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An imidazolate-bridged tetranuclear copper(II) complex: synthesis, magnetic and EPR studies, and crystal structure of [L4Cu4(Im)4](ClO4)4.2H2O (L = 1,4,7-triazacyclononane, Im = imidazolate anion)

Phalguni Chaudhuri、Ina Karpenstein、Manuela Winter 等 9 位作者1993-03-01Inorganic Chemistry

ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTAn imidazolate-bridged tetranuclear copper(II) complex: synthesis, magnetic and EPR studies, and crystal structure of [L4Cu4(Im)4](ClO4)4.2H2O (L = 1,4,7-triazacyclononane, Im = imidazolate anion)Phalguni Chaudhuri, Ina Karpenstein, Manuela Winter, Marek Lengen, Christian Bu…

Metal-Organic Frameworks: Synthesis and ApplicationsMetal complexes synthesis and propertiesMagnetism in coordination complexes

Computation of 3-D magnetostatic fields using a reduced scalar potential

Oszkár Bíró、Kurt Preis、G. Vrisk 等 5 位作者1993-03-01IEEE Transactions on Magnetics

Some improvements to the finite element computation of static magnetic fields in three dimensions using a reduced magnetic scalar potential are presented. Methods are described for obtaining an edge element representation of the rotational part of the magnetic field from a given source current distribution. When the c…

Magnetic Properties and ApplicationsElectromagnetic Simulation and Numerical MethodsNon-Destructive Testing Techniques

INFLUENCE OF THE PEPTIDE BOND ON THE SINGLET MOLECULAR OXYGEN‐MEDIATED (O2[g]) PHOTOOXIDATION OF HISTIDINE and METHIONINE DIPEPTIDES. A KINETIC STUDY

Sandra Miskoski、Norman A. Garcı́a1993-03-01Photochemistry and Photobiology

Abstract The dye‐sensitized photooxidation of l ‐histidine (His) and l ‐methionine (Met) and their simplest dipeptides with glycine (Gly) (His‐Gly, Gly‐His, Gly‐Met) and Met‐methyl ester (Met‐ME) mediated by singlet molecular oxygen (O 2 [ g ]) was studied. The overall rate constants in acetonitrile‐H 2 O ( K t ) for…

Photodynamic Therapy Research StudiesPhotochemistry and Electron Transfer StudiesPhotochromic and Fluorescence Chemistry

Poly(arylmethyl) quartet triradicals and quintet tetraradicals

Andrzej Rajca、Suchada Utamapanya1993-03-01Journal of the American Chemical Society

ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTPoly(arylmethyl) quartet triradicals and quintet tetraradicalsAndrzej Rajca and Suchada UtamapanyaCite this: J. Am. Chem. Soc. 1993, 115, 6, 2396–2401Publication Date (Print):March 1, 1993Publication History Published online1 May 2002Published inissue 1 March 1993https://pub…

Polymer Nanocomposites and PropertiesSynthesis and Properties of Aromatic CompoundsSynthesis and properties of polymers

Composition dependence of the electronic properties of Al-Cu-Fe and Al-Cu-Ru-Si semimetallic quasicrystals

F. S. Pierce、Peter A. Bancel、B. D. Biggs 等 5 位作者1993-03-01Physical review. B, Condensed matter

Electronic transport properties and specific heats of ordered icosahedral phase alloys in the Al-Cu-Ru-Si and Al-Cu-Fe systems are examined, and comparison with high-quality rhombohedral (3/2) approximant phase samples of Al-Cu-Fe is made. Strong temperature dependence and sensitivity to composition changes of these p…

Microstructure and mechanical propertiesQuasicrystal Structures and PropertiesX-ray Diffraction in Crystallography

Effects of Interfacial Conditions on Wall Slip and Sharkskin Melt Fracture of HDPE

S. G. Hatzikiriakos、John M. Dealy1993-03-01International Polymer Processing

Abstract Experiments were performed in capillary and slit rheometers to determine the effects of the presence of fluoropolymers at the polymer-wall interface on wall slip and extrudate distortion of a molten high density polyethylene. Two fluoropolymers were used to modify the interface. It was found that one of these…

Polymer crystallization and propertiesRheology and Fluid Dynamics StudiesTransport Systems and Technology

Simultaneous Concentration Measurement of Vapor and Liquid in an Evaporating Diesel Spray

Mamoru Suzuki、Keiya Nishida、Hiroyuki HIROYASU1993-03-01SAE technical papers on CD-ROM/SAE technical paper series

<div class="htmlview paragraph">A new technique was proposed for the simultaneous measurement of the concentration of fuel vapor and liquid in an evaporating diesel spray injected into a high temperature and high pressure environment. This technique was based on the principle of the absorption of ultraviolet las…

Catalytic Processes in Materials ScienceVehicle emissions and performanceElectrohydrodynamics and Fluid Dynamics

Growth of silica polymers in a lamellar mesophase

M. Dubois、T. Gulik‐Krzywicki、Bernard Cabane1993-03-01Langmuir

ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTGrowth of silica polymers in a lamellar mesophaseM. Dubois, T. Gulik-Krzywicki, and B. CabaneCite this: Langmuir 1993, 9, 3, 673–680Publication Date (Print):March 1, 1993Publication History Published online1 May 2002Published inissue 1 March 1993https://pubs.acs.org/doi/10.1…

Mesoporous Materials and Catalysis

Oxidation resistant inorganic-porphyrin analog polyoxometalates. 3. Synthesis and x-ray crystallographic characterization of a new heteropolyoxoanion structural type, the diruthenium-oxo-bridged bimetallic inorganic-porphyrin analog KLi15[O{RuIVCl(.alpha.2-P2W17O61)}2].2KCl.60H2O

William J. Randall、T.J.R. Weakley、Richard G. Finke1993-03-01Inorganic Chemistry

ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTOxidation resistant inorganic-porphyrin analog polyoxometalates. 3. Synthesis and x-ray crystallographic characterization of a new heteropolyoxoanion structural type, the diruthenium-oxo-bridged bimetallic inorganic-porphyrin analog KLi15[O{RuIVCl(.alpha.2-P2W17O61)}2].2KCl.…

Metal-Organic Frameworks: Synthesis and ApplicationsPorphyrin and Phthalocyanine ChemistryPolyoxometalates: Synthesis and Applications

The first surface-attached catenane: self-assembly of a two-component monolayer

Tianbao Lu、Litao Zhang、George W. Gokel 等 4 位作者1993-03-01Journal of the American Chemical Society

ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTThe first surface-attached catenane: self-assembly of a two-component monolayerTianbao Lu, Litao Zhang, George W. Gokel, and Angel E. KaiferCite this: J. Am. Chem. Soc. 1993, 115, 6, 2542–2543Publication Date (Print):March 1, 1993Publication History Published online1 May 200…

Molecular Junctions and NanostructuresForce Microscopy Techniques and ApplicationsDiatoms and Algae Research

Simulation of elastic and plastic response in the glassy polycarbonate of 4,4'-isopropylidenediphenol

Michelle Hutnik、A. S. Argon、Ulrich W. Suter1993-03-01Macromolecules

ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTSimulation of elastic and plastic response in the glassy polycarbonate of 4,4'-isopropylidenediphenolM. Hutnik, A. S. Argon, and U. W. SuterCite this: Macromolecules 1993, 26, 5, 1097–1108Publication Date (Print):March 1, 1993Publication History Published online1 May 2002Pub…

Liquid Crystal Research AdvancementsPolymer crystallization and propertiesPolymer Nanocomposites and Properties

Mixed monolayers formed by the self-assembly on gold of thiol-functionalized anthraquinones and 1-alkanethiols

Litao Zhang、Tianbao Lu、George W. Gokel 等 4 位作者1993-03-01Langmuir

ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTMixed monolayers formed by the self-assembly on gold of thiol-functionalized anthraquinones and 1-alkanethiolsLitao Zhang, Tianbao Lu, George W. Gokel, and Angel E. KaiferCite this: Langmuir 1993, 9, 3, 786–791Publication Date (Print):March 1, 1993Publication History Publish…

Gold and Silver Nanoparticles Synthesis and ApplicationsMolecular Junctions and Nanostructuresthermodynamics and calorimetric analyses

PHOTOPHYSICAL PROPERTIES OF 3,3′‐DIALKYLTHIACARBOCYANINE DYES IN HOMOGENEOUS SOLUTION

Marianne Krieg、Robert W. Redmond1993-03-01Photochemistry and Photobiology

The photophysical properties of 3,3'-dialkylthiacarbocyanine iodides and chlorides were measured in various solvents. It was found that photoisomerization and fluorescence are the major contributors to the deactivation of the excited singlet state; intersystem crossing occurs with only a very low efficiency. In ethano…

Porphyrin and Phthalocyanine ChemistryPhotodynamic Therapy Research StudiesPhotochemistry and Electron Transfer Studies

New effective catalysts for Mukaiyama-aldol and -Michael reactions: bismuth trichloride-metallic iodide systems

Christophe Le Roux、Hafida Gaspard‐Iloughmane、Jacques Dubac 等 5 位作者1993-03-01The Journal of Organic Chemistry

ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTNew effective catalysts for Mukaiyama-aldol and -Michael reactions: bismuth trichloride-metallic iodide systemsChristophe Le Roux, Hafida Gaspard-Iloughmane, Jacques Dubac, Joel Jaud, and Pierre VignauxCite this: J. Org. Chem. 1993, 58, 7, 1835–1839Publication Date (Print):M…

Catalytic Processes in Materials ScienceIonic liquids properties and applicationsMesoporous Materials and Catalysis

Dependence of the OBDD morphology on diblock copolymer molecular weight in copolymer/homopolymer blends

Richard J. Spontak、Steven D. Smith、Arman Ashraf1993-03-01Macromolecules

ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTDependence of the OBDD morphology on diblock copolymer molecular weight in copolymer/homopolymer blendsRichard J. Spontak, Steven D. Smith, and Arman AshrafCite this: Macromolecules 1993, 26, 5, 956–962Publication Date (Print):March 1, 1993Publication History Published onlin…

Block Copolymer Self-Assembly

Influence of ZrO 2 Grain Size and Content on the Transformation Response in the Al 2 O 3 ─ZrO 2 (12 mol% CeO 2 ) System

Paul Becher、K.B. Alexander、A. Bleier 等 5 位作者1993-03-01Journal of the American Ceramic Society

Based on experimental and modeling studies, the rate of increase in the martensite start temperature M s for the tetragonal‐to‐monoclinic transformation with increase in zirconia grain size is found to rise with decrease in ZrO 2 content in the zirconia‐toughened alumina ZTA system. The observed grain size dependence…

Advanced ceramic materials synthesisIntermetallics and Advanced Alloy PropertiesAdvanced materials and composites

Visible absorption and photocurrent spectra of epitaxially deposited phthalocyanine thin films: interpretation of exciton coupling effects

Lai‐Kwan Chau、C. D. England、Siying Chen 等 4 位作者1993-03-01The Journal of Physical Chemistry

ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTVisible absorption and photocurrent spectra of epitaxially deposited phthalocyanine thin films: interpretation of exciton coupling effectsLai Kwan Chau, Craig D. England, Siying Chen, and Neal R. ArmstrongCite this: J. Phys. Chem. 1993, 97, 11, 2699–2706Publication Date (Pri…

Porphyrin and Phthalocyanine ChemistryPhotochemistry and Electron Transfer StudiesPhotochromic and Fluorescence Chemistry

Deposition of polytetrafluoroethylene films by laser ablation

Graciela B. Blanchet、S. Ismat Shah1993-03-01Applied Physics Letters

Films of polytetrafluoroethylene (PTFE) were deposited by laser ablation using the fourth harmonic, at 266 nm, of a Nd-YAG laser. The films are found to be stoichiometric with the correct optical properties. We suggest that UV absorption onsets the pyrolitic decomposition of PTFE leading to a monomer that subsequently…

Surface Modification and SuperhydrophobicityLaser Material Processing TechniquesPolymer Nanocomposite Synthesis and Irradiation

Colloidal dispersions of surfactant-stabilized polypyrrole particles

Christopher DeArmitt、Steven P. Armes1993-03-01Langmuir

ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTColloidal dispersions of surfactant-stabilized polypyrrole particlesC. DeArmitt and S. P. ArmesCite this: Langmuir 1993, 9, 3, 652–654Publication Date (Print):March 1, 1993Publication History Published online1 May 2002Published inissue 1 March 1993https://pubs.acs.org/doi/10…

Conducting polymers and applicationsPolymer Surface Interaction Studies

Polar fluctuations and first-order Raman scattering in highly polarizableKTaO3crystals with off-center Li and Nb ions

P. DiAntonio、B. E. Vugmeǐster、J. Toulouse 等 4 位作者1993-03-01Physical review. B, Condensed matter

Relatively low concentrations of randomly substituted off-center ions are known to induce ferroelectric order in highly polarizable crystals. In the case of potassium tantalate (${\mathrm{KTaO}}_{3}$) doped with lithium or niobium, the results of first-order Raman scattering from two hard phonon modes (${\mathrm{TO}}_…

Glass properties and applicationsPhotorefractive and Nonlinear OpticsSolid-state spectroscopy and crystallography