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Fabrication of Biomimetic Superhydrophobic Coating with a Micro‐Nano‐Binary Structure

Ning Zhao、Jian Xu、Qiongdan Xie 等 7 位作者2005-06-22Macromolecular Rapid Communications

Abstract Summary: A superhydrophobic coating was facilely fabricated in one step by casting bisphenol A polycarbonate (PC) solution under moisture. Vapor‐induced phase separation occurred during the solidifying process and a rough surface with a micro‐nano‐binary structure (MNBS) similar to the microstructure shown on…

Surface Modification and SuperhydrophobicityAerogels and thermal insulationElectrohydrodynamics and Fluid Dynamics

Dendrimers as Drugs: Discovery and Preclinical and Clinical Development of Dendrimer-Based Microbicides for HIV and STI Prevention

Tom D. McCarthy、Peter Karellas、Scott Henderson 等 9 位作者2005-06-22OpenAlex

Starpharma focuses on the use of dendrimers as drugs in their own right, in contrast to dendrimers as drug delivery vehicles or diagnostics. This contextual review describes how dendrimers offer a unique platform for exploring chemical diversity on the nanoscale and how the production of dendrimer libraries covering a…

RNA Interference and Gene DeliveryChemical Synthesis and AnalysisDendrimers and Hyperbranched Polymers

Reversible single-molecule photoswitching in the GFP-like fluorescent protein Dronpa

Satoshi Habuchi、Ryoko Ando、Peter Dedecker 等 7 位作者2005-06-22OpenAlex

Reversible photoswitching of individual molecules has been demonstrated for a number of mutants of the green fluorescent protein (GFP). To date, however, a limited number of switching events with slow response to light have been achieved at the single-molecule level. Here, we report reversible photoswitching character…

Advanced Fluorescence Microscopy TechniquesPhotochromic and Fluorescence ChemistryPhotoreceptor and optogenetics research

Colloquium:Reactive plasmas as a versatile nanofabrication tool

Kostya Ostrikov2005-06-22OpenAlex

The underlying physics of the application of low-temperature, low-pressure reactive plasmas in various nanoassembly processes is described. From the viewpoint of the ``cause and effect'' approach, this Colloquium focuses on the benefits and challenges of using plasma-based systems in nanofabrication of nanostructured…

Metal and Thin Film MechanicsDiamond and Carbon-based Materials ResearchIon-surface interactions and analysis

Inorganic-Filler Chemical Vapor Deposition: A New Approach To Grow Nanoporous Thin Films

Prahalad M Parthangal、Michael R. Zachariah2005-06-21Chemistry of Materials

A new method for the growth of nanoporous thin films is described. The process is targeted to the formation of titanium dioxide (TiO 2 ) through a low-temperature inorganic-filler chemical vapor deposition (CVD) process. The growth technique employs gas-phase reaction of an alkali metal (Na) and a metal halide (TiCl 4…

Catalytic Processes in Materials ScienceSemiconductor materials and devicesMesoporous Materials and Catalysis

Properties and thermal degradation study of blend films with poly(4‐vinylpyridine) and lignin

Guan Cunxiu、Chen Donghua、Tang Wanjun 等 4 位作者2005-06-21Journal of Applied Polymer Science

Abstract A series of blend films with different ratio of poly(4‐vinylpyridine) (PVP) to lignin were subjected to dynamic DSC and TGA measurement under nitrogen atmosphere at various heating rates. DSC curves showed that the glass transition temperatures of these blends decreased with the increase of lignin content. TG…

Polymer crystallization and propertiesConducting polymers and applicationsPolymer Science and PVC

Novel intercalated nanocomposites of polypropylene/organic‐rectorite/polyethylene‐octene elastomer: Rheology, crystallization kinetics, and thermal properties

Xiaoyan Ma、Guozheng Liang、Hailin Liu 等 5 位作者2005-06-21Journal of Applied Polymer Science

Abstract The melt blending method was applied to prepare ternary composites of polypropylene (PP)/organic‐rectorite (OREC)/polyethylene‐octene elastomer (POE) at constant content of 2 phr (parts per hundred PP) of OREC and 5, 10, 15 phr of POE (named PRE25, PRE210, and PRE215, separately) via twin‐screw extruder. At t…

Polymer crystallization and propertiesPolymer Nanocomposites and Propertiesbiodegradable polymer synthesis and properties

Spin-Probe ESR Study on the Dynamics of Liquid Molecules in the MCM-41 Nanochannel: Temperature Dependence on 2-Propanol and Water

Masaharu Okazaki、Kazumi Toriyama2005-06-21The Journal of Physical Chemistry B

A spin-probe ESR study has been made on the dynamics of 2-propanol and water molecules in the nanochannel of MCM-41 at various temperatures. In the former system, 2-propanol is separated into two phases: one with molecules immobilized in the ESR time scale and the other with mobile ones, even at temperatures more than…

Mesoporous Materials and CatalysisPhotochemistry and Electron Transfer StudiesSpectroscopy and Quantum Chemical Studies

Effects of titanium additions to austenitic ternary alloys on microstructural evolution and void swelling

Tsuyoshi Okita、W.G. Wolfer、F.А. Garner 等 4 位作者2005-06-21The Philosophical Magazine A Journal of Theoretical Experimental and Applied Physics

Ternary austenitic model alloys were modified with 0.25 wt.% titanium and irradiated in the Fast Flux Test Reactor (FFTF) at dose rates ranging over more than two orders in magnitude. While lowering of the dose rate strongly increases swelling by shortening the incubation dose, the steady-state swelling rate is not af…

Fusion materials and technologiesNuclear Materials and PropertiesNuclear materials and radiation effects

From Al4B2O9 Nanowires to BN-Coated Al18B4O33 Nanowires

J. Zhang、Yang Huang、Jing Lin 等 7 位作者2005-06-21The Journal of Physical Chemistry B

A novel route was proposed to completely coat aluminum borate nanowires by in situ providing the precursor for BN coating. Uniformly BN-coated Al18B4O33 nanowires could be obtained by the reaction of Al4B2O9 nanowires with ammonia at high temperature. The high-temperature unstable Al4B2O9 nanowires were converted into…

Advanced ceramic materials synthesisBoron and Carbon Nanomaterials ResearchMXene and MAX Phase Materials

Deformation mechanism of polypropylene composites filled with magnesium hydroxide

Jun Yin、Yong Zhang、Yinxi Zhang2005-06-21Journal of Applied Polymer Science

Abstract The fracture behavior and deformation mechanism of polypropylene (PP) composites filled with magnesium hydroxide [Mg(OH) 2 ] were investigated. The incorporation of Mg(OH) 2 particles into the PP matrix led to an increase in Young's modulus and a significant reduction in the tensile yield strength and elongat…

Polymer Nanocomposites and Propertiesbiodegradable polymer synthesis and propertiesDielectric materials and actuators

Isothermal crystallization kinetics of chain‐extended PET

Luigi Sorrentino、Salvatore Iannace、Ernesto Di Maio 等 4 位作者2005-06-21Journal of Polymer Science Part B Polymer Physics

Abstract The crystallization behavior of a commercial chain‐extended PET (foam grade) was evaluated and compared to that of bottle‐grade PET. Cold and melt isothermal crystallization were analyzed by using the Avrami' model. The foam grade PET showed a slower crystallization kinetic compared to the bottle‐grade PET. T…

Polymer crystallization and propertiesbiodegradable polymer synthesis and propertiesPolymer Foaming and Composites

Superconducting and normal-state interlayer exchange coupling inLa0.67Sr0.33MnO3−YBa2Cu3O7−La0.67Sr0.33MnO3epitaxial trilayers

Kartik Senapati、R. C. Budhani2005-06-21Physical Review B

The issue of interlayer exchange coupling in magnetic multilayers with a superconducting spacer is addressed in ${\mathrm{La}}_{0.67}{\mathrm{Sr}}_{0.33}\mathrm{Mn}{\mathrm{O}}_{3}$ (LSMO)-$\mathrm{Y}{\mathrm{Ba}}_{2}{\mathrm{Cu}}_{3}{\mathrm{O}}_{7}$ (YBCO)-${\mathrm{La}}_{0.67}{\mathrm{Sr}}_{0.33}\mathrm{Mn}{\mathrm…

Physics of Superconductivity and MagnetismMagnetic and transport properties of perovskites and related materialsAdvanced Condensed Matter Physics

Model interaction potentials for selenium fromab initiomolecular simulations

John C. Mauro、Arun K. Varshneya2005-06-21Physical Review B

We develop model interaction potentials for elemental selenium based on ab initio molecular simulations and cluster expansion theory. Our potentials are used in classical Monte Carlo simulations to characterize the structure of selenium glass.

Material Dynamics and PropertiesGlass properties and applicationsPhase-change materials and chalcogenides

Electronic structure and bonding of intergranular glassy films in polycrystallineSi3N4:Ab initiostudies and classical molecular dynamics simulations

Paul Rulis、Jianguo Chen、Lizhi Ouyang 等 6 位作者2005-06-21Physical Review B

The electronic structure and bonding of a realistic model of an intergranular glassy film (IGF) was studied with multiple computational methods. The model has a $\mathrm{Si}--\mathrm{O}--\mathrm{N}$ glassy region sandwiched between crystalline basal planes of $\ensuremath{\beta}\text{\ensuremath{-}}{\mathrm{Si}}_{3}{\…

Luminescence Properties of Advanced MaterialsMaterial Dynamics and PropertiesGlass properties and applications

Size-Selective Synthesis and Stabilization of Gold Organosol in CnTAC: Enhanced Molecular Fluorescence from Gold-Bound Fluorophores

Snigdhamayee Praharaj、Sujit Kumar Ghosh、Sudip Nath 等 7 位作者2005-06-21The Journal of Physical Chemistry B

Gold nanoparticles of variable sizes have been synthesized in toluene employing two-phase (water-toluene) extraction of AuCl4- followed by its reduction with sodium borohydride in the presence of a series of cationic surfactants of a homologous series having the general formula C(n)TAC. The solubility features of the…

Nanoparticles: synthesis and applicationsGold and Silver Nanoparticles Synthesis and ApplicationsLaser-Ablation Synthesis of Nanoparticles

Vacancy-Induced Chemisorption of NO2 on Carbon Nanotubes: A Combined Theoretical and Experimental Study

Francesco Mercuri、Antonio Sgamellotti、Luca Valentini 等 5 位作者2005-06-21The Journal of Physical Chemistry B

The role of structural defects on the adsorption of NO2 on carbon nanotubes (CNTs) is analyzed here by means of both statical density functional theory calculations and Car-Parrinello molecular dynamics and further confirmed by X-ray photoelectron spectroscopy measurements. The interaction of a NO2 molecule with an ac…

Graphene research and applicationsCatalytic Processes in Materials ScienceGas Sensing Nanomaterials and Sensors

Device modeling of long-channel nanotube electro-optical emitter

J. Tersoff、Marcus Freitag、James C. Tsang 等 4 位作者2005-06-21Applied Physics Letters

We present a simple analytic model of long single-wall nanotube electro-optical emitters, along with experimental measurements using improved devices with reduced hysteresis. The model describes well the voltage-controlled motion of the emission spot, and provides a clear picture of the physical mechanism of device op…

Carbon Nanotubes in CompositesNanowire Synthesis and ApplicationsMechanical and Optical Resonators

Local Charge Transport in Two-Dimensional PbSe Nanocrystal Arrays Studied by Electrostatic Force Microscopy

Zonghai Hu、Michael D. Fischbein、Marija Drndić2005-06-21Nano Letters

Two-dimensional PbSe nanocrystal arrays on silicon nitride membranes were investigated using electrostatic force microscopy (EFM) and transmission electron microscopy (TEM). Changes in lattice and transport properties upon annealing in a vacuum were revealed. Local charge transport behavior was directly imaged by EFM…

Quantum Dots Synthesis And PropertiesChalcogenide Semiconductor Thin FilmsForce Microscopy Techniques and Applications

Interactions in blends containing chitosan with functionalized polymers

Cristián Castro、Ligia Gargallo、Ángel Leiva 等 4 位作者2005-06-21Journal of Applied Polymer Science

Abstract The phase behavior of blends containing chitosan with poly(vinyl‐alcohol) (PVA) and poly(2‐hidroxyethyl methacrylate) (P2HEM) was analyzed. Blends were obtained by casting from acetic acid solution (HAc) and 1,1,1,3,3,3 hexafluoro‐2‐propanol (HF2P) and studied by DSC, FT‐IR, and TGA. The phase behavior of the…

Nanocomposite Films for Food PackagingPolymer Nanocomposites and PropertiesConducting polymers and applications