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Phase front and domains during the paraelectric-ferroelectric transition inKD2PO4:Optical observation and dielectric contributions

Jean Bornarel、R. Cach1999-08-01Physical review. B, Condensed matter

Observations of the phase front and the domains during the paraelectric-ferroelectric ${\mathrm{KD}}_{2}{\mathrm{PO}}_{4}$ phase have been performed in very good thermal homogeneity conditions (thermal gradient equal to $2\ifmmode\times\else\texttimes\fi{}{10}^{\ensuremath{-}3}{\mathrm{K}\mathrm{}\mathrm{mm}}^{\mathrm…

Ferroelectric and Piezoelectric MaterialsAcoustic Wave Resonator TechnologiesSolid-state spectroscopy and crystallography

The isotropic–nematic transition and the phase separation of the tobacco mosaic virus particles with polysaccharide

Naohito Urakami、Masayuki Imai、Yoh Sano 等 4 位作者1999-08-01The Journal of Chemical Physics

The isotropic–nematic transition of the tobacco mosaic virus (TMV) particles by polysaccharide is related to a high inhibitory activity against TMV infection. We study the process of the isotropic–nematic transition of the TMV particles as a function of the polysaccharide concentration by Monte Carlo simulations in th…

Liquid Crystal Research AdvancementsPlant Virus Research StudiesPlant Reproductive Biology

Modern steels for transformers and machines

P. Beckley1999-08-01Engineering Science and Education Journal

Electrical machines depend on ferromagnetic materials to handle useful power within a practicable compass. Flux magnification and control lies at the heart of machine efficiency. Reduction of thickness, perfection of purity and improved grain texture are some of the ways forward. Streamlined standardised loss measurin…

Magnetic Properties and ApplicationsNon-Destructive Testing TechniquesInduction Heating and Inverter Technology

Low-temperature dielectric relaxation peaks involving proton tunneling inBa1−xNdxCeO3

Igor L. Kuskovsky、Byeong Soo Lim、A. S. Nowick1999-08-01Physical review. B, Condensed matter

An investigation of dielectric relaxation at relatively low-temperature (55--225 K) of the protonic conductor ${\mathrm{Ba}}_{1\ensuremath{-}x}{\mathrm{Nd}}_{x}{\mathrm{CeO}}_{3},$ for $x=0.05,$ has revealed a major dielectric relaxation peak, as well as an associated smaller peak, with characteristics that strongly s…

Advancements in Solid Oxide Fuel CellsHigh-pressure geophysics and materialsMagnetic and transport properties of perovskites and related materials

Raman intensities near gypsum-bassanite transition in natural gypsum

Pinnelli S. R. Prasad1999-08-01Journal of Raman Spectroscopy

The phase transition sequence of natural gypsum (CaSO4 · 2H2O) was studied by Raman spectroscopy in the temperature range 300–550 K. The reduced peak intensity of the symmetric stretching mode around 1008 cm−1 varied anomalously during the gypsum–bassanite transition. From the spectral variations of this mode in the t…

Geological and Geochemical AnalysisBuilding materials and conservationClay minerals and soil interactions

A maximum entropy method for determining column-length distributions from size-broadened X-ray diffraction profiles

Neal R. Armstrong、W. Kalceff1999-08-01Journal of Applied Crystallography

We present a novel application of the maximum entropy (MaxEnt) method for solving the double-inverse problems of removing instrument broadening from X-ray diffraction profiles and calculating the column-length distribution of the crystallites. The MaxEnt approach is shown to have compelling advantages over the convent…

Crystallography and molecular interactionsMachine Learning in Materials ScienceX-ray Diffraction in Crystallography

Acidities of CeO2 and Ce0.5Zr0.5O2 solid solutions studied by NH3-TPD

Jianying Miao、Lefu Yang、Junxiu Cai1999-08-01Surface and Interface Analysis

Ammonia temperature-programmed desorption (NH3-TPD) was used to study the acidities of CeO2 and Ce0.5Zr0.5O2 solid solutions. The NH3-TPD peaks of both CeO2 and Ce0.5Zr0.5O2 exist at 100–850 °C. The ratio of the lower and middle temperature peak areas to the higher temperature peak is decreased for Ce0.5Zr0.5O2 relati…

Catalytic Processes in Materials ScienceCatalysis and Oxidation ReactionsIndustrial Gas Emission Control

Thermally and Optically Stimulated Luminescence of AlN-Y2O3 Ceramics after Ionising Irradiation

L. Trinkler、A.J.J. Bos、Andrew Winkelman 等 6 位作者1999-08-01Radiation Protection Dosimetry

Thermally (TL) and optically stimulated luminescence (OSL) were studied in AlN-Y2O3 ceramics after irradiation with ionising radiation. The extremely high TL sensitivity (approximately 60 times the sensitivity of LiF:Mg,Tl (TLD-100)) makes AlN-Y2O3 ceramics attractive as a TLD material. However, an essential drawback…

Luminescence Properties of Advanced MaterialsGaN-based semiconductor devices and materialsGa2O3 and related materials

Optical constants of amorphous Se

Takeshi Innami、Takayuki Miyazaki、Sadao Adachi1999-08-01Journal of Applied Physics

The pseudodielectric-function spectra, ε(E)=ε1(E)+iε2(E), of amorphous (a-) selenium (Se) in the 1.2–5.2 eV photon-energy range at room temperature were measured by spectroscopic ellipsometry. The a-Se films investigated were deposited by vacuum evaporation in a base pressure of 2×10−6 Torr on Si(100) substrates at ro…

Chalcogenide Semiconductor Thin FilmsPhase-change materials and chalcogenidesNonlinear Optical Materials Studies

Basic Thermoluminescence Properties of Micas: Muscovite, Sericite and Phlogopite

J.L. B rcena、M. Urbina、Aled Rowlands 等 6 位作者1999-08-01Radiation Protection Dosimetry

Natural thermoluminescence as well as gamma and beta induced thermoluminescence were studied in a set of micas with the general formula (K, Na) Xn AlSi3O10(OH,F)2, where X corresponds to Al3+, Mn2+, Mn3+, Fe2+, Fe3+, Mg2+, Ti4+ or Li+, depending on the mica type. These minerals are classified according to crystallogra…

Luminescence Properties of Advanced MaterialsGlass properties and applicationsRadiation Detection and Scintillator Technologies

Synthesis and testing of nonhalogenated alkyne/phosphorus-containing polymer additives: Potent condensed-phase flame retardants

Alexander B. Morgan、James M. Tour1999-08-01Journal of Applied Polymer Science

In this article, the syntheses and thermal properties of several alkyne- and phosphorus-containing materials are discussed. The materials were synthesized using substituted phenolic molecules which were added to phosphorus oxychloride. The materials synthesized include phosphine oxides, phosphates, diphosphates, and o…

Flame retardant materials and propertiesOrganophosphorus compounds synthesisPhosphorus compounds and reactions

Selected Thermoluminescent Properties in CVD Diamond Film

Mourad Benabdesselam、P. Iacconi、D. Briand 等 5 位作者1999-08-01Radiation Protection Dosimetry

In the present work, some thermoluminescent properties of chemically vapour deposited (CVD) polycrystalline diamond films are investigated. After radiation, two TL peaks at least located at 350 and 540 K are observed. After depletion of the low temperature peaks, the 540 K TL peak is isolated and then analysed by diff…

Diamond and Carbon-based Materials ResearchGas Dynamics and Kinetic TheoryIon-surface interactions and analysis

Dislocations in nonlinear nonlocal media: Martensitic embryo formation

Andrew Reid、Gregory B. Olson、Brian J. Moran1999-08-01Phase Transitions

A model is developed for determining the stress and strain fields of an array of slip dislocation defects in a two-dimensional elastic medium with a highly nonlinear and nonlocal energy functional. The medium serves as a model for an elastic system in the vicinity of a martensitic structural phase transformation, in t…

Microstructure and mechanical propertiesForce Microscopy Techniques and ApplicationsNonlocal and gradient elasticity in micro/nano structures

Polyethyloxazoline monolayers for polymer supported biomembrane models

Thomas Lehmann、Jürgen Rühe1999-08-01Macromolecular Symposia

Abstract The synthesis of polymer monolayers, which are designed to act as “cushions” for lipid membranes attached to solid surfaces, is described. Monolayers of poly(ethyloxazolines) which could act as a polymeric support for biomimetic membranes have been attached to silicon oxide or gold surfaces following differen…

Lipid Membrane Structure and BehaviorPolymer Surface Interaction StudiesForce Microscopy Techniques and Applications

EFFECT OF INTERMITTENT HEATING ON DRYING-INDUCED STRAIN-STRESS OF MOLDED CLAY

Yoshinori Itaya、Shigekatsu Mori、Masanobu Hasatani1999-08-01Drying Technology

Parametric analyses of the strain-stress in the drying process are performed to study the influence of the intermittent drying on the behaviors of drying-induced strain-stress and deformation as well as the drying characteristic. The transient three-dimensional problem of strain-stress and heat and moisture transfer i…

Heat Transfer and OptimizationTextile materials and evaluationsHygrothermal properties of building materials

New Banana-Shaped Mesogens Exhibiting Switchable Phases at Relatively Low Temperatures

W. Weißflog、Ch. Lischka、Siegmar Diele 等 5 位作者1999-08-01Molecular crystals and liquid crystals science technology. Section A, Molecular crystals and liquid crystals/Molecular crystals and liquid crystals science and technology. Section A, Molecular crystals and liquid crystals

4-Chloro-1,3-phenylene bis[4-(4-n-alkylphenyliminomethyl)benzoates] have been synthesized and the mesophases were investigated by optical microscopy, X-ray diffraction measurements and electrooptical methods. Some derivatives exhibit the electrooptically switchable mesophase B2 between 75–125°C, which can be supercool…

Liquid Crystal Research AdvancementsPhotochemistry and Electron Transfer StudiesSynthesis and Properties of Aromatic Compounds

Fresh and weathered pyrochlore studies by Fourier transform infrared spectroscopy coupled with thermal analysis

Mohamed Nasraoui、Essaïd Bilal、R. Gibert1999-08-01Mineralogical Magazine

Abstract Fresh and weathered pyrochlore from the Lueshe carbonatite complex (in the northeast of the Democratic Republic of Congo) was studied by Fourier transfom infrared (FTIR) spectroscopy and by a combination of FTIR spectroscopy and thermal analysis. The former was carried out in the spectral range 400–4000 cm −1…

Geological and Geochemical AnalysisRadioactive element chemistry and processingNuclear materials and radiation effects

Corrosion Resistance of High-Strength Modified 13% Cr Steel

Mitsuo Kimura、Yukio Miyata、Yuka Yamane 等 6 位作者1999-08-01CORROSION

A new 13% Cr martensitic stainless steel (0.025% C-13% Cr-Ni-Mo) with excellent resistance to carbon dioxide (CO2) corrosion and good resistance to sulfide stress cracking (SSC) was developed, and its application limits in oil and gas environments were clarified. The CO2 corrosion rate of the 13% Cr steels with Ni and…

Microstructure and Mechanical Properties of SteelsHydrogen embrittlement and corrosion behaviors in metalsWelding Techniques and Residual Stresses

Amylose-iodine complex formation without KI: Evidence for absence of iodide ions within the complex

Vincent T. Calabrese、Arshad Khan1999-08-01Journal of Polymer Science Part A Polymer Chemistry

Amylose-iodine (AI) complex has been synthesized in aqueous solution without added KI. Complex formation (with solid iodine in amylose solution) is maximized at approximately 35°C and decreases beyond that temperature. Ion-selective electrode (ISE) measurements of an aqueous solution of iodine and AI complex indicate…

Advanced Cellulose Research StudiesExtraction and Separation ProcessesBiopolymer Synthesis and Applications