P. Khulbe1982-04-01Journal of Polymer Science Polymer Chemistry Edition

Abstract Pyrrole reacted with potassium persulfate in aqueous media to form polymers or “pyrrole blacks.” The structure and molecular weight depend on the initial pyrrole/K 2 S 2 O 8 ratio. An ESR line due to trapped electrons or free radical ions appeared at g = 2.0036 (width 3.6 G) in all products and its intensity…

Conducting polymers and applicationsPorphyrin and Phthalocyanine ChemistryAnalytical Chemistry and Sensors

Quantitative low temperature optical microscopy of biological systems

Kenneth R. Diller1982-04-01Journal of Microscopy

A comprehensive review is presented of low temperature optical microscopy techniques as applied to the study of freezing processes in biological systems. Emphasis is placed on analysis of physical and physiological parameters which were measured and/or controlled and the procedures for effecting such operations. Quant…

Spectroscopy and Quantum Chemical StudiesCrystallization and Solubility Studiesthermodynamics and calorimetric analyses

Studies of the ATP-dependent proteolytic enzyme, protease La, from Escherichia coli.

F Larimore、Lloyd Waxman、Alfred L. Goldberg1982-04-01Journal of Biological Chemistry

The ATP-dependent proteolytic activity, protease La, *om Escherichia coli has been partially purified, and the role of ATP investigated.ATP (3 m) stimulated degradation of [methyL3HJcasein and [methyl-'*C]apohemoglobin 8-40-fold but only when M&' was present.The nucleotide had to be continuously present for this proce…

Mass Spectrometry Techniques and ApplicationsEnzyme Structure and FunctionHemoglobin structure and function

Magnetic hardening of Pr-Fe and Nd-Fe alloys by melt-spinning

J. J. Croat1982-04-01Journal of Applied Physics

The dependence of the hard magnetic properties of melt-spun Nd1−xFex (0.5⩽x⩽0.7) and Pr1−xFex (0.4⩽x⩽0.7) alloys on quench rate is reported; the latter was controlled by varying the substrate surface velocity (vs ) of the melt-spinner. All of the alloys show an appreciable maximum in coercivity (Hci ) as a function of…

Magnetic and transport properties of perovskites and related materialsRare-earth and actinide compoundsMagnetic Properties of Alloys

Phase transitions in mesophase macromolecules. III. The transitions in poly(ethylene terephthalate‐co‐p‐oxybenzoate)

Wiriya Meesiri、Jozsef Menczel、Umesh Kumar Gaur 等 4 位作者1982-04-01Journal of Polymer Science Polymer Physics Edition

Abstract The glass and melting transitions of poly(ethylene terephthalate‐co‐ p ‐oxybenzoate)s have been studied by differential scanning calorimetry. Despite the higher glass transition expected for polyoxybenzoate, there is almost no change in the glass transition temperature up to 63 mol % oxybenzoate (353 ± 4 K).…

Liquid Crystal Research AdvancementsPolymer crystallization and propertiesPolymer Nanocomposites and Properties

Melting point relations for simple halides, oxides, and chalcides

L. G. Van Uitert1982-04-01Journal of Applied Physics

For simple halides, oxides, and chalcides, the measure of crystal cohesion represented by the product of the melting point and the square of the bond length scales with the coordination number of the cation as well as with the ease of reversible transfer of electrons between neighboring atoms. Effects due to changes i…

Solid-state spectroscopy and crystallographynanoparticles nucleation surface interactionsX-ray Diffraction in Crystallography

Lattice Mode Anharmonicity in Sodium Nitrite

F. Bréhat、B. Wyncke、M. El Shérif1982-04-01physica status solidi (b)

Abstract The anharmonicity of the infrared active lattice modes of sodium nitrite is studied from measurements of the infrared reflectivity from 60 to 400 cm −1 , in the temperature range 80 to 460 K. The infrared reflectivity spectra are analysed with the four‐parameter dispersion model based on the factorized form o…

Nonlinear Optical Materials ResearchAcoustic Wave Resonator TechnologiesSolid-state spectroscopy and crystallography

Solubilities of some electrolytes in water-pyridine and water-acetonitrile solvent mixtures

J. L. Brisset1982-04-01Journal of Chemical & Engineering Data

ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTSolubilities of some electrolytes in water-pyridine and water-acetonitrile solvent mixturesJean Louis BrissetCite this: J. Chem. Eng. Data 1982, 27, 2, 153–155Publication Date (Print):April 1, 1982Publication History Published online1 May 2002Published inissue 1 April 1982ht…

Thermodynamic properties of mixturesCrystallization and Solubility StudiesChemical and Physical Properties in Aqueous Solutions

Reactions of triplet states of a porphyrin measured by delayed fluorescence

Jehuda Feitelson、D. Mauzerall1982-04-01The Journal of Physical Chemistry

ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTReactions of triplet states of a porphyrin measured by delayed fluorescenceJ. Feitelson and D. MauzerallCite this: J. Phys. Chem. 1982, 86, 9, 1623–1628Publication Date (Print):April 1, 1982Publication History Published online1 May 2002Published inissue 1 April 1982https://p…

Porphyrin and Phthalocyanine ChemistryMolecular Junctions and NanostructuresPhotochemistry and Electron Transfer Studies

Pre-Breakdown Discharges in Highly Non-uniform Fields in Relation to Gas-insulated Systems

H. Anis、K.D. Srivastava1982-04-01IEEE Transactions on Electrical Insulation

In clean SF6 gas-insulated power transmission systems significant pre-breakdown discharges are rarely observed. This is so because the prevailing electric field is only moderately non-uniform. In practical systems, however, conducting particle contamination creates regions of highly non-uniform fields. Initial ionizat…

High voltage insulation and dielectric phenomenaLightning and Electromagnetic PhenomenaAerosol Filtration and Electrostatic Precipitation

Crack Propagation in Irradiated B 4 C Induced by Swelling and Thermal Gradients

G.W. Hollenberg、J.A. Basmajian1982-04-01Journal of the American Ceramic Society

Boron carbide pellets, used as the neutron absorber materials in fast breeder reactors, were observed to crack in two distinctly different ways. Radial thermal gradients are produced as a result of internal heat generation. In larger‐diameter pellets, these thermal expansion gradients are large and it was observed tha…

Fusion materials and technologiesNuclear reactor physics and engineeringNuclear Materials and Properties

Determination of sulfur in asphalts by selective oxidation and photoelectron spectroscopy for chemical analysis

Jean Michel. Ruiz、Brian M. Carden、L. Léna 等 5 位作者1982-04-01Analytical Chemistry

ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTDetermination of sulfur in asphalts by selective oxidation and photoelectron spectroscopy for chemical analysisJean Michel. Ruiz, Brian M. Carden, Louis J. Lena, Emile Jean. Vincent, and Jean Claude. EscalierCite this: Anal. Chem. 1982, 54, 4, 688–691Publication Date (Print)…

Atmospheric chemistry and aerosolsCorrosion Behavior and InhibitionElectrochemical Analysis and Applications

The variation of grain boundary structural width with misorientation angle and boundary plane

S. Hagège、C. B. Carter、F. Cosandey 等 4 位作者1982-04-01Philosophical magazine. A/Philosophical magazine. A. Physics of condensed matter. Structure, defects and mechanical properties

An important characteristic of a grain boundary is the depth to which its displacement field penetrates into the neighbouring single crystals. This boundary thickness, which is called the ‘structural width’ in this paper, may be studied by the use of an electron diffraction technique which is sensitive to the width of…

Microstructure and mechanical propertiesMicrostructure and Mechanical Properties of SteelsCopper Interconnects and Reliability

Phasenverhältnisse in den Systemen Cer‐Wasserstoff und Cer‐Deuterium

Peter Knappe、Horst Müller1982-04-01Zeitschrift für anorganische und allgemeine Chemie

Abstract Die Phasenverhältnisse im System Cer‐Wasserstoff wurden neu untersucht. Im Gegensatz zu den bisherigen Literaturangaben konnte bei den kubischen Hydriden eine Abnahme der Gitterparameter mit steigendem Wasserstoffgehalt nur bis zu einer Zusammensetzung von CeH 2,30 beobachtet werden, bei noch größeren Wassers…

Hydrogen Storage and MaterialsInorganic Chemistry and MaterialsInorganic Fluorides and Related Compounds