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Influence of gas phase composition on the Hot Corrosion of steels and nickel-based alloys beneath a (Ca-Na-K)-sulfate mixture containing PbSO4 and ZnSO4

M. Spiegel2000-05-01Materials and Corrosion

The corrosion of steels and of nickel-based alloys was studied in exposure experiments at 600 °C beneath a molten CaSO4-K2SO4-Na2SO4-PbSO4-ZnSO4 sulphate mixture in N2-5 vol.% O2 with and without additions of 1000 vppm HCl, 1000 vppm SO2 and 1000 vppm HCl in combination with 250 vppm SO2. In the N2-5 vol.% O2 atmosphe…

Corrosion Behavior and InhibitionMetallurgical Processes and ThermodynamicsConcrete Corrosion and Durability

Anisotropic electrical transport in epitaxial La2/3Ca1/3MnO3 thin films

V. S. Amaral、A.A.C.S. Lourenço、João P. Araújo 等 10 位作者2000-05-01Journal of Applied Physics

Epitaxial thin films of La0.62±0.05Ca0.33±0.02MnO3−δ were grown by laser ablation on SrTiO3. On (100) substrates the films grow with the larger c axis perpendicular to the plane. The films deposited on (110) SrTiO3 grow with both the c (long) axis and a (or b, short) axis in the plane of the film. The electrical resis…

Magnetic and transport properties of perovskites and related materialsRare-earth and actinide compoundsAdvanced Condensed Matter Physics

11.2: Zenithal Bistable Device (ZBD™) Suitable for Portable Applications

E. L. Wood、G. P. Bryan‐Brown、P. Brett 等 6 位作者2000-05-01SID Symposium Digest of Technical Papers

Abstract Zenithal Bistable display devices have been made which are compatible in size and functionality with current mobile phone or pager displays. Radical improvements in the viewing characteristics particularly in reflective mode are shown. Furthermore this paper describes: low voltage operation; fast latching tim…

Liquid Crystal Research AdvancementsAdvanced Optical Imaging TechnologiesSemiconductor Lasers and Optical Devices

Configuration Optimization of a Reflective Bistable-Twisted-Nematic Cell for High-Contrast Operation

Gi‐Dong Lee、Gihong Kim、Tae‐Hoon Yoon 等 4 位作者2000-05-01Japanese Journal of Applied Physics

In this study, the configuration of a reflective bistable-twisted-nematic (BTN) liquid-crystal cell is optimized for high contrast and high brightness operation. We searched for the optimum optical parameters of a reflective BTN cell by calculating its optical performances at three wavelengths; red, green, and blue. B…

Liquid Crystal Research AdvancementsPhotonic Crystals and ApplicationsAdvanced Optical Imaging Technologies

Low temperature oxidation and selective etching of chemical vapor deposition a-SiC:H films

Mikhaı̈l R. Baklanov、M. Van Hove、G. Mannaert 等 7 位作者2000-05-01Journal of Vacuum Science & Technology B Microelectronics and Nanometer Structures Processing Measurement and Phenomena

Chemical vapor deposition silicon carbide films are considered as a perspective hard mask and stop layer in advanced dry etch technology because of the high chemical and plasma stability. However the a-SiC:H film should be etched away after technological use. In this case the high chemical stability of the a-SiC:H fil…

ZnO doping and propertiesPlasma Diagnostics and ApplicationsCopper Interconnects and Reliability

Solution multinuclear (31P,111Cd,77Se) magnetic resonance studies of cadmium complexes of heterocyclic aromatic thiones and the structure of [tetrakis(2(1H)-pyridinethione)cadmium] nitrate, [Cd(C5H5NS)4](NO3)2

Umarani Rajalingam、Philip A. W. Dean、Hilary A. Jenkins2000-05-01Canadian Journal of Chemistry

The complex salts CdL 4 (O 3 SCF 3 ) 2 (L = 2(1H)-pyridinethione (Py2SH), 4(1H)-pyridinethione (Py4SH), or 2(1H)-quinolinethione (Q2SH)) have been synthesized by the stoichiometric reaction of Cd(O 3 SCF 3 ) 2 and the appropriate thione. Both ambient-temperature 13 C and reduced-temperature 111 Cd NMR of CdL 4 (O 3 SC…

Metal complexes synthesis and propertiesMagnetism in coordination complexesOrganic and Molecular Conductors Research

Analysis of Rubber Particles Produced by the Solid State Shear Extrusion Pulverization Process

Ecevit Bilgili、Hamid Arastoopour、Barry Bernstein2000-05-01Rubber Chemistry and Technology

Abstract Vulcanized natural rubber was pulverized using a single screw extruder in a non-cryogenic Solid State Shear Extrusion (SSSE) process where rubber granulates were subjected to high compressive and shear stresses. The produced particles had diameters ranging from 40 to 1700 µm. Reprocessing of the produced powd…

Polymer crystallization and propertiesPolymer Nanocomposites and Propertiesbiodegradable polymer synthesis and properties

Addition and Metathesis Reactions of Zirconium and Hafnium Imido Complexes

J.L. Thorman、Ilia A. Guzei、Victor G. Young 等 4 位作者2000-05-01Inorganic Chemistry

The zirconium and hafnium imido metalloporphyrin complexes (TTP)M = NArtPr (TTP = meso-5,10,15,20-tetra-p-tolylporphyrinato dianion; M = Zr (1), Hf; AriPr = 2,6-diisopropylphenyl) were used to mediate addition reactions of carbonyl species and metathesis of nitroso compounds. The imido complexes react in a stepwise ma…

Porphyrin and Phthalocyanine ChemistrySynthetic Organic Chemistry MethodsMetal-Catalyzed Oxygenation Mechanisms

Chiral liquid crystalline m-nitrotolans and tolans: synthesis and mesomorphic properties

Aloir A. Merlo、Jose E. Braun、Ursula Bohlke Vasconcelos 等 5 位作者2000-05-01Liquid Crystals

Two homologous series, 4'-(4-n-alkoxybenzoyloxy)-4-substituted 3-nitrotolans (Ia-d) and 4'-(4-n-alkoxybenzoyloxy)-4-substituted tolans (IIa-c), with substituents (S)-2-methyl-1-butyl and n-alkyl, were synthesized by Sonogashira's coupling. Their mesomorphic behaviour is reported. The thermal stability of the series II…

Liquid Crystal Research AdvancementsPlant Reproductive BiologyMolecular spectroscopy and chirality

Anisotropy determination in epitaxial Sm–Co/Fe exchange springs

Michael J. Pechan、Nienchtze Teng、Jason-Dennis Stewart 等 8 位作者2000-05-01Journal of Applied Physics

We report in-plane anisotropy in epitaxial Sm–Co(x)/Fe(y) bilayers as determined by ferromagnetic resonance (FMR). Four samples, (x,y)=(35,30) and (20, 20) nm each on MgO (110) and (100) substrates, have been prepared via magnetron sputtering. The two substrate orientations result in twofold and fourfold Sm–Co symmetr…

Magnetic properties of thin filmsMagnetic Properties and ApplicationsMagnetic Properties of Alloys

Cation-cation complexes of PuO2+and NpO2+with Th4+and UO22+

Ν. J. Stoyer、Darleane C. Hoffman、R.J. Silva2000-05-01Radiochimica Acta

Cation-cation complexes of NpO 2 + and PuO 2 + with UO 2 2+ and Th 4+ were studied using laser-induced photoacoustic spectroscopy (LIPAS). An equilibrium constant of 2.4±0.2 M -1 was measured at an ionic strength of 6.0 M for the NpO 2 + · UO 2 2+ complex which is in good agreement with previous measurements using con…

Atmospheric chemistry and aerosolsSpectroscopy and Laser ApplicationsNuclear Materials and Properties

Spin fluctuations in the spin-Peierls compoundMEM(TCNQ)2studied using muon spin relaxation

Brendon W. Lovett、Stephen J. Blundell、F. L. Pratt 等 7 位作者2000-05-01Physical review. B, Condensed matter

We report a muon spin relaxation $(\ensuremath{\mu}\mathrm{SR})$ investigation of the organic spin-Peierls compound $\mathrm{MEM}(\mathrm{TCNQ}{)}_{2}$ at temperatures down to 39 mK. We have observed a slowing down of the electronic spins as the spin-Peierls gap widens at temperatures below the spin-Peierls transition…

Physics of Superconductivity and MagnetismQuantum and electron transport phenomenaOrganic and Molecular Conductors Research

Ultrathin diamond-like carbon coatings used for reduction of pole tip recession in magnetic tape heads

William W. Scott、Bharat Bhushan、A. V. Lakshmikumaran2000-05-01Journal of Applied Physics

Diamond-like carbon (DLC) coatings were deposited using a commercial direct ion beam deposition technique on thin-film Al2O3–TiC inductive write heads. The coating thicknesses used were 5, 10, and 20 nm. Accelerated wear tests were conducted with metal particle tapes in a linear tape drive. Atomic force microscopy was…

Metal and Thin Film MechanicsDiamond and Carbon-based Materials ResearchLubricants and Their Additives

Novel method for preparing palladium membranes by photocatalytic deposition

Liqun Wu、Nanping Xu、Jun Shi2000-05-01AIChE Journal

Abstract An ultrathin palladium film on a porous TiO 2 ceramic membrane was successfully synthesized by a novel photocatalytic deposition (PCD) method. The mechanism was interpreted by the photocatalytic reaction between the surface of the TiO 2 semiconductor and the Pd(II) solution. Energy dispersive (EDS) analysis a…

Electrocatalysts for Energy ConversionAdvanced Photocatalysis TechniquesCatalytic Processes in Materials Science

The effect of Pseudomonas NCIMB 2021 biofilm on AISI 316 stainless steel

Iwona B. Beech、Vitaly Zinkevich、L. Hanjangsit 等 5 位作者2000-05-01Biofouling

A bioreactor system operating in a continuous mode was designed to generate biofilms on polished and as-received surfaces of AISI 316 stainless steel coupons exposed for 36 d to a pure culture of marine Pseudomonas NCIMB 2021. Scanning electron microscopy (SEM) and atomic force microscopy were employed to determine th…

Corrosion Behavior and InhibitionHydrogen embrittlement and corrosion behaviors in metalsMarine Biology and Environmental Chemistry

Temperature and stress dependences of the magnetostriction in ternary and quaternary Terfenol alloys

J. B. Restorff、M. Wun‐Fogle、A. E. Clark2000-05-01Journal of Applied Physics

The magnetization and magnetostriction of a variety of Laves phase rods of TbxDyyHo1−x−yFe1.95 grown in the form of [112] oriented dendritic platelets were measured as a function of magnetic field H(−2200<H<2200 Oe), compressive stress (20, 30, and 40 MPa), and temperature T(−60<T<80 °C). C…

Microstructure and Mechanical Properties of SteelsMagnetic Properties and ApplicationsMagnetic Properties of Alloys

Revised Fine Splitting of Excitons in Diamond

R. Sauer、H. Sternschulte、Siegfried Wahl 等 5 位作者2000-05-01Physical Review Letters

We study low-strain synthetic high pressure, high temperature diamonds by cathodoluminescence and observe novel fine structure in the free exciton and the boron-bound exciton emission. The basic spectral structure is a doublet with DeltaE approximately 11 meV common to both exciton spectra. This resolves the previousl…

High-pressure geophysics and materialsDiamond and Carbon-based Materials ResearchElectronic and Structural Properties of Oxides

Single-Walled Carbon Nanotube–Polymer Composites: Strength and Weakness

Pulickel M. Ajayan、Linda S. Schadler、C. Giannaris 等 4 位作者2000-05-01Advanced Materials

Can carbon nanotubes be efficient structural reinforcements for high-strength polymer composites? Here it is shown that, during loading, individual single-walled nanotubes pull out of their bundles (see Figure), making load transfer difficult. It is thus concluded that the effectiveness of reinforcement is determined…

Carbon Nanotubes in CompositesConducting polymers and applications

A thermal van der Pauw test structure

Oliver Paul、Patrick Ruther、Luca Plattner 等 4 位作者2000-05-01IEEE Transactions on Semiconductor Manufacturing

A micromachined thermal van der Pauw test structure is reported. Similar in principle to the conventional electrical van der Pauw Greek cross test structures, it enables the in-plane thermal sheet conductivities of thin films to be determined. The microstructure was fabricated using a commercial CMOS application-speci…

Force Microscopy Techniques and ApplicationsThermal properties of materialsAdhesion, Friction, and Surface Interactions

Cs3AgAs4Se8 and CsAgAs2Se4: Selenoarsenates with Infinite 1∞[AsSe2]- Chains in Different Ag+ Coordination Environments

Michael Wachhold、Mercouri G. Kanatzidis2000-05-01Inorganic Chemistry

Two quaternary silver selenoarsenates Cs3AgAs4Se8 (I) and CsAgAs2Se4 (II) have been discovered by methanothermal reaction of Li3AsSe3 with AgBF4 in the presence of the respective alkali metal sources Cs2CO3 and CsCl. Orange crystals of Cs3AgAs4Se8 (I) were formed after reaction at 120 degrees C for 72 h, whereas red C…

Chalcogenide Semiconductor Thin FilmsCrystal Structures and PropertiesPhase-change materials and chalcogenides