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Nanohybrids of Magnetic Iron-Oxide Particles in Hydrophobic Organoclays for Oil Recovery

Ru-Siou Hsu、Wen‐Hsin Chang、Jiang‐Jen Lin2010-04-19ACS Applied Materials & Interfaces

Nanohybrids with magnetic iron-oxide nanoparticles (FeNPs) embedded in the multilayered silicate clay were synthesized by in situ Fe(2+)/Fe(3+) coprecipitation. The natural clay, sodium montmorillonite (Na(+)-MMT), was first modified with hydrophobic poly(oxypropylene)amine salts (POP at 2000 and 4000 g/mol M(w)). The…

Enhanced Oil Recovery TechniquesPolymer Nanocomposites and PropertiesIron oxide chemistry and applications

Facile Synthesis, Shape Evolution, and Photocatalytic Activity of Truncated Cuprous Oxide Octahedron Microcrystals with Hollows

Hui Yang、Zhi‐Hong Liu2010-04-19Crystal Growth & Design

Microcrystals of cuprous oxide (Cu 2 O) samples exhibiting different morphologies such as rods, hexapods, octahedra, and truncated octahedra with hollows were synthesized via a facile hydrothermal method and were then characterized by X-ray powder diffraction (XRD) and scanning electron microscopy (SEM). It was observ…

ZnO doping and propertiesCopper-based nanomaterials and applicationsElectronic and Structural Properties of Oxides

Unzipping of Functionalized Multiwall Carbon Nanotubes Induced by STM

María C. Paiva、Wei Xu、M. Fernanda R. P. Proença 等 6 位作者2010-04-19Nano Letters

Carbon nanotubes (CNTs), functionalized by a cycloaddition reaction, were studied by ultrahigh vacuum scanning tunneling microscopy (STM). The STM images provided evidence for partial or total unzipping of the outer CNT layer. The formation of graphene ribbons was triggered by the STM tip, under specific operating con…

Carbon Nanotubes in CompositesGraphene research and applicationsNanopore and Nanochannel Transport Studies

A magnetoelectric memory cell with coercivity state as writing data bit

Zheng Li、Jing Wang、Yuanhua Lin 等 4 位作者2010-04-19Applied Physics Letters

Commercial magnetic recording media employ magnetic-field-induced two different magnetization states ±M to write data. In this paper, we present a magnetic memory cell in which electric-field-induced two different coercive-field Hc states (i.e., low-Hc and high-Hc) rather than ±M are served as writing data bits. A mul…

Magnetic properties of thin filmsFerroelectric and Piezoelectric MaterialsMultiferroics and related materials

Achiral Bent-Core Molecules with a Series of Linear or Branched Carbosilane Termini: Dark Conglomerate Phases, Supramolecular Chirality and Macroscopic Polar Order

Yongqiang Zhang、Ute Baumeister、Carsten Tschierske 等 5 位作者2010-04-19Chemistry of Materials

New organic−inorganic hybrid materials that combine a bent π-conjugated aromatic core with one linear or branched carbosilane unit have been synthesized and investigated, with respect to their self-assembly in liquid crystalline (LC) phases, by means of polarizing microscopy, differential scanning calorimetry (DSC), X…

Liquid Crystal Research AdvancementsSynthesis and Properties of Aromatic CompoundsMolecular spectroscopy and chirality

The Potential of Microstructural Optimization in Metal/Oxide Catalysts: Higher Intrinsic Activity of Copper by Partial Embedding of Copper Nanoparticles

Malte Behrens、Andreas Furche、Igor Kasatkin 等 9 位作者2010-04-19ChemCatChem

The activity of Cu/ZnO/Al2O3 catalysts for methanol synthesis is determined by the microstructural arrangement of the oxides among other factors. A large metal/oxide interface area seems to enhance the intrinsic activity of Cu. A novel type of Cu/ZnO/Al2O3 catalyst demonstrates the potential of this positive effect, w…

Catalytic Processes in Materials ScienceCatalysts for Methane ReformingCopper-based nanomaterials and applications

A Chemical Route to High Molecular Weight Vegetable Oil-Based Polyhydroxyalkanoate

Zoran S. Petrovìć、Jelena Milić、Yijin Xu 等 4 位作者2010-04-19Macromolecules

To our knowledge, this is the first description of the material properties of a high molecular weight linear polyester prepared from the methyl ester of 9-hydoxynonanoic acid (HNME). The HNME of high purity was prepared by ozonolysis of castor oil, followed by methanolysis of triglycerides. High molecular weight polye…

Polymer crystallization and propertiesPolymer Nanocomposites and Propertiesbiodegradable polymer synthesis and properties

Thermoelectric properties of polycrystalline In4Se3 and In4Te3

Xun Shi、Jung Y. Cho、James R. Salvador 等 5 位作者2010-04-19Applied Physics Letters

High thermoelectric performance of a single crystal layered compound In4Se3 was reported recently. We present here an electrical and thermal transport property study over a wide temperature range for polycrystalline samples of In4Se3 and In4Te3. Our data demonstrate that these materials are lightly doped semiconductor…

Advanced Thermoelectric Materials and DevicesChalcogenide Semiconductor Thin FilmsThermal Radiation and Cooling Technologies

Effects of cantilever buckling on vector piezoresponse force microscopy imaging of ferroelectric domains in BiFeO3 nanostructures

R. Nath、Seungbum Hong、Jeffrey A. Klug 等 7 位作者2010-04-19Applied Physics Letters

Systematic studies are presented on the effects of cantilever buckling in vector piezoresponse force microscopy (V-PFM) imaging of polarization domains in thin-film based (001)-oriented BiFeO3 nanostructures, as observed through the coupling of out-of-plane and in-plane PFM images. This effect is a strong function of…

Ferroelectric and Piezoelectric MaterialsMultiferroics and related materialsForce Microscopy Techniques and Applications

Hyperfine magnetic field on iron atoms and Co–Fe disordering in Co2FeSi

Vadim Ksenofontov、M. Wójcik、S. Wurmehl 等 7 位作者2010-04-19Journal of Applied Physics

The Heusler compound Co2FeSi is a prospective half-metallic material for spintronic applications. Defects and antisite disordering play a crucial role among the factors reducing spin polarization in such materials. To clarify effects of possible off-stoichiometry, a continuous series of model solid solutions Co3−xFexS…

Rare-earth and actinide compoundsMXene and MAX Phase MaterialsHeusler alloys: electronic and magnetic properties

Origin of antiferromagnetism in CoO: A density functional theory study

Hui-Xiong Deng、Jingbo Li、Shu-Shen Li 等 6 位作者2010-04-19Applied Physics Letters

We have investigated the origin of antiferromagnetism of CoO in the rocksalt structure using spin-polarized density functional theory calculations. We find that in the rocksalt structure, the superexchange interaction between the occupied and unoccupied eg states plays the dominant role, which leads to an antiferromag…

Physics of Superconductivity and MagnetismZnO doping and propertiesMagnetic and transport properties of perovskites and related materials

Syntheses of Zinc Oxide and Zinc Hydroxide Single Nanosheets

Ozge Altuntasoglu、Yuki Matsuda、Shintaro Ida 等 4 位作者2010-04-19Chemistry of Materials

In this study, we present the preparation of zinc oxide (ZnO) and zinc hydroxide (Zn(OH) 2 ) single nanosheets for the first time. ZnO nanosheet was prepared by delamination of layered ZnO film intercalated with the dodecyl sulfate (DS − ) ion which was synthesized by cathodic electrodeposition process. In this case,…

ZnO doping and propertiesSupercapacitor Materials and FabricationGas Sensing Nanomaterials and Sensors

Giant dielectric constant dominated by Maxwell–Wagner relaxation in Al2O3/TiO2 nanolaminates synthesized by atomic layer deposition

Wei Li、Orlando Auciello、Ramesh Nath Premnath 等 4 位作者2010-04-19Applied Physics Letters

Nanolaminates consisting of Al2O3 and TiO2 oxide sublayers were synthesized by using atomic layer deposition to produce individual layers with atomic scale thickness control. The sublayer thicknesses were kept constant for each multilayer structure, and were changed from 50 to 0.2 nm for a series of different samples.…

Ferroelectric and Piezoelectric MaterialsMicrowave Dielectric Ceramics SynthesisDielectric properties of ceramics

Preparation of cereal-like Y V O4:Ln3 +(Ln = Sm, Eu, Tb, Dy) for high quantum efficiency photoluminescence

Liping Li、Minglei Zhao、Wenming Tong 等 6 位作者2010-04-19Nanotechnology

In this work, preparation of cereal-like architectures Y V O(4) and Y V O(4):Ln(3 + ) (Ln = Eu, Sm, Dy, Tb) was initiated using a hydrothermal method. During the formation reaction, Na(3)C(6)H(5)O(7).2H(2)O was used to effectively adjust the concentration of Y(3 + ) species necessary for cereal-like architectures. Pha…

Luminescence Properties of Advanced MaterialsTransition Metal Oxide NanomaterialsNuclear materials and radiation effects

Anisotropic SmCo5 nanoflakes by surfactant-assisted high energy ball milling

Bai Cui、A.M. Gabay、W. F. Li 等 6 位作者2010-04-19Journal of Applied Physics

Crystallographically anisotropic SmCo5 nanoflakes were fabricated directly by one-step surfactant-assisted high energy ball milling (HEBM) of Sm17Co83 ingot powders for 5 h in heptane and oleic acid (OA) without preprocessing or further annealing. The SmCo5 nanoflakes have a strong [001] out-of-plane texture. The thic…

Magnetic properties of thin filmsRare-earth and actinide compoundsMagnetic Properties of Alloys

Immobilizing Water-Soluble Dendritic Electron Donors and Electron Acceptors—Phthalocyanines and Perylenediimides—onto Single Wall Carbon Nanotubes

Uwe Hahn、Sarah Engmann、Christian Oelsner 等 6 位作者2010-04-19Journal of the American Chemical Society

The complementary use of spectroscopy and microscopy sheds light onto mutual interactions between semiconducting single wall carbon nanotubes (SWNT) and either a strong dendritic electron acceptor-perylenediimide-or a strong dendritic electron donor-phthalocyanine. Importantly, the stability of the perylenediimide/SWN…

Organic Electronics and PhotovoltaicsCarbon Nanotubes in CompositesMolecular Junctions and Nanostructures

CryoEM structure of Hsp104 and its mechanistic implication for protein disaggregation

Sukyeong Lee、Bernhard Sielaff、Jungsoon Lee 等 4 位作者2010-04-19Proceedings of the National Academy of Sciences

Hsp104 is a ring-forming AAA+ machine that recognizes both aggregated proteins and prion-fibrils as substrates and, together with the Hsp70 system, remodels substrates in an ATP-dependent manner. Whereas the ability to disaggregate proteins is dependent on the Hsp104 M-domain, the location of the M-domain is controver…

Protein Structure and DynamicsHeat shock proteins researchEnzyme Structure and Function

Enhanced generation of single optically active spins in diamond by ion implantation

Boris Naydenov、V. Richter、Johannes Beck 等 10 位作者2010-04-19Applied Physics Letters

The nitrogen-vacancy (NV) centers in diamond are amongst the most promising candidates for quantum information applications. Up to now the creation of such defects was highly probabilistic, requiring many copies of the nanodevice. Here we show that by employing a two step implantation process which includes low dose N…

Metal and Thin Film MechanicsDiamond and Carbon-based Materials ResearchIon-surface interactions and analysis

Structures and Photoluminescent Properties of the Lanthanide Coordination Complexes with Hydroxyquinoline Carboxylate Ligands

Rui Feng、Feilong Jiang、Mingyan Wu 等 6 位作者2010-04-19Crystal Growth & Design

A series of luminescent lanthanide coordination complexes, [Eu 2 (hqc) 6 (H 2 O) 4 ]·8H 2 O ( 1 ), [Ln 2 (hqc) 6 (H 2 O) 2 (DMF) 2 ]·2H 2 O (Ln = Eu ( 2 ), Dy ( 3 ), Ho ( 4 )), and [Ln 2 (hqc) 6 (H 2 O) 4 ]·2H 2 O·2DMF (Ln = Ce ( 5 ), La ( 6 ), Pr ( 7 ); Hhqc =2-hydroxyquinoline-4-carboxylic acid), have been synthesiz…

Metal-Organic Frameworks: Synthesis and ApplicationsMagnetism in coordination complexesLanthanide and Transition Metal Complexes

Towards a Quantitative Description of Solid Electrolyte Conductance Switches

Monica Morales-Masis、Hans-Dieter Wiemhofer、Jan M. van Ruitenbeek2010-04-19arXiv

We present a quantitative analysis of the steady state electronic transport in a resistive switching device. The device is composed of a thin film of Ag$_{2}$S (solid electrolyte) contacted by a Pt nano-contact acting as ion-blocking electrode, and a large area Ag reference electrode. When applying a bias voltage both…

Materials Science