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Role of a universal branch-point energy at ZnO interfaces

Martin Allen、S. M. Durbin2010-10-07Physical Review B

Contemporary interface state models were tested using the barrier heights of laterally homogeneous ZnO Schottky contacts. A strong correlation was found between barrier height and metal Miedema electronegativity, indicating that interfacial chemical bonding may play an important role in the charge transfer at metal-Zn…

ZnO doping and propertiesSemiconductor materials and interfacesElectronic and Structural Properties of Oxides

Shrinking Core Model for Knudsen Diffusion-Limited Atomic Layer Deposition on a Nanoporous Monolith with an Ultrahigh Aspect Ratio

Hoo-Yong Lee、Cheng Jin An、Shan Ji Piao 等 6 位作者2010-10-07The Journal of Physical Chemistry C

ZnO was grown on nanoporous alumina monoliths by atomic layer deposition (ALD) from diethylzinc (DEZ) and water. The alumina monolith has a cylindrical shape with a length of 6.2 ± 2.0 mm and a diameter of 1.93 ± 0.78 mm, of which the average pore diameter and specific surface area are 8.9 nm and 256 m 2 /g, respectiv…

Catalytic Processes in Materials ScienceSemiconductor materials and devicesMesoporous Materials and Catalysis

Surface‐enhanced Raman spectroscopy in living plant using triplex AuAgC core–shell nanoparticles

Aiguo Shen、Jingzhe Guo、Wei Xie 等 6 位作者2010-10-07Journal of Raman Spectroscopy

Abstract This paper presents, for the first time, noninvasive imaging of a livingplant using biocompatible carbon‐encapsulated AuAg nanoparticles (NPs) using micro‐Raman spectroscopy (MRS). A convenient and controllable hydrothermal synthetic route was developed to synthesize the layer‐by‐layer triplex AuAgC core–s…

Gold and Silver Nanoparticles Synthesis and ApplicationsQuantum Dots Synthesis And PropertiesCarbon and Quantum Dots Applications

Phase Behavior of Neat Triblock Copolymers and Copolymer/Homopolymer Blends Near Network Phase Windows

Maëva S. Tureau、Lixia Rong、Benjamin S. Hsiao 等 4 位作者2010-10-07Macromolecules

The phase behavior of poly(isoprene- b -styrene- b -methyl methacrylate) (ISM) copolymers near the styrene-rich network phase window was examined through the use of neat triblock copolymers and copolymer/homopolymer blends. Both end-block and middle-block blending protocols were employed using poly(isoprene) (PI), pol…

Advanced Polymer Synthesis and CharacterizationBlock Copolymer Self-AssemblyMachine Learning in Materials Science

Micro-structured Materials and Mechanical Cues in 3D Collagen Gels

James B. Phillips、Robert A. Brown2010-10-07Methods in molecular biology

Collagen gels provide a versatile and widely used substrate for three-dimensional (3D) cell culture. Here we describe how cell-seeded Type-I collagen gels can be adapted to provide powerful 3D models to support a wide range of research applications where cell/substrate alignment, density, stiffness/compliance, and str…

Cellular Mechanics and Interactions3D Printing in Biomedical ResearchCollagen: Extraction and Characterization

Dendritic Arenethiol-Based Capping Strategy for Engineering Size and Surface Reactivity of Gold Nanoparticles

Hong Yan、Christina Wong、A. Chianese 等 7 位作者2010-10-07Chemistry of Materials

The report describes a strategy for the synthesis of gold nanoparticles for which size and surface reactivity of the particles are controlled by the molecular sizes of dendritic arenethiols (DAT) as capping agents. This strategy exploits two important attributes of the DAT molecules: one involving the utilization of t…

Gold and Silver Nanoparticles Synthesis and ApplicationsDendrimers and Hyperbranched PolymersNanomaterials for catalytic reactions

Differentiation of Mouse Embryonic Stem Cells in Self-Assembling Peptide Scaffolds

Núria Marí‐Buyé、Carlos E. Semino2010-10-07Methods in molecular biology

Here, we describe the capacity of mouse embryonic stem cells (mESCs) to differentiate into osteoblast-like cells in a three-dimensional (3D) self-assembling peptide scaffold, a synthetic nanofiber biomaterial with future applications in regenerative medicine. We have previously demonstrated that classical tissue cultu…

RNA Interference and Gene Delivery3D Printing in Biomedical ResearchSupramolecular Self-Assembly in Materials

Microcellular Foaming of Layered Double Hydroxide−Polymer Nanocomposites

Antonio B. Martínez、Vera Realinho、Marcelo Antunes 等 5 位作者2010-10-07Industrial & Engineering Chemistry Research

Microcellular foams of polystyrene (PS), poly(styrene-co-acrylonitrile) (SAN), and poly(methyl methacrylate) (PMMA) having organically modified layered double hydroxides (LDH) were prepared using a high-pressure CO 2 dissolution foaming process and characterized both structurally and thermo-mechanically. The saturatio…

biodegradable polymer synthesis and propertiesCarbon dioxide utilization in catalysisPolymer Foaming and Composites

Valence change of europium inEuFe2As1.4P0.6and compressedEuFe2As2and its relation to superconductivity

Liling Sun、Jing Guo、Genfu Chen 等 16 位作者2010-10-07Physical Review B

Superconductivity can be realized in Eu-containing pnictides by applying chemical (internal) and physical (external) pressure, the intrinsic physical mechanism of which attracts much attention in the studies of pnictide superconductors. Here we present the experimental evidence for the pressure-induced valence change…

Rare-earth and actinide compoundsIron-based superconductors researchIntellectual Capital and Performance Analysis

New Efficient Intercalation of Bioactive Molecules into Layered Double Hydroxide Materials by Solid-State Exchange: An in Situ XRPD Study

Marco Milanesio、Eleonora Conterosito、Davide Viterbo 等 5 位作者2010-10-07Crystal Growth & Design

A new soft and fast solid state reaction is exploited for the preparation of exchanged layered double hydroxide materials and, in particular, for intercalating bioactive molecules. The characterization of the nanocomposite, carried out by crystallographic and thermogravimetric techniques, revealed that this synthesis…

Polyoxometalates: Synthesis and ApplicationsLayered Double Hydroxides Synthesis and ApplicationsInorganic Chemistry and Materials

Superstrong Low‐Resistant Carbon Nanotube–Carbide–Metal Nanocontacts

Ming‐Sheng Wang、Dmitri Golberg、Yoshio Bando2010-10-07Advanced Materials

An in-situ TEM nanowelding process via Joule heating was used to achieve superstrong CNT-carbide-metal contacts, in which all shells of a multiwalled CNT contact the tungsten wire through the intermediate tungsten carbide layer. A remarkably high tensile strength (5–15GPa) and ultralow resistance(<1 kΩ) were documente…

Carbon Nanotubes in CompositesGraphene research and applicationsDiamond and Carbon-based Materials Research

High-performance uncooled amorphous silicon VGA and XGA IRFPA with 17μm pixel-pitch

J. L. Tissot、Sebastien Tinnes、A. Durand 等 6 位作者2010-10-07Proceedings of SPIE, the International Society for Optical Engineering/Proceedings of SPIE

The high level of accumulated expertise by ULIS and CEA/LETI on uncooled microbolometers made from amorphous silicon with 45&mu;m, 35&mu;m and 25&mu;m, enables ULIS to develop VGA and XGA IRFPA formats with 17&mu;m pixel-pitch to fulfill every applications. These detector keeps all the recent innovations developed on…

Thin-Film Transistor TechnologiesTransition Metal Oxide NanomaterialsCCD and CMOS Imaging Sensors

Dynamical current-current correlation of the hexagonal lattice and graphene

Tobias Stauber、G. Gómez-Santos2010-10-07Physical Review B

We discuss the dynamical current-current correlation function of the hexagonal lattice using a local current operator defined on a continuum-replica model of the original lattice model. In the Dirac approximation, the correlation function can be decomposed into a parallel and perpendicular contribution. We show that t…

Graphene research and applicationsQuantum and electron transport phenomenaTheoretical and Computational Physics

Orbital momentum Hall effect inp-doped graphane

I. V. Tokatly2010-10-07Physical Review B

It is shown that an electric field applied to $p$-doped graphane generates a dissipationless orbital momentum Hall current. In the clean limit the corresponding Hall conductivity is independent of the concentration of holes. The Hall effect is related to the $2\ensuremath{\pi}$-Berry phase accumulated when heavy and l…

Carbon Nanotubes in CompositesGraphene research and applicationsQuantum and electron transport phenomena

Densification and Crystallization of Nonstoichiometric Cordierite Glass with Excess MgO Synthesized from Kaolin and Talc

Banjuraizah Johar、Hasmaliza Mohamad、Zainal Arifin Ahmad2010-10-07Journal of the American Ceramic Society

Densification and crystallization behaviors of nonstoichiometric cordierite synthesized from minerals through the glass route are reported in this paper. DTA of glass powder was conducted under isothermal and nonisothermal conditions. The activation energy was calculated from the dilatometry test at constant heating r…

Advanced ceramic materials synthesisGlass properties and applicationsMicrowave Dielectric Ceramics Synthesis

Control of the Microstructure and Crystalline Orientation of ZnO Films on a Seed-free Glass Substrate by Using a Spin-Spray Method

Hajime Wagata、Naoki Ohashi、Takaaki Taniguchi 等 6 位作者2010-10-07Crystal Growth & Design

ZnO films on nonseeded substrates with controllable microstructures and crystal orientations were fabricated with a spin-spray method employing trisodium citrate as an additive. The microstructure of the films was made to change from a rod array to a dense film by increasing the trisodium citrate concentration in the…

ZnO doping and propertiesCopper-based nanomaterials and applicationsGa2O3 and related materials

Solution-Electrospun Isotactic Polypropylene Fibers: Processing and Microstructure Development during Stepwise Annealing

Chi Wang、Tsai-Chuan Hsieh、Yong-Wen Cheng2010-10-07Macromolecules

Isotactic polypropylene (iPP) fibers with diameters between 0.3 and 1.2 μm were successfully produced from high-temperature electrospinning solutions using a jacket-type heat exchanger to maintain the solution temperature, an infrared emitter to control the environmental temperature, and a laser heating device to heat…

Advanced Sensor and Energy Harvesting MaterialsPolymer crystallization and propertiesElectrospun Nanofibers in Biomedical Applications

Brightening of Triplet Dark Excitons by Atomic Hydrogen Adsorption in Single-Walled Carbon Nanotubes Observed by Photoluminescence Spectroscopy

Kotaro Nagatsu、Shohei Chiashi、Satoru Konabe 等 4 位作者2010-10-07Physical Review Letters

Adsorption and desorption of atomic hydrogen on single-walled carbon nanotubes were observed by photoluminescence spectroscopy. A satellite peak appeared at the lower energy side of the E11 photoluminescence emission peak after exposure to atomic hydrogen and then disappeared after annealing at 300 °C in vacuum. The e…

Carbon Nanotubes in CompositesGraphene research and applicationsDiamond and Carbon-based Materials Research

Electric Field Control of Spin Rotation in Bilayer Graphene

Paolo Michetti、Patrik Recher、Giuseppe Iannaccone2010-10-07Nano Letters

The manipulation of the electron spin degree of freedom is at the core of the spintronics paradigm, which offers the perspective of reduced power consumption, enabled by the decoupling of information processing from net charge transfer. Spintronics also offers the possibility of devising hybrid devices able to perform…

Graphene research and applicationsQuantum and electron transport phenomenaMolecular Junctions and Nanostructures

Electronic conductivity of Ce0.8Gd0.2−xPrxO2−δ and influence of added CoO

Kerstin Schmale、Mariano Grünebaum、Marijn Janssen 等 6 位作者2010-10-07physica status solidi (b)

Abstract Doped ceria and ceria based solid oxide solutions show a unique combination of oxygen ion mobility, electronic conductivity, and high catalytic activity for redox reactions. In this work, the minority conductivity of electrons has been measured directly as a function of the composition of ceria–praseodymia ba…

Catalytic Processes in Materials ScienceAdvancements in Solid Oxide Fuel CellsElectronic and Structural Properties of Oxides