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Model for solute diffusion during rapid solidification of binary alloy in semi-infinite volume

G. L. Buchbinder、P. Martaller2009-12-23arXiv

On the basis of local nonequilibrium approach, the one-dimensional model of the solute diffusion during rapid solidification of the binary alloy in the semi-infinite volume is considered. Within the scope of the model it is supposed that mass transport is described by the telegrapher equation. The basic assumption con…

Materials Science

Nonlinear Elasticity of the Phase Field Crystal Model from the Renormalization Group

Pak Yuen Chan、Nigel Goldenfeld2009-12-23arXiv

The rotationally-covariant renormalization group equations of motion for the density wave amplitudes in the phase field crystal model are shown to follow from a dynamical equation driven by an effective free energy density that we derive. We show that this free energy can be written purely as a function of the strain…

Materials Sciencecond-mat.stat-mech

Dynamic phase transition and hysteresis dispersion law of the kinetic Ising model with next-nearest neighbor interaction

William D. Baez、Trinanjan Datta2009-12-23arXiv

We study the effects of next-nearest neighbor (NNN) interaction on the dynamic phase transition (DPT) and hysteresis loop area law in the two-dimensional ferromagnetic kinetic Ising model. We find that inclusion of the NNN interaction causes the DPT boundary of the NN kinetic Ising model to shift to larger values of m…

cond-mat.stat-mechMaterials Science

Diffusion of Mn through GaAs barrier

J. Adell、I. Ulfat、L. Ilver 等 5 位作者2009-12-23arXiv

Thermally stimulated diffusion of Mn across the (Ga,Mn)As/GaAs interface has been studied by X-ray photoemission. Ga(0.95)Mn(0.05)As layers were capped with GaAs of different thickness 4, 6 and 8ML, and Mn diffusing through the GaAs layers was trapped on the surface by means of amorphous As covering the surface. It wa…

Materials Science

In situ spectroscopic detection ofSMSI effect in a Ni/CeO 2 system: hydrogen-induced burial and dig out of metallic nickel

Alfonso Caballero、Juan P. Holgado、Victor M. Gonzalez-delaCruz 等 6 位作者2009-12-23Chemical Communications

In situ APPES technique demonstrates that the strong metal support interaction effect (SMSI) in the Ni-ceria system is associated with the decoration and burial of metallic particles by the partially reduced support, a phenomenon reversible by evacuation at high temperature of the previously absorbed hydrogen.

Catalysis and Oxidation ReactionsCatalytic Processes in Materials ScienceElectrocatalysts for Energy Conversion

Versatile Solution Phase Triangular Silver Nanoplates for Highly Sensitive Plasmon Resonance Sensing

Denise E. Charles、Damian Aherne、Matthew Gara 等 8 位作者2009-12-23ACS Nano

Solution phase triangular silver nanoplates (TSNP) with versatile tunability throughout the visible-NIR wavelengths are presented as highly sensitive localized surface plasmon refractive index sensors. A range of 20 TSNP solutions with edge lengths ranging from 11 to 200 nm and aspect ratios from 2 to 13 have been stu…

Advanced biosensing and bioanalysis techniquesGold and Silver Nanoparticles Synthesis and ApplicationsPlasmonic and Surface Plasmon Research

Thickness-Dependent Morphologies of Gold on N-Layer Graphenes

Haiqing Zhou、Caiyu Qiu、Zheng Liu 等 9 位作者2009-12-23Journal of the American Chemical Society

We report that gold thermally deposited onto n-layer graphenes interacts differently with these substrates depending on the number layer, indicating the different surface properties of graphenes. This results in thickness-dependent morphologies of gold on n-layer graphenes, which can be used to identify and distinguis…

Surface and Thin Film PhenomenaThermal properties of materialsGraphene research and applications

Doping dependence of the Raman peaks intensity of graphene close to the Dirac point

Cinzia Casiraghi2009-12-23Physical Review B

Here we use pristine graphene samples in order to analyze how the Raman peaks intensity, measured at 2.41 and 1.96 eV excitation energy, changes with the amount of doping. The use of pristine graphene allows investigating the intensity dependence close to the Dirac point. We show that the $G$ peak intensity is indepen…

Advancements in Battery MaterialsGraphene research and applicationsQuantum and electron transport phenomena

Bandlike Motion and Mobility Saturation in Organic Molecular Semiconductors

Simone Fratini、S. Ciuchi2009-12-23Physical Review Letters

We analyze a model that accounts for the inherently large thermal lattice fluctuations associated with the weak van der Waals intermolecular bonding in crystalline organic semiconductors. In these materials the charge mobility generally exhibits a "metalliclike" power-law behavior, with no sign of thermally activated…

Molecular Junctions and NanostructuresOrganic Electronics and PhotovoltaicsOrganic and Molecular Conductors Research

Combining Aurophilic Interactions and Halogen Bonding To Control the Luminescence from Bimetallic Gold−Silver Clusters

Antonio Laguna、Tania Lasanta、José M. López‐de‐Luzuriaga 等 6 位作者2009-12-23Journal of the American Chemical Society

The luminescence in a series of new bimetallic gold-silver vapochromic structures can be efficiently switched among different colors simply by exposure to solvent vapors. The emission color in these systems is controlled by both aurophilic interactions and halogen bonding, which affect the emission energy through diff…

Magnetism in coordination complexesNanocluster Synthesis and ApplicationsOrganometallic Complex Synthesis and Catalysis

A promising new route towards single-molecule magnets based on the oxalate ligand

Gong‐Feng Xu、Qing‐Lun Wang、Patrick Gámez 等 9 位作者2009-12-23Chemical Communications

A unique purely lanthanide-based single-molecule magnet (SMM) with an oxalate bridge has been designed through a rational synthetic approach. This strategy opens up new opportunities to design SMMs through the premeditated choice of a blocking ligand and suitable oxalate bridge.

Porphyrin and Phthalocyanine ChemistryMagnetism in coordination complexesLanthanide and Transition Metal Complexes

Effect of dimensionality on the charge-density wave in few-layer2H-NbSe2

Matteo Calandra、I. I. Mazin、Francesco Mauri2009-12-23Physical Review B

We investigate the charge-density wave (CDW) instability in single and double layers, as well as in the bulk $2{\text{H-NbSe}}_{2}$. We demonstrate that the density functional theory correctly describes the metallic CDW state in the bulk $2{\text{H-NbSe}}_{2}$. We predict that both monolayer and bilayer ${\text{NbSe}}…

Organic and Molecular Conductors Research2D Materials and ApplicationsQuantum, superfluid, helium dynamics

Design of Bis-spiropyran Ligands as Dipolar Molecule Receptors and Application to in Vivo Glutathione Fluorescent Probes

Na Shao、Jianyu Jin、Hao Wang 等 7 位作者2009-12-23Journal of the American Chemical Society

Despite considerable efforts toward the development of various sophisticated spiropyrans for metal ion sensing, less attention has been paid to organic molecule sensing. One of the major difficulties for detection of organic molecules using a spiropyran is the weak and nonspecific interaction between the spiropyran an…

Photoreceptor and optogenetics researchMolecular Sensors and Ion DetectionPhotochromic and Fluorescence Chemistry

Close packing density of polydisperse hard spheres

Robert S. Farr、Robert D. Groot2009-12-23OpenAlex

The most efficient way to pack equally sized spheres isotropically in three dimensions is known as the random close packed state, which provides a starting point for many approximations in physics and engineering. However, the particle size distribution of a real granular material is never monodisperse. Here we presen…

Pickering emulsions and particle stabilizationMaterial Dynamics and PropertiesPhase Equilibria and Thermodynamics

Grain Boundary Migration in Metals

Günter Gottstein、L.S. Shvindlerman2009-12-23OpenAlex

A major goal of materials science is to create new engineering materials and optimize their cost and performance. Understanding how adjacent materials behave at their borders is an essential part of this process. Grain boundaries are the longest-known crystal defects, but although they were discovered in the mid-eight…

Microstructure and mechanical properties

Plasmonics in graphene at infrared frequencies

Marinko Jablan、Hrvoje Buljan、Marin Soljačić2009-12-23OpenAlex

We point out that plasmons in doped graphene simultaneously enable low losses and significant wave localization for frequencies below that of the optical phonon branch $\ensuremath{\hbar}{\ensuremath{\omega}}_{Oph}\ensuremath{\approx}0.2\text{ }\text{eV}$. Large plasmon losses occur in the interband regime (via excita…

Graphene research and applicationsPlasmonic and Surface Plasmon ResearchGold and Silver Nanoparticles Synthesis and Applications

Investigation of partial discharge in single void and multi-voids using data mining technique

Kai Xian Lai、B.T. Phung、T.R. Blackburn2009-12-22Australasian Universities Power Engineering Conference

Partial discharge (PD) is a phenomenon that commonly occurs in the insulation of power system equipment. In this paper, PDs occurring in a single void and multi-voids were investigated. Air voids at atmospheric pressure were injected into cylindrical epoxy resin blocks to create test samples with single void and multi…

Power Transformer Diagnostics and InsulationHigh voltage insulation and dielectric phenomenaElevator Systems and Control

A green epoxidation system with poly(4‐vinylpyridine) microsphere‐supported molybdenum catalyst

Lijing Cao、Mu Yang、Ge Wang 等 5 位作者2009-12-22Journal of Polymer Science Part A Polymer Chemistry

Abstract The immobilization of molybdenum (Mo) compounds on poly(4‐vinylpyridine) (P4VP) microspheres for catalytic epoxidation was reported. P4VP‐supported Mo compounds were highly efficient and selective for the epoxidation of cis ‐cyclooctene using hydrogen peroxide (H 2 O 2 ) as oxygen source. When ethanol was use…

Catalysis and Hydrodesulfurization StudiesPolyoxometalates: Synthesis and ApplicationsCarbon dioxide utilization in catalysis

Highly sensitive MOS photodetector with wide band responsivity assisted by nanoporous anodic aluminum oxide membrane

Yung-Ting Chen、Tzu-Huan Cheng、Chung-Liang Cheng 等 7 位作者2009-12-22Optics Express

A new approach for developing highly sensitive MOS photodetector based on the assistance of anodic aluminum oxide (AAO) membrane is proposed, fabricated, and characterized. It enables the photodetector with the tunability of not only the intensity but also the range of the response. Under a forward bias, the response…

Nanowire Synthesis and ApplicationsSemiconductor materials and devicesAnodic Oxide Films and Nanostructures

Application of wavelet transform to study partial discharge in XLPE sample

Guomin Luo、Daming Zhang2009-12-22Australasian Universities Power Engineering Conference

Partial discharge (PD) plays a paramount role in determining system reliability. But noise is always a major limitation of PD measurement. Many research work shows that wavelet transform (WT) has a potential to extract PD pulse from noise environment. De-noising algorithm based on WT has three steps: decomposition, th…

Image and Signal Denoising MethodsHigh voltage insulation and dielectric phenomenaPower Transformer Diagnostics and Insulation